Mayr's Database of Reactivity Parameters

Aldehydes

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
benzaldehyde-boron trichloride complex
*

E Param.: 1.12

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
4-chlorobenzaldehyde-boron trichloride complex
*

E Param.: 1.44

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-chloro-benzaldehyde (in DMSO)
*
DMSO

E Param.: -18.03

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
3-fluoro-benzaldehyde (in DMSO)
*
DMSO

E Param.: -18.27

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
3-methoxy-benzaldehyde (in DMSO)
*
DMSO

E Param.: -19.32

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
4-fluoro-benzaldehyde (in DMSO)
*
DMSO

E Param.: -19.42

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
benzaldehyde (in DMSO)
*
DMSO

E Param.: -19.52

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
hexanal (in DMSO)
*
DMSO

E Param.: -18.76

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
butanal (in DMSO)
C4H8O*
DMSO

E Param.: -18.72

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
cinnamaldehyde (in DMSO)
*
DMSO

E Param.: -19.92

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
p-nitro-cinnamaldehyde (in DMSO)
*
DMSO

E Param.: -18.19

*J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m