Mayr's Database of Reactivity Parameters

Acceptor-Substituted Ethylenes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Acceptor-Substituted Ethylenes

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
bh 6k
*

E Param.: -18.20

 * Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
diethyl 4-cyano-benzylidene malonate
C15H15NO4 *

E Param.: -18.06

 *** Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
jul(t-Bu)2QM
*

E Param.: -17.90

 **** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
bh6j
*

E Param.: -17.90

 ** Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
hex-3-yn-2-one
C6H8O *

E Param.: -17.90

 - Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803
diethyl fumarate
C8H12O4 *
 DMSO

E Param.: -17.79

 *** Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779
diethyl 4-nitrobenzylidene malonate
C14H15NO6 *

E Param.: -17.67

 *** Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
*
 DMSO

E Param.: -17.64

 *** J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one
C24H30O2 *
 DMSO

E Param.: -17.42

 *** Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...]
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
*
 DMSO

E Param.: -17.33

 *** J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m