Mayr's Database of Reactivity Parameters

Azoles and Azole Anions

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Azoles and Azole Anions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
imidazole (in DMSO)
*
 DMSO

N  Param.: 11.58

sN Param.: 0.79		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
benzimidazole (in DMSO)
*
 DMSO

N  Param.: 10.50

sN Param.: 0.79		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
2-methyl-benzimidazole (in DMSO)
*
 DMSO

N  Param.: 10.02

sN Param.: 0.85		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
5-methyl-benzimidazole (in DMSO)
*
 DMSO

N  Param.: 10.69

sN Param.: 0.79		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
2,5-dimethyl-benzimidazole (in DMSO)
*
 DMSO

N  Param.: 10.21

sN Param.: 0.85		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
5,6-dimethyl-benzimidazole (in DMSO)
*
 DMSO

N  Param.: 11.08

sN Param.: 0.71		 *** Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
5-methoxy-benzimidazole (in DMSO)
*
 DMSO

N  Param.: 11.00

sN Param.: 0.71		 * Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.09

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.03

sN Param.: 0.50		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.29

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411