Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Cationic Metal-π-Complexes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles
Found 20 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

fc(Ph)CH+
0E Parameter: -2.64
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
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fc(ani)CH+
0E Parameter: -2.90
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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fc(Me)CH+
0E Parameter: -2.57
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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fc2CH+
0E Parameter: -8.54
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)
E Parameter: -14.14
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
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[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)
E Parameter: -14.21
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
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[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)
E Parameter: -14.46
***Organometallics 2012, 31, 2416-2424
DOI: 10.1021/om3000357
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C7H7+-Fe(CO)3
E Parameter: -3.49
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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C7H9+-Fe(CO)3
E Parameter: -9.21
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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C6H7+-Fe(CO)3
E Parameter: -7.76
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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C6H6OMe+-Fe(CO)3
E Parameter: -8.94
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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propyn-1-ylium-Co2(CO)6
E Parameter: -0.84
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1-phenyl-proyn-ylium-Co2(CO)6
E Parameter: -0.97
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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3-phenylpropyn-1-ylium-Co2(CO)6
E Parameter: -1.58
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6
E Parameter: -1.60
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)
E Parameter: -6.19
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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Pd-allyl cation
E Parameter: -10.11
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1,3-diphenylpropyn-1-ylium-Cr(CO)3
E Parameter: 1.07
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1,1,3-triphenylpropyn-1-ylium-Cr(CO)3
E Parameter: -0.25
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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dicarbonyl(cyclopentadienyl)propene-iron(II)
E Parameter: -11.20
***Helv. Chim. Acta 2005, 88, 1754-1768
DOI: 10.1002/hlca.200590137