Details of Molecule 3-chloro-benzaldehyde (in DMSO)
|Molecule class||Electrophiles » C-Electrophiles » Aldehydes|
The previously reported E = -18.0 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (epoxide ring closure is rate-determining).
J. Am. Chem. Soc. 2011, 133, 8240-8251