Mayr's Database of Reactivity Parameters

Pyridines, Quinolines etc.

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
quinine
*
 dichloromethane

N  Param.: 10.46

sN Param.: 0.75		***J. Org. Chem. 2009, 74, 7157-7164
10.1021/jo901670w
nicotine (in CH2Cl2)
C10H14N2*
 dichloromethane

N  Param.: 10.40

sN Param.: 1.04		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
2,6-dimethylpyridine (in CH2Cl2)
C7H9N*
 dichloromethane

N  Param.: 9.87

sN Param.: 0.68		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,4,6-trimethylpyridine (in MeCN)
C8H11N*
 MeCN

N  Param.: 9.39

sN Param.: 0.60		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,4,6-trimethylpyridine (in CH2Cl2)
C8H11N*
 dichloromethane

N  Param.: 9.34

sN Param.: 0.71		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504
2,6-dimethylpyridine (in MeCN)
C7H9N*
 MeCN

N  Param.: 9.11

sN Param.: 0.69		***Synthesis 2017, 49, 3495-3504
10.1055/s-0036-1590504