Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
20% water/80% acetone (v/v)
H2O *
 water-acetone mix

N  Param.: 5.77

sN Param.: 0.87		 *** Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
20% ethanol/80% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 5.77

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
60% water/40%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.81

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.96

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% methanol/80% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.04

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% ethanol/67% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.06

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
40% water/60%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.28

sN Param.: 0.87		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% ethanol/50% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.37

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% methanol/67% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.38

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z