|
di-p-anisyl-allylium ion
|
|
E Param.: -1.45 |
 |
J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
|
diarylallylium ion (4-NMe2)2
|
|
E Param.: -7.50 |
|
J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
|
bis(julidin-9-yl)allylium ion
|
|
E Param.: -9.78 |
|
J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
|
4-methoxy-<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -14.70 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
4-methyl-<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -14.23 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -13.85 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
4-bromo-<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -13.37 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
4-cyano-<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -12.61 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
4-nitro-<i>trans-beta</i>-nitrostyrene
|
|
E Param.: -12.37 |
|
J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
|
(ethene-1,1-diyldisulfonyl)dibenzene
|
DMSO |
E Param.: -7.50 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
(2-phenylethene-1,1-diyldisulfonyl)dibenzene
|
DMSO |
E Param.: -12.93 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene
|
DMSO |
E Param.: -13.88 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline
|
DMSO |
E Param.: -16.53 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide
|
DMSO |
E Param.: -11.78 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide
|
DMSO |
E Param.: -13.02 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide
|
DMSO |
E Param.: -14.55 |
|
Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
|
MacMillan-iminium ion (2nd generation)
|
MeCN |
E Param.: -5.52 |
|
Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
|
MacMillan-iminium ion (spiro)
|
MeCN |
E Param.: -7.67 |
|
Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)
|
|
E Param.: -14.14 |
|
Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)
|
|
E Param.: -14.21 |
|
Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)
|
|
E Param.: -14.46 |
|
Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
|
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium
|
DMSO |
E Param.: -11.52 |
|
Angew. Chem. Int. Ed. 2012, 51, 5234-5238
10.1002/anie.201109042 |
|
PhCH=N+Me2 (in MeCN)
|
MeCN |
E Param.: -9.27 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
pTolCH=N+CH2 (in MeCN)
|
MeCN |
E Param.: -9.64 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
p-AniCH=N+Me2 (in MeCN)
|
MeCN |
E Param.: -10.69 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
PhCH=N+(CH2)4 (in MeCN)
|
MeCN |
E Param.: -9.35 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
PhCH=N+(CH2)5 (in MeCN)
|
MeCN |
E Param.: -9.60 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
p-CF3-C6H4-CH=N+Me2 (in MeCN)
|
MeCN |
E Param.: -8.34 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
|
2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ)
|
MeCN |
E Param.: -3.66 |
|
J. Am. Chem. Soc. 2013, 135, 12377-12387
10.1021/ja405890d |
|
maleic anhydride
|
DMSO |
E Param.: -11.31 |
|
Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
|
N-methyl maleimide
|
DMSO |
E Param.: -14.07 |
|
Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
|
fumaronitrile
|
DMSO |
E Param.: -15.71 |
|
Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
|
diethyl fumarate
|
DMSO |
E Param.: -17.79 |
|
Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
|
diethyl maleate
|
DMSO |
E Param.: -19.49 |
|
Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
|
2,5-dichloroquinone (C-H)
|
|
E Param.: -12.28 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
2,5-dichloroquinone (C-Cl)
|
|
E Param.: -16.11 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
p-chloranil (C=O)
|
|
E Param.: -12.13 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
p-chloranil (C-Cl)
|
|
E Param.: -13.84 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
p-fluoranil (C=O)
|
|
E Param.: -9.37 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
p-fluoranil (C-F)
|
|
E Param.: -11.12 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
o-chloranil (C=O)
|
|
E Param.: -8.77 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
o-chloranil (C-Cl)
|
|
E Param.: -12.02 |
|
J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
|
3-benzylidene-1-methyl-3H-indol-1-ium ion
|
|
E Param.: -1.80 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
|
|
E Param.: -2.19 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom
|
|
E Param.: -3.02 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion
|
|
E Param.: -6.26 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion
|
|
E Param.: -7.79 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
|
|
E Param.: -5.15 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion
|
|
E Param.: -5.05 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
bis(1-methylindol-3-yl)methylium ion
|
|
E Param.: -5.99 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
bis(5-methoxy-1-methylindol-3-yl)methylium ion
|
|
E Param.: -6.90 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
bis(1,2-dimethylindol-3-yl)methylium ion
|
|
E Param.: -10.23 |
|
J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
|
ethenesulfonyl fluoride (ESF)
|
DMSO |
E Param.: -12.09 |
|
Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
|
2-phenylethene-1-sulfonyl fluoride
|
DMSO |
E Param.: -16.63 |
|
Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
|
9-phenyl-9H-fluoren-9-ylium
|
dichloromethane |
E Param.: 2.41 |
|
Chem. Eur. J. 2017, 23, 623-630
10.1002/chem.201603963 |
|
9-(4-methoxyphenyl)-9H-fluoren-9-ylium
|
dichloromethane |
E Param.: 0.85 |
|
Chem. Eur. J. 2017, 23, 623-630
10.1002/chem.201603963 |
|
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium
|
dichloromethane |
E Param.: -4.51 |
|
Chem. Eur. J. 2017, 23, 623-630
10.1002/chem.201603963 |
|
(E)-4-phenylbut-3-en-2-one (in DMSO)
|
DMSO |
E Param.: -23.01 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
methyl prop-2-enoate (in DMSO)
|
DMSO |
E Param.: -18.84 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
ethyl prop-2-enoate (in DMSO)
|
DMSO |
E Param.: -19.07 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
tert-butyl prop-2-enoate (in DMSO)
|
DMSO |
E Param.: -20.22 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
N,N-dimethylprop-2-enamide (in DMSO)
|
DMSO |
E Param.: -23.54 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
ethenylsulfonylbenzene (in DMSO)
|
DMSO |
E Param.: -18.36 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
acrylonitrile (in DMSO)
|
DMSO |
E Param.: -19.05 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
but-3-en-2-one (in DMSO)
|
DMSO |
E Param.: -16.76 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
1-phenylprop-2-en-1-one (in DMSO)
|
DMSO |
E Param.: -15.25 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
|
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium
|
DMSO |
E Param.: -10.09 |
|
Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...] |
|
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium
|
DMSO |
E Param.: -11.80 |
|
Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...] |
|
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium
|
DMSO |
E Param.: -11.48 |
|
Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...] |
|
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium
|
DMSO |
E Param.: -11.79 |
|
Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...] |
|
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium
|
DMSO |
E Param.: -12.02 |
|
Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...] |
|
2-methylcyclopentenone
|
DMSO |
E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
cyclopentenone
|
DMSO |
E Param.: -20.60 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
furan-2(5H)-one
|
DMSO |
E Param.: -20.70 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
cyclohexenone
|
DMSO |
E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
3-methylenetetrahydropyran-2-one
|
DMSO |
E Param.: -19.50 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
3-methylenedihydrofuranone
|
DMSO |
E Param.: -19.40 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one
|
DMSO |
E Param.: -17.00 |
|
Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
|
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one
|
DMSO |
E Param.: -16.84 |
|
Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
|
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one
|
DMSO |
E Param.: -16.25 |
|
Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
|
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one
|
DMSO |
E Param.: -17.42 |
|
Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
|
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one
|
DMSO |
E Param.: -11.68 |
|
Eur. J. Org. Chem. 2020, , 3812-3817
10.1002/ejoc.202000295 |
|
3-nitro-1-tosyl-1H-indole
|
|
E Param.: -14.87 |
|
Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
|
phenyl isocyanate
|
MeCN |
E Param.: -15.38 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
p-tosyl isocyanate
|
MeCN |
E Param.: -7.69 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
phenyl isothiocyanate
|
DMSO |
E Param.: -18.15 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
p-nitrophenyl isothiocyanate
|
DMSO |
E Param.: -15.89 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
diphenylcarbodiimide
|
DMSO |
E Param.: -20.14 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
carbon disulfide
|
DMSO |
E Param.: -17.70 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
|
3,6-dinitro-1-tosyl-1H-indole
|
|
E Param.: -12.90 |
|
Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
|
cycloheptenone
|
DMSO |
E Param.: -22.00 |
|
Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A |
|
Umemoto I (triflate)
|
|
E Param.: -13.08 |
|
Eur. J. Org. Chem. 2024, 27, e202400085
10.1002/ejoc.202400085 |
|
Umemoto I (tetrafluoroborate)
|
|
E Param.: -13.39 |
|
Eur. J. Org. Chem. 2024, 27, e202400085
10.1002/ejoc.202400085 |
|
Umemoto II (triflate)
|
|
E Param.: -12.80 |
|
Eur. J. Org. Chem. 2024, 27, e202400085
10.1002/ejoc.202400085 |
|
(E)-6-(4-nitrobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -13.15 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
|
(E)-6-(4-(trifluoromethyl)benzylidene)benzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -13.54 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
|
(E)-6-(3-fluorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -14.00 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
|
(E)-6-(4-chlorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -13.99 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
|
(E)-6-benzylidenebenzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -14.47 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
|
(E)-6-(4-methylbenzylidene)benzo[d][1,3]dioxol-5(6H)-one
|
|
E Param.: -14.85 |
|
Chem. Eur. J. 2025, 31, e202403785
10.1002/chem.202403785 |
C-Nucleophiles (602)
