Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
60% water/40%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 3.77

sN Param.: 0.88		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% ethanol/33% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.74

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% water/33% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.05

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
7% water/93% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.34

sN Param.: 0.96		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
80% ethanol/20% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 6.94

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% methanol/20% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.20

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.04

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%EtOH (v/v)
*
 water-EtOH mix

N  Param.: 5.54

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20%TFE (v/v)
H2O *
 water-TFE mix

N  Param.: 4.78

sN Param.: 0.83		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z