Details of Molecule benzaldehyde (in DMSO)
For reactivities of structurally related compounds go to:
Electrophiles » C-Electrophiles » Aldehydes
| Structure |
 |
| Molecule class | Electrophiles » C-Electrophiles » Aldehydes |
| Quality |
 |
| Parameters |
E Parameter: -12.90 |
| Comment |
Only 1 reference nucleophile was used to determine the E parameter. Determined from the kinetics of an epoxidation reaction with a carbanion (ArSO2CHCl-) and corrected by the splitting ratio of forward and backward reaction. The previously reported E = -19.5 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at PhCHO (JACS 2011, 133, 8240), in which the epoxide ring closure is rate-determining. |
| Sum formula | C7H6O |
| Solvent | DMSO |
| Reference |
J. Am. Chem. Soc. 2018, 140, 5500-5515 DOI: 10.1021/jacs.8b01657 |