Acceptor-Substituted Ethylenes
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
3-methylcyclohexenone   |
DMSO | E Param.: -29.60 |
 |
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylcyclopentenone  |
DMSO | E Param.: -28.90 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-methylcyclohexenone  |
DMSO | E Param.: -27.50 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)  |
DMSO | E Param.: -24.69 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
cinnamonitrile (in DMSO)  |
DMSO | E Param.: -24.60 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl cinnamate (in DMSO)  |
DMSO | E Param.: -24.52 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
diethyl 2-((julolidine-9-yl)methylene)malonate  |
E Param.: -23.80 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
ethyl (E)-but-2-enoate (in DMSO)  |
DMSO | E Param.: -23.59 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
N,N-dimethylprop-2-enamide (in DMSO)  |
DMSO | E Param.: -23.54 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate  |
E Param.: -23.40 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-(dimethylamino)benzylidene malonate  |
E Param.: -23.10 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
(E)-4-phenylbut-3-en-2-one (in DMSO)  |
DMSO | E Param.: -23.01 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl 2-methylprop-2-enoate (in DMSO)  |
DMSO | E Param.: -22.77 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
2-methylcyclopentenone  |
DMSO | E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclohexenone  |
DMSO | E Param.: -22.10 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cycloheptenone  |
DMSO | E Param.: -22.00 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
dihydro-2H-pyran-2-one  |
DMSO | E Param.: -21.80 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
diethyl 4-methoxy-benzylidene malonate  |
E Param.: -21.47 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-methyl-benzylidene malonate  |
E Param.: -21.11 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
furan-2(5H)-one  |
DMSO | E Param.: -20.70 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
cyclopentenone  |
DMSO | E Param.: -20.60 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
diethyl benzylidene malonate  |
E Param.: -20.55 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
tert-butyl prop-2-enoate (in DMSO)  |
DMSO | E Param.: -20.22 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
3-methylenetetrahydropyran-2-one  |
DMSO | E Param.: -19.50 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
diethyl maleate  |
DMSO | E Param.: -19.49 |
|
Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
3-methylenedihydrofuranone  |
DMSO | E Param.: -19.40 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
(E)-1,3-diphenylprop-2-en-1-one (in DMSO)  |
DMSO | E Param.: -19.39 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO)  |
DMSO | E Param.: -19.36 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO)  |
DMSO | E Param.: -19.17 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one  |
DMSO | E Param.: -19.15 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
ethyl prop-2-enoate (in DMSO)  |
DMSO | E Param.: -19.07 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
acrylonitrile (in DMSO)  |
DMSO | E Param.: -19.05 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
diethyl 3-chloro-benzylidene malonate  |
E Param.: -18.98 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
methyl prop-2-enoate (in DMSO)  |
DMSO | E Param.: -18.84 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
(E)-2-(4-methoxybenzylidene)acenaphthylen-1(2H)-one  |
E Param.: -18.72 |
|
J. Phys. Org. Chem. 2026, 39, e70061 10.1002/poc.70061 |
|
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
ethenylsulfonylbenzene (in DMSO)  |
DMSO | E Param.: -18.36 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
diethyl 4-cyano-benzylidene malonate  |
E Param.: -18.06 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
jul(t-Bu)2QM  |
E Param.: -17.90 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
hex-3-yn-2-one  |
E Param.: -17.90 |
 |
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
diethyl fumarate  |
DMSO | E Param.: -17.79 |
|
Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
diethyl 4-nitrobenzylidene malonate  |
E Param.: -17.67 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)  |
DMSO | E Param.: -17.64 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one  |
DMSO | E Param.: -17.42 |
|
Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)  |
DMSO | E Param.: -17.33 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |