Mayr's Database of Reactivity Parameters

Aliphatic amines

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Aliphatic amines

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
quinuclidine (in MeCN)
C7H13N *
 MeCN

N  Param.: 20.54

sN Param.: 0.60		 *** Angew. Chem. Int. Ed. 2007, 46, 6176-6179
10.1002/anie.200701489
N-methyl-pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 20.59

sN Param.: 0.52		 *** J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-pyrrolidine (in CH2Cl2)
*
 dichloromethane

N  Param.: 20.60

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
trimethylamine (in MeCN)
*
 MeCN

N  Param.: 23.05

sN Param.: 0.45		 *** J. Org. Chem. 2012, 77, 8142-8155
10.1021/jo301497g