Mayr's Database of Reactivity Parameters

H-B hydride donors

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
bromoborane-triethylamine-complex
*
dichloromethane

N  Param.: 7.49

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-trimethylamine-complex
*
dichloromethane

N  Param.: 7.97

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N,N-diethylaniline-complex
*
dichloromethane

N  Param.: 8.53

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N,N-diisopropylaniline-complex
*
dichloromethane

N  Param.: 8.84

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-triethylamine-complex
C6H18BN *
dichloromethane

N  Param.: 8.90

sN Param.: 0.75
*** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
borane-N-ethyl-N-isopropylaniline-complex
*
dichloromethane

N  Param.: 9.12

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dipp Imd boronate
*
dichloromethane

N  Param.: 9.55

sN Param.: 0.81
*** Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
cyanoborate ion (in water)
*
water

N  Param.: 9.99

sN Param.: 0.54
*** Org. Biomol. Chem. 2023, 21, 85-88
10.1039/D2OB02041F
borane-pyridine-complex
*
dichloromethane

N  Param.: 10.01

sN Param.: 0.75
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
[H-B(C6F5)3]- [NEt4]+
*
MeCN

N  Param.: 10.04

sN Param.: 0.73
*** Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298