Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1% water/99% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
t-butylperoxy anion (in H2O)
C4H9O2 *
 water

N  Param.: 14.29

sN Param.: 0.51		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
cumene peroxy anion (in H2O)
C9H11O2 *
 water

N  Param.: 13.92

sN Param.: 0.61		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
phthalimidoperoxyhexanoate (in H2O)
C14H20NO5 *
 water

N  Param.: 16.02

sN Param.: 0.54		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
2-phenylperoxyacetate (in H2O)
C8H7O3 *
 water

N  Param.: 15.63

sN Param.: 0.56		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3,5-dichloroperoxybenzoate (in H2O)
C7H3Cl2O3 *
 water

N  Param.: 17.93

sN Param.: 0.50		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
magnesium 2-carboperoxybenzoate (in H2O)
C8H4O5 *
 water

N  Param.: 18.43

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3-chloroperoxybenzoate (in H2O)
C7H4ClO3 *
 water

N  Param.: 18.19

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-fluoroperoxybenzoate (in H2O)
C7H4FO3 *
 water

N  Param.: 17.99

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-nitroperoxybenzoate (in H2O)
C7H4NO5 *
 water

N  Param.: 17.43

sN Param.: 0.50		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086