Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
80% methanol/20% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.20

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% methanol/50% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.67

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% methanol/67% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.38

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% methanol/80% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.04

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% methanol/90% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 5.55

sN Param.: 0.97		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
methanolate (in 91M9AN)
CH3O- *
 MeOH-MeCN mix

N  Param.: 14.51

sN Param.: 0.68		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
n-propanolate (in propan-1-ol)
C3H8O- *
 nPrOH

N  Param.: 16.03

sN Param.: 0.70		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
91% n-propanol/9% MeCN (v/v)
C3H8O *
 nPrOH-MeCN mix

N  Param.: 7.05

sN Param.: 0.80		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
n-propanolate (in 91nPr9AN)
C3H8O- *
 nPrOH-MeCN mix

N  Param.: 16.73

sN Param.: 0.63		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170