Mayr's Database of Reactivity Parameters

Pyridines, Quinolines etc.

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Pyridines, Quinolines etc.

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in CH2Cl2)
C12H11N2O3S- *
 dichloromethane

N  Param.: 19.63

sN Param.: 0.65		 *** J. Am. Chem. Soc. 2025, 147, 5043-5050
10.1021/jacs.4c14825
((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in MeCN)
C12H11N2O3S- *
 MeCN

N  Param.: 17.28

sN Param.: 0.65		 *** J. Am. Chem. Soc. 2025, 147, 5043-5050
10.1021/jacs.4c14825
2,4,6-trimethylpyridine (in CH2Cl2)
C8H11N *
 dichloromethane

N  Param.: 9.34

sN Param.: 0.71		 *** Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,4,6-trimethylpyridine (in MeCN)
C8H11N *
 MeCN

N  Param.: 9.39

sN Param.: 0.60		 *** Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,6-dimethylpyridine (in CH2Cl2)
C7H9N *
 dichloromethane

N  Param.: 9.87

sN Param.: 0.68		 *** Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,6-dimethylpyridine (in MeCN)
C7H9N *
 MeCN

N  Param.: 9.11

sN Param.: 0.69		 *** Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2-(naphthylmethyl)quinuclidine (in MeCN)
*
 MeCN

N  Param.: 15.66

sN Param.: 0.62		 *** J. Org. Chem. 2009, 74, 7157-7164
10.1021/jo901670w
2-Ac super-dmap (in MeCN)
*
 MeCN

N  Param.: 15.39

sN Param.: 0.60		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
2-Bn super-dmap (in MeCN)
*
 MeCN

N  Param.: 17.69

sN Param.: 0.57		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
2-Bz super-dmap (in MeCN)
*
 MeCN

N  Param.: 14.19

sN Param.: 0.67		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589