Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1% water/99% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
2% water/98% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.62

sN Param.: 1.10		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
3% water/97% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.19

sN Param.: 1.08		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
5% water/95% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -0.10

sN Param.: 0.97		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
7% water/93% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.34

sN Param.: 0.96		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.96

sN Param.: 0.93		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
trifluoroethanol
C2H3F3O *
 TFE

N  Param.: 1.11

sN Param.: 0.96		 *** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
50% water/50% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.50

sN Param.: 1.03		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
30% water/70% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.65

sN Param.: 0.96		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 2.93

sN Param.: 0.88		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z