Acceptor-Substituted Ethylenes

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-methylcyclohexenone	DMSO	E Param.: -27.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
cyclohexenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
dihydro-2H-pyran-2-one	DMSO	E Param.: -21.80	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenetetrahydropyran-2-one	DMSO	E Param.: -19.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenedihydrofuranone	DMSO	E Param.: -19.40	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -17.00	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.84	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.25	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -17.42	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -11.68	Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295
3-methylcyclohexenone	DMSO	E Param.: -29.60	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
cycloheptenone	DMSO	E Param.: -22.00	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
ani(Br)2QM		E Param.: -8.63	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
ani(Ph)2QM		E Param.: -12.18	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
dma(Ph)2QM		E Param.: -13.39	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
tol(t-Bu)2QM		E Param.: -15.83	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
jul(t-Bu)2QM		E Param.: -17.90	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
benzylidenemalononitrile		E Param.: -9.42	J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182
p-(methoxy)benzylidenemalononitrile		E Param.: -10.80	J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182
p-(dimethylamino)benzylidenemalononitrile		E Param.: -13.30	J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione		E Param.: -13.56	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
2-(p-methoxybenzylidene)-indan-1,3-dione		E Param.: -11.32	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
2-benzylidene-indan-1,3-dione		E Param.: -10.11	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
jul-indan-1,3-dione		E Param.: -14.68	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
aniBBS		E Param.: -10.37	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
dmaBBS		E Param.: -12.76	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
julBBS		E Param.: -13.84	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
dma(S)BBS		E Param.: -10.73	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
jul(S)BBS		E Param.: -11.89	J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g
benzylidene-Meldrum's acid		E Param.: -9.15	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s
p-(methoxy)benzylidene Meldrum's acid		E Param.: -10.28	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s
p-(dimethylamino)benzylidene Meldrum's acid		E Param.: -12.76	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s
jul Meldrum's acid		E Param.: -13.97	J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s
diethyl benzylidene malonate		E Param.: -20.55	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-nitrobenzylidene malonate		E Param.: -17.67	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-cyano-benzylidene malonate		E Param.: -18.06	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 3-chloro-benzylidene malonate		E Param.: -18.98	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-methyl-benzylidene malonate		E Param.: -21.11	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-methoxy-benzylidene malonate		E Param.: -21.47	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 4-(dimethylamino)benzylidene malonate		E Param.: -23.10	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate		E Param.: -23.40	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
diethyl 2-((julolidine-9-yl)methylene)malonate		E Param.: -23.80	Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone		E Param.: -11.87	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone		E Param.: -16.38	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -17.18	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -16.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -15.03	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.50	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
4-phenylbut-3-yn-2-one		E Param.: -16.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803