N-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
cysteine (dianionic, in water, S-nucleophile!)	water	N Param.: 23.43 s_N Param.: 0.42	Org. Biomol. Chem. 2007, 5, 3814-3820 10.1039/b713778h
trimethylamine (in MeCN)	MeCN	N Param.: 23.05 s_N Param.: 0.45	J. Org. Chem. 2012, 77, 8142-8155 10.1021/jo301497g
(S)-4-benzyl-1,3-oxazolidin-2-one anion (in DMSO)	DMSO	N Param.: 22.67 s_N Param.: 0.54	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883
1,1-dimethylhydrazine (in MeCN)	MeCN	N Param.: 22.41 s_N Param.: 0.45	Angew. Chem. Int. Ed. 2012, 51, 1353-1356 10.1002/anie.201107315
1,3-oxazolidin-2-one anion (in DMSO)	DMSO	N Param.: 22.40 s_N Param.: 0.59	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883
4-methyl-imidazole anion (in DMSO)	DMSO	N Param.: 21.29 s_N Param.: 0.51	Chem. Eur. J. 2012, 18, 127-137 10.1002/chem.201102411
imidazole anion (in DMSO)	DMSO	N Param.: 21.09 s_N Param.: 0.51	Chem. Eur. J. 2012, 18, 127-137 10.1002/chem.201102411
2-methyl-imidazole anion (in DMSO)	DMSO	N Param.: 21.03 s_N Param.: 0.50	Chem. Eur. J. 2012, 18, 127-137 10.1002/chem.201102411
2,4-dimethyl-imidazole anion (in DMSO)	DMSO	N Param.: 20.69 s_N Param.: 0.60	Chem. Eur. J. 2012, 18, 127-137 10.1002/chem.201102411
N-methyl-pyrrolidine (in CH2Cl2)	dichloromethane	N Param.: 20.60 s_N Param.: 0.52	J. Phys. Org. Chem. 2010, 23, 1029-1035 10.1002/poc.1707