Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
o,o'-di-tert-butylphenolate (in DMSO)
C14H21KO *
 DMSO

N  Param.: 21.02

sN Param.: 0.59		 ** J. Org. Chem. 2019, 84, 8837-8858
10.1021/acs.joc.9b01485
ethanol
C2H6O *
 EtOH

N  Param.: 7.44

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
ethanolate (in ethanol)
C2H5O- *
 EtOH

N  Param.: 15.78

sN Param.: 0.65		 *** Can. J. Chem. 2005, 83, 1554-1560
10.1139%2Fv05-170
91% ethanol/9% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 7.10

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% ethanol/20% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.94

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% ethanol/33% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.74

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% ethanol/50% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.37

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% ethanol/67% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.06

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% ethanol/80% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 5.77

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% ethanol/90% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 5.19

sN Param.: 0.96		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z