Allyl Element Compounds
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II)   |
dichloromethane | N Param.: 8.45 sN Param.: 0.83 |
 |
Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 |
allyltris(trimethylsilyl)silane  |
dichloromethane | N Param.: 1.95 sN Param.: 0.98 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
(2-methylallyl)tris(trimethylsilyl)silane  |
dichloromethane | N Param.: 4.63 sN Param.: 0.87 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
2-phenyl-allyltrimethylsilane  |
dichloromethane | N Param.: 5.38 sN Param.: 0.89 |
|
Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215 |
(1H-inden-1-yl)trimethylstannane (in CH2Cl2)  |
dichloromethane | N Param.: 6.68 sN Param.: 0.81 |
|
Angew. Chem. Int. Ed. 2015, 54, 12497-12500 10.1002/anie.201501385 |
(1H-inden-1-yl)trimethylsilane (in CH2Cl2)  |
dichloromethane | N Param.: -0.10 sN Param.: 1.05 |
|
Angew. Chem. Int. Ed. 2015, 54, 12497-12500 10.1002/anie.201501385 |
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)  |
dichloromethane | N Param.: -0.64 sN Param.: 1.10 |
|
J. Am. Chem. Soc. 2017, 139, 15324-15327 10.1021/jacs.7b10240 |
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)  |
MeCN | N Param.: 8.71 sN Param.: 0.80 |
|
J. Am. Chem. Soc. 2017, 139, 15324-15327 10.1021/jacs.7b10240 |
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)  |
MeCN | N Param.: 9.49 sN Param.: 0.82 |
|
J. Am. Chem. Soc. 2017, 139, 15324-15327 10.1021/jacs.7b10240 |
allyltrimethylsilane  |
dichloromethane | N Param.: 1.68 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |