Electrophiles
Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
---|---|---|---|---|
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -16.84 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -16.25 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -17.42 | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] | |
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one | DMSO | E Param.: -11.68 | Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295 | |
phenyl isothiocyanate | DMSO | E Param.: -18.15 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
p-nitrophenyl isothiocyanate | DMSO | E Param.: -15.89 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
diphenylcarbodiimide | DMSO | E Param.: -20.14 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
carbon disulfide | DMSO | E Param.: -17.70 | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 | |
3-methylcyclohexenone | DMSO | E Param.: -29.60 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
cycloheptenone | DMSO | E Param.: -22.00 | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A | |
indolecarboxylate derived iminium ion | dichloromethane | E Param.: -9.50 | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933 | |
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium | dichloromethane | E Param.: -6.00 | Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864 | |
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium | dichloromethane | E Param.: -7.00 | Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864 | |
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium | dichloromethane | E Param.: -5.90 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-cyanophenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Param.: -6.00 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Param.: -10.60 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-2,2,3-trimethyl-4-oxo-1-((E)-3-(p-tolyl)allylidene)imidazolidin-1-ium | dichloromethane | E Param.: -7.20 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-1-((E)-3-(4-methoxyphenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium | dichloromethane | E Param.: -8.00 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(3-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium | dichloromethane | E Param.: -6.10 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium | dichloromethane | E Param.: -7.30 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
(2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium | dichloromethane | E Param.: -5.90 | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 | |
dibenzo[a,d]tropylium ion | dichloromethane | E Param.: -0.63 | Liebigs Ann. 1995, , 2005-2009 10.1002/jlac.1995199[...] | |
(E)-2-(tert-butyl)-3-(4-methylbenzylidene)-3H-indol-1-ium | dichloromethane | E Param.: -5.06 | Eur. J. Org. Chem. 2016, , 4050-4058 10.1002/ejoc.201600572 | |
9-phenyl-9H-fluoren-9-ylium | dichloromethane | E Param.: 2.41 | Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963 | |
9-(4-methoxyphenyl)-9H-fluoren-9-ylium | dichloromethane | E Param.: 0.85 | Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963 | |
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium | dichloromethane | E Param.: -4.51 | Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963 | |
benzhydrylium ion Ph2CH+ | E Param.: 5.47 | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | ||
ani(Br)2QM | E Param.: -8.63 | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | ||
ani(Ph)2QM | E Param.: -12.18 | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | ||
dma(Ph)2QM | E Param.: -13.39 | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | ||
tol(t-Bu)2QM | E Param.: -15.83 | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | ||
jul(t-Bu)2QM | E Param.: -17.90 | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | ||
(pcp)2CH+ | E Param.: 5.48 | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | ||
pfp(Ph)CH+ | E Param.: 5.20 | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | ||
(fur)2CH+ | E Param.: -1.36 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(ani)2CH+ | E Param.: 0.00 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(tol)2CH+ | E Param.: 3.63 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(pfa)2CH+ | E Param.: -3.14 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(mfa)2CH+ | E Param.: -3.85 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(dpa)2CH+ | E Param.: -4.72 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(mor)2CH+ | E Param.: -5.53 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(mpa)2CH+ | E Param.: -5.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(dma)2CH+ | E Param.: -7.02 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(pyr)2CH+ | E Param.: -7.69 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(thq)2CH+ | E Param.: -8.22 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(ind)2CH+ | E Param.: -8.76 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(jul)2CH+ | E Param.: -9.45 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
(lil)2CH+ | E Param.: -10.04 | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | ||
5-methoxyfuroxano[3,4-d]pyrimidine | E Param.: -8.37 | J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606 | ||
benzylidenemalononitrile | E Param.: -9.42 | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |