S- and Se-Nucleophiles
For reactivities of structurally related compounds go to: Nucleophiles
Found 33 Molecules.
| Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
|---|---|---|---|---|
 dimethylsulfide (in CH2Cl2) | dichloromethane | N Parameter: 12.32 sN Parameter: 0.72 |  | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 dimethylselenide (in CH2Cl2) | dichloromethane | N Parameter: 12.60 sN Parameter: 0.72 |  | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 dibutylsulfide (in CH2Cl2) | dichloromethane | N Parameter: 11.86 sN Parameter: 0.74 | | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 tetrahydrothiophene (in CH2Cl2) | dichloromethane | N Parameter: 13.10 sN Parameter: 0.72 | | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 tetrahydrothiopyran (in CH2Cl2) | dichloromethane | N Parameter: 11.94 sN Parameter: 0.75 | | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 phenylsulfinate (in DMSO) | DMSO | N Parameter: 19.60 sN Parameter: 0.60 | | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 |
 4-nitrothiophenolate (in DMSO) | DMSO | N Parameter: 18.92 sN Parameter: 0.87 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 3,5-bis(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 19.71 sN Parameter: 0.86 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 4-(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 21.30 sN Parameter: 0.86 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 3-(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 21.75 sN Parameter: 0.86 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 3-chlorothiophenolate (in DMSO) | DMSO | N Parameter: 22.50 sN Parameter: 0.78 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 4-bromothiophenolate (in DMSO) | DMSO | N Parameter: 22.80 sN Parameter: 0.78 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 thiophenolate (in DMSO) | DMSO | N Parameter: 23.36 sN Parameter: 0.74 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 4-methylthiophenolate (in DMSO) | DMSO | N Parameter: 24.35 sN Parameter: 0.69 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 naphthalene-2-thiolate (in DMSO) | DMSO | N Parameter: 22.55 sN Parameter: 0.83 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 4-methoxythiophenolate (in DMSO) | DMSO | N Parameter: 24.97 sN Parameter: 0.68 | | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 |
 thiocyanate (in MeCN) | MeCN | N Parameter: 17.94 sN Parameter: 0.60 | | J. Am. Chem. Soc. 2003, 125, 14126-14132 DOI: 10.1021/ja037317u |
 phenylsulfinate (in MeCN) | MeCN | N Parameter: 20.11 sN Parameter: 0.59 | | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 |
 thioacetate (in MeCN) | MeCN | N Parameter: 21.20 sN Parameter: 0.63 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 O-ethyl dithiocarbonate (in MeCN) | MeCN | N Parameter: 19.30 sN Parameter: 0.69 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 O-isopropyl dithiocarbonate (in MeCN) | MeCN | N Parameter: 18.27 sN Parameter: 0.78 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 N,N-dimethyl dithiocarbamate (in MeCN) | MeCN | N Parameter: 20.93 sN Parameter: 0.69 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 pyrrolidin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 22.40 sN Parameter: 0.63 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 piperidin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 23.84 sN Parameter: 0.57 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 4-methylpiperazin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 23.61 sN Parameter: 0.57 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 morpholin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 21.72 sN Parameter: 0.64 | | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j |
 dimethylsulfide (in MeCN) | MeCN | N Parameter: 12.70 sN Parameter: 0.72 | | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 tetrahydrothiophene (in MeCN) | MeCN | N Parameter: 13.30 sN Parameter: 0.72 | | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 |
 SO3(2-) (in water) | water | N Parameter: 16.83 sN Parameter: 0.56 | | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y |
 2-sulfidoacetate (in water) | water | N Parameter: 22.62 sN Parameter: 0.43 | | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y |
 cysteine (dianionic, in water) | water | N Parameter: 23.43 sN Parameter: 0.42 | | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h |
 glutathione GSH(NH3+/S-) | water | N Parameter: 20.97 sN Parameter: 0.56 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 DOI: 10.1002/anie.201909803 |
 phenylsulfinate (in 50W50AN) | water-MeCN mix | N Parameter: 13.75 sN Parameter: 0.68 | | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 |