Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Details of Molecule p-nitro-cinnamaldehyde (in DMSO)

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Aldehydes
Structure image of molecule
Molecule class Electrophiles » C-Electrophiles » Aldehydes
Quality -
Parameters
Comment The reported E = 18.19 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (rate-determining epoxide ring closure).
Sum formula C9H7NO3
Solvent DMSO
Reference J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m