Acceptor-Substituted Ethylenes
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
4-phenylbut-3-yn-2-one   |
E Param.: -16.90 |
 |
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
hex-3-yn-2-one  |
E Param.: -17.90 |
|
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
butynone  |
E Param.: -16.60 |
|
Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 |
|
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate  |
E Param.: -23.40 |
 |
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 2-((julolidine-9-yl)methylene)malonate  |
E Param.: -23.80 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6m  |
E Param.: -17.30 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
1,2-diaza-1,3-diene 1e  |
MeOH | E Param.: -14.90 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1f  |
MeOH | E Param.: -15.30 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO)  |
DMSO | E Param.: -19.36 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO)  |
DMSO | E Param.: -19.17 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one  |
DMSO | E Param.: -19.15 |
|
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
cinnamonitrile (in DMSO)  |
DMSO | E Param.: -24.60 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
3-methylcyclopentenone  |
DMSO | E Param.: -28.90 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
2-methylcyclohexenone  |
DMSO | E Param.: -27.50 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
3-methylcyclohexenone  |
DMSO | E Param.: -29.60 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
ethyl 2-methylprop-2-enoate (in DMSO)  |
DMSO | E Param.: -22.77 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl (E)-but-2-enoate (in DMSO)  |
DMSO | E Param.: -23.59 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl cinnamate (in DMSO)  |
DMSO | E Param.: -24.52 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)  |
DMSO | E Param.: -24.69 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
dihydro-2H-pyran-2-one  |
DMSO | E Param.: -21.80 |
|
Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
benzylidenemalononitrile  |
E Param.: -9.42 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(methoxy)benzylidenemalononitrile  |
E Param.: -10.80 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(dimethylamino)benzylidenemalononitrile  |
E Param.: -13.30 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione  |
E Param.: -13.56 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-(p-methoxybenzylidene)-indan-1,3-dione  |
E Param.: -11.32 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-benzylidene-indan-1,3-dione  |
E Param.: -10.11 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
jul-indan-1,3-dione  |
E Param.: -14.68 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
aniBBS  |
E Param.: -10.37 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
dmaBBS  |
E Param.: -12.76 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
julBBS  |
E Param.: -13.84 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
dma(S)BBS  |
E Param.: -10.73 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
jul(S)BBS  |
E Param.: -11.89 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
benzylidene-Meldrum's acid  |
E Param.: -9.15 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
p-(methoxy)benzylidene Meldrum's acid  |
E Param.: -10.28 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
p-(dimethylamino)benzylidene Meldrum's acid  |
E Param.: -12.76 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
jul Meldrum's acid  |
E Param.: -13.97 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
diethyl benzylidene malonate  |
E Param.: -20.55 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-nitrobenzylidene malonate  |
E Param.: -17.67 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-cyano-benzylidene malonate  |
E Param.: -18.06 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 3-chloro-benzylidene malonate  |
E Param.: -18.98 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-methyl-benzylidene malonate  |
E Param.: -21.11 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-methoxy-benzylidene malonate  |
E Param.: -21.47 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-(dimethylamino)benzylidene malonate  |
E Param.: -23.10 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone  |
E Param.: -11.87 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |