Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
91% propan-2-ol/9% MeCN (v/v)
C3H8O *
 iPrOH-MeCN mix

N  Param.: 6.49

sN Param.: 0.96		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
50% methanol/50% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.67

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% water/80%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.68

sN Param.: 0.85		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% ethanol/33% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.74

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
80% ethanol/20% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.94

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% water/90%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 7.03

sN Param.: 0.86		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
91% n-propanol/9% MeCN (v/v)
C3H8O *
 nPrOH-MeCN mix

N  Param.: 7.05

sN Param.: 0.80		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170