Mayr's Database of Reactivity Parameters

Aliphatic amines

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Aliphatic amines

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-aminobutan-1-ol (in DMSO)
*
 DMSO

N  Param.: 14.39

sN Param.: 0.67		 *** J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
benzylamine (in DMSO)
*
 DMSO

N  Param.: 15.28

sN Param.: 0.65		 *** J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
1-aminopropan-2-ol (in DMSO)
*
 DMSO

N  Param.: 15.47

sN Param.: 0.65		 *** J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
diethanolamine (in DMSO)
*
 DMSO

N  Param.: 15.51

sN Param.: 0.70		 *** J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
ethanolamine (in DMSO)
*
 DMSO

N  Param.: 16.07

sN Param.: 0.61		 *** J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
DABCO (in MeCN)
C6H12N2 *
 MeCN

N  Param.: 18.80

sN Param.: 0.70		 *** Angew. Chem. Int. Ed. 2007, 46, 6176-6179
10.1002/anie.200701489
quinuclidine (in MeCN)
C7H13N *
 MeCN

N  Param.: 20.54

sN Param.: 0.60		 *** Angew. Chem. Int. Ed. 2007, 46, 6176-6179
10.1002/anie.200701489
2,2,2-trifluoroethylamine (in MeCN)
*
 MeCN

N  Param.: 10.13

sN Param.: 0.75		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
tert-butylamine (in MeCN)
*
 MeCN

N  Param.: 12.35

sN Param.: 0.72		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
isopropylamine (in MeCN)
*
 MeCN

N  Param.: 13.77

sN Param.: 0.70		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925