Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
ethanol (in MeCN)
*
 MeCN

N  Param.: 7.13

sN Param.: 0.71		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
tert-butanol (in MeCN)
*
 MeCN

N  Param.: 5.35

sN Param.: 0.72		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
methanol
CH4O *
 MeOH

N  Param.: 7.54

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
91% methanol/9% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.45

sN Param.: 0.87		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% methanol/20% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.20

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% methanol/50% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.67

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z