Mayr's Database of Reactivity Parameters

Hydrazines, Hydroxylamines etc.

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Hydrazines, Hydroxylamines etc.

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)
C3H8N2 *
 dichloromethane

N  Param.: 19.31

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092
N-methylenepyrrolidin-1-amine (in CH2Cl2)
C5H10N2 *
 dichloromethane

N  Param.: 17.90

sN Param.: 0.48		 *** Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092
hydrazine (in MeCN)
*
 MeCN

N  Param.: 16.45

sN Param.: 0.56		 *** Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
1,1-dimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 11.72

sN Param.: 0.73		 *** Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
trimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 12.43

sN Param.: 0.75		 *** Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
1,1-dimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 22.41

sN Param.: 0.45		 *** Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
trimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 17.75

sN Param.: 0.53		 *** Angew. Chem. Int. Ed. 2012, 51, 1353-1356
10.1002/anie.201107315
methylhydrazine (in MeCN)
*
 MeCN

N  Param.: 17.73

sN Param.: 0.58		 *** J. Org. Chem. 2012, 77, 8142-8155
10.1021/jo301497g
1,2-dimethylhydrazine (in MeCN)
*
 MeCN

N  Param.: 16.15

sN Param.: 0.68		 *** J. Org. Chem. 2012, 77, 8142-8155
10.1021/jo301497g
formohydrazide (in MeCN)
*
 MeCN

N  Param.: 10.35

sN Param.: 0.76		 *** J. Org. Chem. 2012, 77, 8142-8155
10.1021/jo301497g