Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
ethanol (in MeCN)
*
 MeCN

N  Param.: 7.13

sN Param.: 0.71		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
tert-butanol (in MeCN)
*
 MeCN

N  Param.: 5.35

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
50% water/50% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.50

sN Param.: 1.03		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
30% water/70% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 1.65

sN Param.: 0.96		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
10% water/90% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.96

sN Param.: 0.93		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
7% water/93% HFIP (w/w)
*
 water-HFIP mix

N  Param.: 0.34

sN Param.: 0.96		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
5% water/95% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -0.10

sN Param.: 0.97		***J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064