Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Details of Molecule 3-chloro-benzaldehyde (in DMSO)

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Aldehydes
Structure image of molecule
Molecule class Electrophiles » C-Electrophiles » Aldehydes
Quality -

The previously reported E = -18.0 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (epoxide ring closure is rate-determining).

Sum formula C7H5ClO
Solvent DMSO
Reference J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m