Mayr's Database of Reactivity Parameters

H-Si hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-Si hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
benzyldimethylsilane
C9H14Si *
 dichloromethane

N  Param.: 2.78

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
chlorodimethylsilane
C2H7ClSi *
 dichloromethane

N  Param.: 0.79

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dichloro(methyl)silane
*
 dichloromethane

N  Param.: -3.20

sN Param.: 0.73		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
diethyl(methyl)silane
C5H14Si *
 dichloromethane

N  Param.: 3.40

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dihexylsilane
*
 dichloromethane

N  Param.: 2.27

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl((trimethylgermyl)methyl)silane
C6H18GeSi *
 dichloromethane

N  Param.: 5.36

sN Param.: 0.62		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl((trimethylstannyl)methyl)silane
C6H18SiSn *
 dichloromethane

N  Param.: 6.53

sN Param.: 0.58		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl(neopentyl)silane
C7H18Si *
 dichloromethane

N  Param.: 3.55

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl(p-tolyl)silane
C9H14Si *
 dichloromethane

N  Param.: 3.83

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl(phenyl)silane
C8H12Si *
 dichloromethane

N  Param.: 3.55

sN Param.: 0.75		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839