Mayr's Database of Reactivity Parameters

H-C hydride donors

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
tetra-sec.butylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.15
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(phenethyl)stannane
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-propyl-1,3-dioxolane
C6H12O2 *
dichloromethane

N  Param.: -1.06

sN Param.: 0.81
*** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylplumbyl)propyl)germane (in MeCN)
*
MeCN

N  Param.: -1.00

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyldioxolane
C9H10O2 *
dichloromethane

N  Param.: -0.90

sN Param.: 0.80
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
3-propylcyclopentene
C8H14 *
dichloromethane

N  Param.: -0.88

sN Param.: 0.94
*** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
9,10-dihydroanthracene
C14H12 *
dichloromethane

N  Param.: -0.86

sN Param.: 0.92
*** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
(2-([1,1'-biphenyl]-4-yl)ethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: -0.80

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(E,E)-2,5-heptadiene
C7H12 *
dichloromethane

N  Param.: -0.74

sN Param.: 0.99
*** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
4-methyl-2,5-heptadiene
C8H14 *
dichloromethane

N  Param.: -0.73

sN Param.: 0.97
* J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538