C-Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
ani(pop)CH+   |
E Param.: 0.61 |
 |
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
ani(t-Bu)2QM  |
E Param.: -16.11 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(tol)CH+  |
E Param.: 1.48 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
aniBBS  |
E Param.: -10.37 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
benzaldehyde (in DMSO)  |
DMSO | E Param.: -12.90 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
benzaldehyde-boron trichloride complex  |
E Param.: 1.12, Deviation: ±0.24 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
benzhydrylium ion Ph2CH+  |
E Param.: 5.47 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
benzylidene-Meldrum's acid  |
E Param.: -9.15 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
benzylidenemalononitrile  |
E Param.: -9.42 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6m  |
E Param.: -17.30 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bis(1,2-dimethylindol-3-yl)methylium ion  |
E Param.: -10.23 |
|
J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 |
|
bis(1-methylindol-3-yl)methylium ion  |
E Param.: -5.99 |
|
J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 |
|
bis(5-methoxy-1-methylindol-3-yl)methylium ion  |
E Param.: -6.90 |
|
J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 |
|
bis(julidin-9-yl)allylium ion  |
E Param.: -9.78 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
but-3-en-2-one (in DMSO)  |
DMSO | E Param.: -16.76 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
butanal (in DMSO)  |
DMSO |  |
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
|
butynone  |
E Param.: -16.60 |
|
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
C6H6OMe+-Fe(CO)3  |
E Param.: -8.94, Deviation: ±0.13 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H7+-Fe(CO)3  |
E Param.: -7.76, Deviation: ±0.31 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H7+-Fe(CO)3  |
E Param.: -3.49, Deviation: ±0.17 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H9+-Fe(CO)3  |
E Param.: -9.21, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
carbon disulfide  |
DMSO | E Param.: -17.70 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
cinnamaldehyde (in DMSO)  |
DMSO | |
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
|
cinnamonitrile (in DMSO)  |
DMSO | E Param.: -24.60 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
cumyl cation  |
E Param.: 5.74 |
|
Macromolecules 2010, 43, 1719-1723 10.1021/ma9024569 |
|
cyclobutanone (in DMSO)  |
DMSO | E Param.: -17.50 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
cycloheptanone (in DMSO)  |
DMSO | E Param.: -22.10 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
cycloheptenone  |
DMSO | E Param.: -22.00 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclohexanone (in DMSO)  |
DMSO | E Param.: -19.90 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
cyclohexenone  |
DMSO | E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclopentanone (in DMSO)  |
DMSO | E Param.: -21.00 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
cyclopentenone  |
DMSO | E Param.: -20.60 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
di-p-anisyl-allylium ion  |
E Param.: -1.45 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
di-p-tolyl-allylium ion  |
E Param.: 1.23 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
diarylallylium ion (3,3-F2)2  |
E Param.: 6.11 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
diarylallylium ion (3-F)2  |
E Param.: 4.15 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
diarylallylium ion (4-Br)2  |
E Param.: 2.85 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
diarylallylium ion (4-Cl)2  |
E Param.: 2.69 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
diarylallylium ion (4-NMe2)2  |
E Param.: -7.50 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |
|
dibenzo[a,d]tropylium ion  |
dichloromethane | E Param.: -0.63 |
|
Liebigs Ann. 1995, , 2005-2009 10.1002/jlac.1995199[...] |
dicarbonyl(cyclopentadienyl)propene-iron(II)  |
E Param.: -11.20 |
|
Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 |
|
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate  |
E Param.: -23.40 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 2-((julolidine-9-yl)methylene)malonate  |
E Param.: -23.80 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 3-chloro-benzylidene malonate  |
E Param.: -18.98 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |