Prof. Dr. Konstantin Karaghiosoff - Faculty for Chemistry and Pharmacy

Christin Kirst, PhD - OLED

Forschungsgebiet OLED

  • Synthese fluoreszierender Materialien basierend auf einfachen, funktionalisierten Phosphorverbindungen.
  • Synthese verschiedener Metallkomplexe mit unterschiedlichen Eigenschaften.
  • leichtes Fine-Tuning von chemischen, physikalischen und optischen Eigenschaften der Verbindungen durch Variation der Substituenten am Phosphor.
  • Quantenchemische Berechnungen der jeweiligen Verbindungen zur Ermittlung von Struktur-Eigenschaftsbeziehungen.

Research field OLED

  • synthesis of fluorescent materials based on simple, functionalized phosphorus-containing compounds.
  • synthesis of metal-complexes with varying properties.
  • easy fine-tuning of chemical, physical and optical properties of these compounds through variation of the substituents on phosphorus.
  • quantum-chemical calculations to investigate structure-property-relationships.

christin.kirst@cup.uni-muenchen.de

Publikationen/Publications

C. Kirst, J. Tietze, P. Mayer, H.-C. Böttcher, K. Karaghiosoff, Coinage Metal Complexes of Bis(quinoline-2-ylmethyl)phenylphosphine – Simple Reactions Can Lead to Unprecedented Results, ChemistryOpen 2022, 11, e202100224. DOI 10.1002/open.202100224

C. Kirst, J. Tietze, M. Ebeling, L. Horndasch, K. Karaghiosoff, The Formation of P–C Bonds Utilizing Organozinc Reagents for the Synthesis of Aryl- and Heteroaryl-Dichlorophosphines, J. Org. Chem. 2021, DOI 10.1021/acs.joc.1c01560.

C. Kirst, F. Zoller, T. Bräuniger, P. Mayer, D. Fattakhova-Rohlfing, K. Karaghiosoff, Investigation of structural changes of Cu(I) and Ag(I) complexes utilizing a flexible, yet sterically demanding multidentate phosphine oxide ligand, accepted in Inorg. Chem. DOI: 10.1021/acs.inorgchem.0c03334.

C. Kirst, M. Reichel, K. Karaghiosoff, Coordination complexes of di(2-pyridyl) ketone with copper(I) and their formation in solution and under solvent-free conditions, Inorganica Chim. Acta 2020, 119951-119962. DOI: 10.1016/j.ica.2020.119951.

C. Kirst, K. Karaghiosoff, Copper(I) and silver(I) complexes of bridging bis(quinaldinyl)phenylphosphine oxide ligand, Phosphorus, Sulfur, and Silicon and the Related Elements 2020, 195(11), 918-923. DOI: 10.1080/10426507.2020.1804162.

P. Sanz Camacho, D. McKay, D. M. Dawson, C. Kirst, J. R. Yates, T. F. G. Green, D. B. Cordes, A. M. Z. Slawin, J. D. Woollins, S. E. Ashbrook, Investigating Unusual Homonuclear Intermolecular “Through-Space” J Couplings in Organochalcogen Systems, Inorg. Chem. 2016, 55(21), 10881–10887. DOI: 10.1021/acs.inorgchem.6b01121.

C. Kirst, B. E. Bode, D. B. Cordes, P. S. Nejman, A. M. Z. Slawin, K. Karaghiosoff, J. D. Woollins, Diphosphane 2,2’-binaphtho[1,8-de][1,3,2]- dithiaphosphinine and the easy formation of a stable phosphorus radical cation, Dalton Trans., 2016, 45, 6348-6351. DOI: 10.1039/C6DT00304D.

D. G. Piercey, D. E. Chavez, S. Heimsch, C. Kirst, T. M. Klapötke, J. Stierstorfer, An Energetic N-Oxide and N-Amino Heterocycle and its transformation to 1,2,3,4-Tetrazine-1-oxide, Propellants Explos. Pyrotech., 2015, 40(4), 491-497. DOI: 10.1002/prep.201400224.