Mayr's Database of Reactivity Parameters

H-Si hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-Si hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
dichloro(methyl)silane
*
 dichloromethane

N  Param.: -3.20

sN Param.: 0.73		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
triethoxysilane
C6H16O3Si *
 dichloromethane

N  Param.: -1.80

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
phenylsilane
C6H8Si *
 dichloromethane

N  Param.: 0.06

sN Param.: 0.71		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
hexylsilane
*
 dichloromethane

N  Param.: 0.19

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
chlorodimethylsilane
C2H7ClSi *
 dichloromethane

N  Param.: 0.79

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(chloromethyl)dimethylsilane
C3H9ClSi *
 dichloromethane

N  Param.: 0.80

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
methyl(neopentyl)(phenyl)silane
C12H20Si *
 dichloromethane

N  Param.: 0.87

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(3-chlorobenzyl)dimethylsilane
C9H13ClSi *
 dichloromethane

N  Param.: 1.30

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
diphenylsilane
*
 dichloromethane

N  Param.: 1.52

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
methyl(phenyl)silane
C7H10Si *
 dichloromethane

N  Param.: 2.13

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839