Mayr's Database of Reactivity Parameters

C-Electrophiles

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-methylsulfanylpropan-2-one (in DMSO)
C4H8OS *
 DMSO

E Param.: -15.60

 * J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
3-methylcyclopentenone
C6H8O *
 DMSO

E Param.: -28.90

 * Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
2-methylcyclohexenone
C7H10O *
 DMSO

E Param.: -27.50

 * Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylcyclohexenone
C7H10O *
 DMSO

E Param.: -29.60

 * Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
bh6a
*

E Param.: -18.60

 ** Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
bh 6f
*

E Param.: -18.90

 ** Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
bh 6i
*

E Param.: -19.10

 ** Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
bh6j
*

E Param.: -17.90

 ** Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
diarylallylium ion (3-F)2
*

E Param.: 4.15

 ** J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w
indolecarboxylate derived iminium ion
*
 dichloromethane

E Param.: -9.50

 ** Angew. Chem. Int. Ed. 2009, 48, 5034-5037
10.1002/anie.200900933