Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-isopropyl-4,5-dimethyl-1,3-dioxolane (ani)
*
 dichloromethane

N  Param.: -4.10

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.40

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-isopropyl-4,5-dimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -3.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxepane
*
 dichloromethane

N  Param.: -3.80

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2)
C8H12 *
 dichloromethane

N  Param.: 1.88

sN Param.: 0.96		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,3,5-trimethylcyclohexa-1,4-diene (in CH2Cl2)
C9H14 *
 dichloromethane

N  Param.: 4.95

sN Param.: 0.79		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2)
C10H16 *
 dichloromethane

N  Param.: 4.27

sN Param.: 0.86		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
bis(4-methoxyphenyl)methane (in CH2Cl2)
C15H16O2 *
 dichloromethane

N  Param.: -2.11

sN Param.: 0.98		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,3-bis(trimethylsilyl)propane
*
 dichloromethane/MeCN mix

N  Param.: -5.30

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839