Mayr's Database of Reactivity Parameters

Pyridines, Quinolines etc.

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Pyridines, Quinolines etc.

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4-chloropyridine (in CH2Cl2)
C5H4ClN *
 dichloromethane

N  Param.: 11.70

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
pyridine (in CH2Cl2)
C5H5N *
 dichloromethane

N  Param.: 12.90

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-methylpyridine (in CH2Cl2)
C6H7N *
 dichloromethane

N  Param.: 13.70

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-methoxypyridine (in CH2Cl2)
C6H7NO *
 dichloromethane

N  Param.: 13.70

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-aminopyridine (in CH2Cl2)
C5H6N2 *
 dichloromethane

N  Param.: 15.20

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-(dimethylamino)pyridine (in CH2Cl2)
C7H10N2 *
 dichloromethane

N  Param.: 15.80

sN Param.: 0.66		 *** Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
4-pyrrolidinopyridine (in CH2Cl2)
C9H12N2 *
 dichloromethane

N  Param.: 15.90

sN Param.: 0.67		 * Chem. Eur. J. 2007, 13, 336-345
10.1002/chem.200600941
quinine
*
 dichloromethane

N  Param.: 10.46

sN Param.: 0.75		 *** J. Org. Chem. 2009, 74, 7157-7164
10.1021/jo901670w
quinidine
*
 dichloromethane

N  Param.: 10.54

sN Param.: 0.74		 *** J. Org. Chem. 2009, 74, 7157-7164
10.1021/jo901670w
4-(2-(fluorodiphenylmethyl)pyrrolidin-1-yl)pyridine
C22H21FN2 *
 dichloromethane

N  Param.: 14.57

sN Param.: 0.75		 *** Eur. J. Org. Chem. 2014, , 1202-1211
10.1002/ejoc.201301730