Mayr's Database of Reactivity Parameters

C-Electrophiles

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(mpa)2CH+
C27H25N2 *

E Param.: -5.89

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(pcp)2CH+
C13H9Cl2 *

E Param.: 5.48

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(pfa)2CH+
C29H23F6N2 *

E Param.: -3.14

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(pfp)2CH+
C13H9F2 *

E Param.: 5.01, Deviation: ±0.05

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(PhCH2)2N+=CH-CH-Ph
C23H22N+ *

E Param.: -8.50

 *** Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889
(pyr)2CH+
C21H25N2 *

E Param.: -7.69

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium
C25H31N2O4 *
 dichloromethane

E Param.: -7.00

 ** Angew. Chem. Int. Ed. 2013, 52, 7967-7971
10.1002/anie.201301864
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium
C22H20F5N2O *
 dichloromethane

E Param.: -6.00

 ** Angew. Chem. Int. Ed. 2013, 52, 7967-7971
10.1002/anie.201301864
(S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium
C24H26N3O *
 dichloromethane

E Param.: -7.30

 ** Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009
(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium
C24H30N3O *
 dichloromethane

E Param.: -10.60

 ** Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009