Acceptor-Substituted Ethylenes
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione   |
E Param.: -13.56 |
 |
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-(p-methoxybenzylidene)-indan-1,3-dione  |
E Param.: -11.32 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-benzylidene-indan-1,3-dione  |
E Param.: -10.11 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide  |
DMSO | E Param.: -11.78 |
|
Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium  |
DMSO | E Param.: -11.52 |
|
Angew. Chem. Int. Ed. 2012, 51, 5234-5238 10.1002/anie.201109042 |
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium  |
DMSO | E Param.: -12.02 |
|
Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium  |
DMSO | E Param.: -11.79 |
|
Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium  |
DMSO | E Param.: -11.48 |
|
Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium  |
DMSO | E Param.: -10.09 |
|
Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-methylcyclohexenone  |
DMSO | E Param.: -27.50 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-methylcyclopentenone  |
DMSO | E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-phenylethene-1-sulfonyl fluoride  |
DMSO | E Param.: -16.63 |
|
Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
3-methylcyclohexenone  |
DMSO | E Param.: -29.60 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylcyclopentenone  |
DMSO | E Param.: -28.90 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylenedihydrofuranone  |
DMSO | E Param.: -19.40 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylenetetrahydropyran-2-one  |
DMSO | E Param.: -19.50 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline  |
DMSO | E Param.: -16.53 |
|
Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
4-benzylidene-2,6-di-tert-butylcyclohexa-2,5-dien-1-one  |
E Param.: -15.58 |
|
Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224 |
|
4-bromo-<i>trans-beta</i>-nitrostyrene  |
E Param.: -13.37 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
4-cyano-<i>trans-beta</i>-nitrostyrene  |
E Param.: -12.61 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
4-methoxy-<i>trans-beta</i>-nitrostyrene  |
E Param.: -14.70 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
4-methyl-<i>trans-beta</i>-nitrostyrene  |
E Param.: -14.23 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
4-nitro-<i>trans-beta</i>-nitrostyrene  |
E Param.: -12.37 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
4-phenylbut-3-yn-2-one  |
E Param.: -16.90 |
 |
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
<i>trans-beta</i>-nitrostyrene  |
E Param.: -13.85 |
|
J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |
|
acrylonitrile (in DMSO)  |
DMSO | E Param.: -19.05 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ani(Br)2QM  |
E Param.: -8.63 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(Ph)2QM  |
E Param.: -12.18 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(t-Bu)2QM  |
E Param.: -16.11 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
aniBBS  |
E Param.: -10.37 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
benzylidene-Meldrum's acid  |
E Param.: -9.15 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
benzylidenemalononitrile  |
E Param.: -9.42 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6m  |
E Param.: -17.30 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
but-3-en-2-one (in DMSO)  |
DMSO | E Param.: -16.76 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
butynone  |
E Param.: -16.60 |
|
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
cinnamonitrile (in DMSO)  |
DMSO | E Param.: -24.60 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
cycloheptenone  |
DMSO | E Param.: -22.00 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclohexenone  |
DMSO | E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclopentenone  |
DMSO | E Param.: -20.60 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate  |
E Param.: -23.40 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 2-((julolidine-9-yl)methylene)malonate  |
E Param.: -23.80 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 3-chloro-benzylidene malonate  |
E Param.: -18.98 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-(dimethylamino)benzylidene malonate  |
E Param.: -23.10 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-cyano-benzylidene malonate  |
E Param.: -18.06 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |