Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
40% water/60%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 6.28

sN Param.: 0.87		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.96

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
60% water/40%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.81

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.54

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
90% water/10%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.38

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% water/50% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.50

sN Param.: 1.03		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
30% water/70% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.65

sN Param.: 0.96		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.96

sN Param.: 0.93		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
7% water/93% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.34

sN Param.: 0.96		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
5% water/95% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -0.10

sN Param.: 0.97		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064