Mayr's Database of Reactivity Parameters

H-B hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-B hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
NaBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 14.74

sN Param.: 0.81		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
Bu4NBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 14.94

sN Param.: 0.79		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
KBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 15.14

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263