C-Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
diethyl 4-(dimethylamino)benzylidene malonate		E Param.: -23.10	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-cyano-benzylidene malonate		E Param.: -18.06	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-methoxy-benzylidene malonate		E Param.: -21.47	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-methyl-benzylidene malonate		E Param.: -21.11	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-nitrobenzylidene malonate		E Param.: -17.67	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl benzylidene malonate		E Param.: -20.55	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl fumarate	DMSO	E Param.: -17.79	Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779
diethyl maleate	DMSO	E Param.: -19.49	Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779
dihydro-2H-pyran-2-one	DMSO	E Param.: -21.80	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
dimethylmethyleneammonium ion		E Param.: -6.69	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
diphenylallylium ion		E Param.: 2.70	J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w
diphenylcarbodiimide	DMSO	E Param.: -20.14	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
dma(Ph)2QM		E Param.: -13.39	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
dma(S)BBS		E Param.: -10.73	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
dma(t-Bu)2QM		E Param.: -17.29	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
dmaBBS		E Param.: -12.76	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.84	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
ethenesulfonyl fluoride (ESF)	DMSO	E Param.: -12.09	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
ethenylsulfonylbenzene (in DMSO)	DMSO	E Param.: -18.36	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl (E)-but-2-enoate (in DMSO)	DMSO	E Param.: -23.59	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl 2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetate		E Param.: -12.01	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
ethyl 2-methylprop-2-enoate (in DMSO)	DMSO	E Param.: -22.77	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl 3-nitro-1H-indole-1-carboxylate		E Param.: -14.10	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
ethyl cinnamate (in DMSO)	DMSO	E Param.: -24.52	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl prop-2-enoate (in DMSO)	DMSO	E Param.: -19.07	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
fc(ani)CH+		E Param.: -2.90, Deviation: ±0.09	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
fc(Me)CH+		E Param.: -2.57	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
fc(Ph)CH+		E Param.: -2.64	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
fc2CH+		E Param.: -8.54, Deviation: ±0.53	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
flavylium ion		E Param.: -3.45, Deviation: ±0.16	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
fumaronitrile	DMSO	E Param.: -15.71	Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779
furan-2(5H)-one	DMSO	E Param.: -20.70	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
hex-3-yn-2-one		E Param.: -17.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
hexanal (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
indolecarboxylate derived iminium ion	dichloromethane	E Param.: -9.50	Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933
Jorgensen/Hayashi-iminium ion		E Param.: -8.20	Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889
jul Meldrum's acid		E Param.: -13.97	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s
jul(S)BBS		E Param.: -11.89	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
jul(t-Bu)2QM		E Param.: -17.90	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
jul-indan-1,3-dione		E Param.: -14.68	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
julBBS		E Param.: -13.84	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
MacMillan-iminium ion (1st generation)	MeCN	E Param.: -7.37	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (2nd generation)	MeCN	E Param.: -5.52	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (spiro)	MeCN	E Param.: -7.67	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
maleic anhydride	DMSO	E Param.: -11.31	Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779
Me2C=C=N(+)Me2		E Param.: -2.80	Synthesis 2025, 57, 3251-3262 10.1055/a-2649-1999
Me2N+=CH-CH-Ph		E Param.: -9.20	Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889
methoxy-(4-methoxyphenyl)methylium ion		E Param.: 0.14, Deviation: ±0.01	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
methoxy-(4-methylphenyl)methylium ion		E Param.: 1.90, Deviation: ±0.22	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
methoxy-phenylmethylium ion		E Param.: 2.97, Deviation: ±0.09	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c