Nucleophiles
Found 1302 Molecules.
Molecule | Solvent | Reactivity Parameters | Classification | Reference (sort by title or year) |
---|---|---|---|---|
o-nitrophenolate (in DMF) | DMF | N Parameter: 16.65 sN Parameter: 0.70 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
o-nitrophenolate (in DMSO) | DMSO | N Parameter: 15.48 sN Parameter: 0.71 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-nitrophenolate (in DMF) | DMF | N Parameter: 15.05 sN Parameter: 0.80 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-nitrophenolate (in MeCN) | MeCN | N Parameter: 15.14 sN Parameter: 0.82 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
o-nitrophenolate (in MeCN) | MeCN | N Parameter: 15.83 sN Parameter: 0.80 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
cysteine (dianionic, in water) | water | N Parameter: 23.43 sN Parameter: 0.42 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate | MeCN | N Parameter: 6.24 sN Parameter: 1.00 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
potassium trifluoro(furan-2-yl)borate | MeCN | N Parameter: 5.99 sN Parameter: 0.79 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
((dimethylsilyl)methyl)trimethylsilane | dichloromethane | N Parameter: 4.86 sN Parameter: 0.64 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
((methylsilanediyl)bis(methylene))bis(trimethylsilane) | dichloromethane | N Parameter: 4.91 sN Parameter: 0.64 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(1H-inden-1-yl)trimethylsilane (in CH2Cl2) | dichloromethane | N Parameter: -0.10 sN Parameter: 1.05 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1H-inden-1-yl)trimethylstannane (in CH2Cl2) | dichloromethane | N Parameter: 6.68 sN Parameter: 0.81 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1H-inden-1-yl)zinc(II) bromide*LiBr (in DMSO) | DMSO | N Parameter: 15.60 sN Parameter: 0.51 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1H-inden-1-yl)zinc(II) chloride*LiCl (in DMSO) | DMSO | N Parameter: 18.10 sN Parameter: 0.46 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
(1S)-(-)-alpha-pinene | dichloromethane | N Parameter: 0.68 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2,2-diphenylethyl)diethyl(methyl)silane | dichloromethane | N Parameter: -6.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(2,3-dimethylbut-2-enyl)triethylsilane | dichloromethane | N Parameter: 3.15 sN Parameter: 1.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-([1,1'-biphenyl]-4-yl)ethyl)trimethylstannane | 1,2-dichloroethane | N Parameter: -0.80 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(2-methylallyl)benzene | dichloromethane | N Parameter: 0.25 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II) | dichloromethane | N Parameter: 8.45 sN Parameter: 0.83 | Helv. Chim. Acta 2005, 88, 1754-1768 DOI: 10.1002/hlca.200590137 | |
(2-methylallyl)tributylstannane | dichloromethane | N Parameter: 7.48 sN Parameter: 0.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)trichlorosilane | dichloromethane | N Parameter: -0.57 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-methylallyl)trimethylsilane | dichloromethane | N Parameter: 4.41 sN Parameter: 0.96 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)triphenylgermane | dichloromethane | N Parameter: 4.67 sN Parameter: 0.81 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)triphenylsilane | dichloromethane | N Parameter: 4.17 sN Parameter: 0.79 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(2-methylallyl)triphenylstannane | dichloromethane | N Parameter: 5.13 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(2-methylallyl)tris(trimethylsilyl)silane | dichloromethane | N Parameter: 4.63 sN Parameter: 0.87 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
(2R,5S)-5-benzyl-3-methyl-2-(5-methylfuran-2-yl)imidazolidin-4-one | MeCN | N Parameter: 7.39 sN Parameter: 1.00 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(2S,3S)-3-isopropyl-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine | dichloromethane | N Parameter: 14.96 sN Parameter: 0.64 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
(2S,5S)-5-benzyl-2-(tert-butyl)-3-methyl-1-((E)-styryl)imidazolidin-4-one | MeCN | N Parameter: 5.80 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2012, 51, 5739-5742 DOI: 10.1002/anie.201201240 | |
(2S,5S)-5-benzyl-2-(tert-butyl)-3-methylimidazolidin-4-one | MeCN | N Parameter: 5.44 sN Parameter: 1.12 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(2S,5S)-5-benzyl-3-methyl-2-(5-methylfuran-2-yl)imidazolidin-4-one | MeCN | N Parameter: 8.76 sN Parameter: 0.89 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(3,3,4,4,5,5,6,6,7,7,7-undecafluoro)-2-(trimethylsiloxy)hept-1-ene | dichloromethane | N Parameter: -3.52 sN Parameter: 1.17 | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w | |
(3-chlorobenzyl)dimethylsilane | dichloromethane | N Parameter: 1.30 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4,4-dimethylpentyl)trimethylstannane | dichloromethane/MeCN mix | N Parameter: -3.90 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4-(tert-butyl)phenethyl)trimethylstannane | 1,2-dichloroethane | N Parameter: -0.30 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4-Br-C6H4)-(CO)-CH=SMe2 | dichloromethane | N Parameter: 11.95 sN Parameter: 0.76 | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 DOI: 10.1002/anie.200900933 | |
(4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 13.78 sN Parameter: 0.72 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
(4-chlorophenethyl)trimethylstannane | 1,2-dichloroethane | N Parameter: -1.80 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4-chlorophenyl)dimethylsilane | dichloromethane | N Parameter: 3.05 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 15.68 sN Parameter: 0.65 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
(4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 14.48 sN Parameter: 0.71 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
(4-methoxyphenethyl)trimethylstannane | 1,2-dichloroethane | N Parameter: 0.20 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(4-methoxyphenyl)dimethylsilane | dichloromethane | N Parameter: 4.23 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(5-methyl-furan-2-yl) MDA boronate | MeCN | N Parameter: 6.38 sN Parameter: 0.86 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
(5-methyl-furan-2-yl) MIDA boronate | MeCN | N Parameter: 1.84 sN Parameter: 1.26 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
(5-methyl-furan-2-yl) pinacol boronate | MeCN | N Parameter: 2.90 sN Parameter: 0.98 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
(5-methyl-furan-2-yl) trifluoroborate | MeCN | N Parameter: 7.66 sN Parameter: 1.04 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
(5-methyl-furan-2-yl)(1,1,1-tris(methoxy)ethane)borate | MeCN | N Parameter: 12.55 sN Parameter: 0.92 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
(allyl)dicarbonyl(cyclopentadienyl)iron(II) | dichloromethane | N Parameter: 6.78 sN Parameter: 0.95 | Helv. Chim. Acta 2005, 88, 1754-1768 DOI: 10.1002/hlca.200590137 | |
(bis(trimethylsiloxy)amino)styrene | dichloromethane | N Parameter: 4.80 sN Parameter: 0.86 | J. Org. Chem. 2001, 66, 3196-3200 DOI: 10.1021/jo0015927 | |
(C6H5)-(CO)-CH=SMe2 (in DMSO) | DMSO | N Parameter: 13.95 sN Parameter: 0.69 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
(chloromethyl)dimethylsilane | dichloromethane | N Parameter: 0.80 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
(Cp*)2Zr(Me)2 - Dimethyl-bis(pentamethylcyclopentadienyl)zirconium | dichloromethane | N Parameter: 5.49 sN Parameter: 1.06 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
(cyclohexen-1-yl)prolinate (in MeCN) | MeCN | N Parameter: 18.86 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2010, 49, 9526-9529 DOI: 10.1002/anie.201004344 | |
(E)-1-(1,2-diphenylvinyl)piperidine (in MeCN) | MeCN | N Parameter: 9.94 sN Parameter: 0.86 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-1-(1,2-diphenylvinyl)pyrrolidine (in MeCN) | MeCN | N Parameter: 11.66 sN Parameter: 0.82 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-1-(2-(4-methoxyphenyl)-1-phenylvinyl)pyrrolidine (in MeCN) | MeCN | N Parameter: 11.99 sN Parameter: 0.84 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-1-(2-(4-nitrophenyl)-1-phenylvinyl)pyrrolidine (in MeCN) | MeCN | N Parameter: 10.42 sN Parameter: 0.82 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-1-(N-morpholino)propene | dichloromethane | N Parameter: 12.06 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
(E)-1-styryl-2-(triphenylsilyl)pyrrolidine (in CH2Cl2) | dichloromethane | N Parameter: 11.77 sN Parameter: 0.98 | J. Am. Chem. Soc. 2014, 136, 14263-14269 DOI: 10.1021/ja508065e | |
(E)-1-styryl-2-tritylpyrrolidine (in CH2Cl2) | dichloromethane | N Parameter: 10.19 sN Parameter: 1.06 | J. Am. Chem. Soc. 2014, 136, 14263-14269 DOI: 10.1021/ja508065e | |
(E)-1-styrylpyrrolidine (in CH2Cl2) | dichloromethane | N Parameter: 12.26 sN Parameter: 0.93 | J. Am. Chem. Soc. 2014, 136, 14263-14269 DOI: 10.1021/ja508065e | |
(E)-1-styrylpyrrolidine (in MeCN) | MeCN | N Parameter: 13.87 sN Parameter: 0.76 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-13-(ethylthio)-6-styryl-6,12-diazadispiro[4.1.47.25]tridec-12-ene (in MeCN) | MeCN | N Parameter: 7.79 sN Parameter: 0.87 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-2,2,3,5,5-pentamethyl-1-styrylimidazolidin-4-one (in MeCN) | MeCN | N Parameter: 7.10 sN Parameter: 0.82 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-2,2,3,5,5-pentamethyl-1-styrylimidazolidine-4-thione (in MeCN) | MeCN | N Parameter: 6.49 sN Parameter: 0.83 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-2-((1-(but-1-en-1-yl)-2,2,5,5-tetramethyl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in MeCN) | MeCN | N Parameter: 9.23 sN Parameter: 0.74 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-2-methyl-penta-1,3-diene | dichloromethane | N Parameter: 3.09 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(E)-4-(1,2-diphenylvinyl)morpholine (in MeCN) | MeCN | N Parameter: 8.78 sN Parameter: 0.83 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-4-(2-phenyl-2-(pyrrolidin-1-yl)vinyl)benzonitrile (in MeCN) | MeCN | N Parameter: 10.63 sN Parameter: 0.84 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-4-(benzylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2) | dichloromethane | N Parameter: 7.99 sN Parameter: 0.98 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-(benzylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in MeCN) | MeCN | N Parameter: 8.30 sN Parameter: 0.84 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-(3-phenylbut-1-en-1-yl)-2,5-dihydro-1H-imidazole (in MeCN) | MeCN | N Parameter: 7.92 sN Parameter: 0.73 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-(3-phenylprop-1-en-1-yl)-2,5-dihydro-1H-imidazole (in MeCN) | MeCN | N Parameter: 9.64 sN Parameter: 0.70 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2) | dichloromethane | N Parameter: 8.13 sN Parameter: 0.97 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in MeCN) | MeCN | N Parameter: 8.12 sN Parameter: 0.88 | Chem. Eur. J. 2024, 30, e202302764 DOI: 10.1002/chem.202302764 | |
(E)-4-styrylmorpholine | MeCN | N Parameter: 11.66 sN Parameter: 0.83 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-beta-(N-morpholino)styrene | dichloromethane | N Parameter: 10.76 sN Parameter: 0.87 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
(E)-beta-(N-piperidino)styrene (in MeCN) | MeCN | N Parameter: 13.84 sN Parameter: 0.73 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
(E)-but-2-ene | dichloromethane | N Parameter: -2.45 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(E)-but-2-enyltrimethylsilane | dichloromethane | N Parameter: 1.94 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(E)-penta-1,3-diene | dichloromethane | N Parameter: 1.49 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(E)-propenylbenzene | dichloromethane | N Parameter: -0.49 sN Parameter: 1.18 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
(E,E)-2,5-heptadiene | dichloromethane | N Parameter: -0.74 sN Parameter: 0.99 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
(E,E)-hexa-2,4-diene | dichloromethane | N Parameter: 1.17 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(EtO)2P(O)CH(-)CN (in DMSO) | DMSO | N Parameter: 18.57 sN Parameter: 0.66 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
(EtO)2P(O)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 19.23 sN Parameter: 0.65 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
(p-bromophenyl)diazomethane | dichloromethane | N Parameter: 8.87 sN Parameter: 0.82 | J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995 | |
(p-cyanophenyl)diazomethane | dichloromethane | N Parameter: 7.66 sN Parameter: 0.80 | J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995 | |
(p-nitrophenyl)diazomethane | dichloromethane | N Parameter: 7.17 sN Parameter: 0.83 | J. Am. Chem. Soc. 2018, 140, 16758-16772 DOI: 10.1021/jacs.8b09995 | |
(R)-2-(tert-butyl)-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine | dichloromethane | N Parameter: 12.95 sN Parameter: 0.58 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
(R)-2-benzhydryl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine | dichloromethane | N Parameter: 15.30 sN Parameter: 0.55 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
(R)-2-isopropyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine | dichloromethane | N Parameter: 16.50 sN Parameter: 0.48 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
(R)-2-isopropylpyrrolidine | MeCN | N Parameter: 16.44 sN Parameter: 0.71 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-1-(3,5-bis(trifluoromethyl)phenyl)-3-(pyrrolidin-2-ylmethyl)thiourea | MeCN | N Parameter: 14.97 sN Parameter: 0.69 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-1-(3,5-bis(trifluoromethyl)phenyl)-3-(pyrrolidin-2-ylmethyl)urea | MeCN | N Parameter: 17.50 sN Parameter: 0.64 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-1-(pyrrolidin-2-ylmethyl)-1H-imidazole | MeCN | N Parameter: 15.55 sN Parameter: 0.69 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-1-(pyrrolidin-2-ylmethyl)pyrrolidine | MeCN | N Parameter: 18.33 sN Parameter: 0.64 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-(azidodiphenylmethyl)pyrrolidine | MeCN | N Parameter: 9.90 sN Parameter: 1.22 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-(azidomethyl)pyrrolidine | MeCN | N Parameter: 15.43 sN Parameter: 0.73 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-(diphenyl((trimethylsilyl)oxy)methyl)pyrrolidine | MeCN | N Parameter: 12.03 sN Parameter: 0.98 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-(methoxymethyl)pyrrolidine | MeCN | N Parameter: 16.50 sN Parameter: 0.71 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-(pyrrolidin-2-ylmethyl)isoindoline-1,3-dione | MeCN | N Parameter: 15.90 sN Parameter: 0.77 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-benzhydrylpyrrolidine | MeCN | N Parameter: 16.61 sN Parameter: 0.67 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine | dichloromethane | N Parameter: 13.45 sN Parameter: 0.72 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
(S)-3,3-difluoro-2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine (in CH2Cl2) | dichloromethane | N Parameter: 10.83 sN Parameter: 0.80 | ARKIVOC 2024, (4), 202312093 DOI: 10.24820/ark.5550190.p012.093 | |
(S)-3-butyl-1-(pyrrolidin-2-ylmethyl)-1H-imidazol-3-ium trifluoromethanesulfonate | MeCN | N Parameter: 13.57 sN Parameter: 0.53 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-4-benzyl-1,3-oxazolidin-2-one anion (in DMSO) | DMSO | N Parameter: 22.67 sN Parameter: 0.54 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
(S)-4-phenyl-1-(pyrrolidin-2-ylmethyl)-1H-1,2,3-triazole | MeCN | N Parameter: 15.32 sN Parameter: 0.72 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-5-benzyl-2,2,3-trimethylimidazolidin-4-one | MeCN | N Parameter: 6.04 sN Parameter: 0.92 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-diphenyl(pyrrolidin-2-yl)methanol | MeCN | N Parameter: 16.18 sN Parameter: 0.56 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-N,N-dimethyl-1-(pyrrolidin-2-yl)methanamine | MeCN | N Parameter: 17.41 sN Parameter: 0.68 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-N,N-dimethylpyrrolidine-2-carboxamide | MeCN | N Parameter: 17.61 sN Parameter: 0.67 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-N-propylpyrrolidine-2-carboxamide | MeCN | N Parameter: 15.20 sN Parameter: 0.73 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-pyrrolidin-2-ylmethanamine | MeCN | N Parameter: 17.24 sN Parameter: 0.67 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S)-pyrrolidin-2-ylmethanol | MeCN | N Parameter: 16.74 sN Parameter: 0.67 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
(S,E)-2-(diphenyl(trimethylsiloxy)methyl)-1-styrylpyrrolidine | MeCN | N Parameter: 10.56 sN Parameter: 1.01 | Angew. Chem. Int. Ed. 2012, 51, 5739-5742 DOI: 10.1002/anie.201201240 | |
(S,E)-3-benzyl-1-methyl-4-styryl-1,4-diazaspiro[4.4]nonan-2-one | MeCN | N Parameter: 7.92 sN Parameter: 1.07 | Angew. Chem. Int. Ed. 2012, 51, 5739-5742 DOI: 10.1002/anie.201201240 | |
(S,E)-5-benzyl-2,2,3-trimethyl-1-styrylimidazolidin-4-one | MeCN | N Parameter: 7.20 sN Parameter: 1.14 | Angew. Chem. Int. Ed. 2012, 51, 5739-5742 DOI: 10.1002/anie.201201240 | |
(triisopropylsiloxy)ethene | dichloromethane | N Parameter: 3.44 sN Parameter: 0.94 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(trimethylsilyl)diazomethane | dichloromethane | N Parameter: 8.97 sN Parameter: 0.75 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
(tris(trimethylsilyl)siloxy)ethene | dichloromethane | N Parameter: 4.01 sN Parameter: 0.83 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
(Z)-1,2-diphenyl-1-(trimethylsiloxy)ethene (in MeCN) | MeCN | N Parameter: 3.00 sN Parameter: 0.83 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
(Z)-1-(1,3-dimesityl-1H-imidazol-3-ium-2-yl)-2-phenylprop-1-en-1-olate (in DMSO) | DMSO | N Parameter: 14.40 sN Parameter: 0.64 | Angew. Chem. Int. Ed. 2013, 52, 11163-11167 DOI: 10.1002/ange.201303524 | |
(Z)-1-(1,3-dimesityl-1H-imidazol-3-ium-2-yl)-2-phenylprop-1-en-1-olate (in THF) | THF | N Parameter: 15.33 sN Parameter: 0.79 | Angew. Chem. Int. Ed. 2013, 52, 11163-11167 DOI: 10.1002/ange.201303524 | |
(Z)-1-(1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium-2-yl)-2-phenylprop-1-en-1-olate (in THF) | THF | N Parameter: 15.92 sN Parameter: 0.72 | Angew. Chem. Int. Ed. 2013, 52, 11163-11167 DOI: 10.1002/ange.201303524 | |
(Z)-1-(N-morpholino)propene | dichloromethane | N Parameter: 12.26 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
(Z)-1-(triisopropylsiloxy)propen | dichloromethane | N Parameter: 3.87 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(Z)-1-phenyl-1-(trimethylsiloxy)propene (in MeCN) | MeCN | N Parameter: 5.18 sN Parameter: 0.94 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
(Z)-2-phenyl-1-(1,3,4-triphenyl-4H-1,2,4-triazol-1-ium-5-yl)prop-1-en-1-olate (in THF) | THF | N Parameter: 14.40 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2013, 52, 11163-11167 DOI: 10.1002/ange.201303524 | |
(Z)-2-phenyl-1-(1,3,4-triphenyl-4H-1,2,4-triazol-1-ium-5-yl)prop-1-en-1-olate (in THF) | THF | N Parameter: 16.73 sN Parameter: 0.63 | Angew. Chem. Int. Ed. 2013, 52, 11163-11167 DOI: 10.1002/ange.201303524 | |
(Z)-but-2-ene | dichloromethane | N Parameter: -2.44 sN Parameter: 1.09 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
(Z)-but-2-enyltrimethylsilane | dichloromethane | N Parameter: 1.69 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(Z)-penta-1,3-diene | dichloromethane | N Parameter: 0.66 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
(Z)-phenylpropene | dichloromethane | N Parameter: -1.07 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1% water/99% HFIP (w/w) | water-HFIP mix | N Parameter: -1.93 sN Parameter: 1.09 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane | dichloromethane | N Parameter: 3.61 sN Parameter: 0.79 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,1,1,3,3-pentamethyldisiloxane | dichloromethane | N Parameter: 3.12 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,1,3,3-tetramethylguanidine | dichloromethane | N Parameter: 13.58 sN Parameter: 0.77 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
1,1-bis(trimethylsiloxy)propene | dichloromethane | N Parameter: 10.38 sN Parameter: 0.87 | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 | |
1,1-diethoxyethene | dichloromethane | N Parameter: 9.81 sN Parameter: 0.81 | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 | |
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2) | dichloromethane | N Parameter: 6.98 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092 | |
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2) | dichloromethane | N Parameter: 19.31 sN Parameter: 0.46 | Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092 | |
1,1-dimethylhydrazine (in MeCN) | MeCN | N Parameter: 11.72 sN Parameter: 0.73 | Angew. Chem. Int. Ed. 2012, 51, 1353-1356 DOI: 10.1002/anie.201107315 | |
1,1-dimethylhydrazine (in MeCN) | MeCN | N Parameter: 22.41 sN Parameter: 0.45 | Angew. Chem. Int. Ed. 2012, 51, 1353-1356 DOI: 10.1002/anie.201107315 | |
1,1-dimethylsilepane | dichloromethane | N Parameter: -3.10 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,1-dimethylsiletane | dichloromethane | N Parameter: -2.10 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,1-dimethylsilinane | dichloromethane | N Parameter: -2.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,1-dimethylsilolane | dichloromethane | N Parameter: -3.86 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyrimidine (TBN) | dichloromethane | N Parameter: 16.15 sN Parameter: 0.73 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO) | DMSO | N Parameter: 20.08 sN Parameter: 0.74 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2) | dichloromethane | N Parameter: 4.27 sN Parameter: 0.86 | J. Am. Chem. Soc. 2014, 136, 13863-13873 DOI: 10.1021/ja507598y | |
1,2,5-trimethylpyrrole | MeCN | N Parameter: 8.69 sN Parameter: 1.07 | Eur. J. Org. Chem. 2008, , 2369-2374 DOI: 10.1002/ejoc.200800092 | |
1,2-bis(trimethylsiloxy)cyclohexene | dichloromethane | N Parameter: 4.46 sN Parameter: 1.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1,2-dihydronaphthalene (in MeCN) | MeCN | N Parameter: -3.30 sN Parameter: 1.00 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,2-dimethylhydrazine (in MeCN) | MeCN | N Parameter: 16.15 sN Parameter: 0.68 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
1,2-dimethylindole | dichloromethane | N Parameter: 6.54 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
1,3,4-triphenyl-1H-1,2,4-triazol-4-ium-5-ide (in THF) | THF | N Parameter: 14.07 sN Parameter: 0.84 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
1,3,5-trimethyl-2-methylene-1,2-dihydropyridine (in DMSO) | DMSO | N Parameter: 21.16 sN Parameter: 0.59 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1,3,5-trimethylcyclohexa-1,4-diene (in CH2Cl2) | dichloromethane | N Parameter: 4.95 sN Parameter: 0.79 | J. Am. Chem. Soc. 2014, 136, 13863-13873 DOI: 10.1021/ja507598y | |
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN) | MeCN | N Parameter: 19.85 sN Parameter: 0.34 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-Bis(2,6-diisopropylphenyl)-4-methylene-5-(4-(trifluoromethyl)phenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 22.30 sN Parameter: 0.49 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-bis(2,6-diisopropylphenyl)-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 22.80 sN Parameter: 0.60 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-Bis(2,6-diisopropylphenyl)-5-(4-methoxyphenyl)-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 23.55 sN Parameter: 0.56 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-bis(2,6-diisopropylphenyl)-5-methyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 24.86 sN Parameter: 0.52 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF) | THF | N Parameter: 21.36 sN Parameter: 0.42 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF) | THF | N Parameter: 20.78 sN Parameter: 0.61 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-bis(trimethylgermyl)propane (in MeCN) | MeCN | N Parameter: -3.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,3-bis(trimethylsilyl)propane | dichloromethane/MeCN mix | N Parameter: -5.30 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,3-bis(trimethylstannyl)propane (in MeCN) | MeCN | N Parameter: -1.70 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,3-di-tert-butyl-1,3,2-diazaphosphinane (in MeCN) | MeCN | N Parameter: 13.46 sN Parameter: 0.52 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN) | MeCN | N Parameter: 18.74 sN Parameter: 0.47 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN) | MeCN | N Parameter: 25.54 sN Parameter: 0.35 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-di-tert-butyl-2,3-dihydro-1H-benzo[d][1,3,2]diazaphosphole (in MeCN) | MeCN | N Parameter: 20.93 sN Parameter: 0.43 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-diaminopropane (in water) | water | N Parameter: 14.02 sN Parameter: 0.54 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO) | DMSO | N Parameter: 20.63 sN Parameter: 0.76 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
1,3-diethyl-thiobarbiturate anion (in DMSO) | DMSO | N Parameter: 14.90 sN Parameter: 0.80 | J. Org. Chem. 2017, 82, 8476-8488 DOI: 10.1021/acs.joc.7b01223 | |
1,3-Diisopropyl-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 30.25 sN Parameter: 0.54 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
1,3-dimesityl-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 21.72 sN Parameter: 0.45 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN) | MeCN | N Parameter: 17.68 sN Parameter: 0.68 | Angew. Chem. Int. Ed. 2019, 58, 5983-5987 DOI: 10.1002/anie.201901456 | |
1,3-dimesityl-2-methylene-2,3-dihydro-1H-imidazole (in THF) | THF | N Parameter: 17.80 sN Parameter: 0.79 | J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838 | |
1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 23.35 sN Parameter: 0.40 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
1,3-dimethoxybenzene | dichloromethane | N Parameter: 2.48 sN Parameter: 1.09 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1,3-dimethyl-2-methylene-1,2-dihydropyridine (in DMSO) | DMSO | N Parameter: 19.91 sN Parameter: 0.62 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1,3-dimethyl-2-methylene-1,2-dihydropyridine (in MeCN) | MeCN | N Parameter: 19.69 sN Parameter: 0.61 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole | THF | N Parameter: 19.84 sN Parameter: 0.58 | J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838 | |
1,3-dimethyl-2-methylenehexahydropyrimidine (in THF) | THF | N Parameter: 18.68 sN Parameter: 0.63 | J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838 | |
1,3-dimethyl-2-methyleneimidazolidine (in THF) | THF | N Parameter: 18.11 sN Parameter: 0.68 | J. Org. Chem. 2021, 86, 2974-2985 DOI: 10.1021/acs.joc.0c02838 | |
1,3-dimethylbarbiturate anion (in DMSO) | DMSO | N Parameter: 17.46 sN Parameter: 0.72 | J. Org. Chem. 2017, 82, 8476-8488 DOI: 10.1021/acs.joc.7b01223 | |
1,3-dimethylimidazolidin-2-imine | dichloromethane | N Parameter: 12.46 sN Parameter: 0.87 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
1,3-dioxepane | dichloromethane | N Parameter: -3.80 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,3-dioxolane | dichloromethane | N Parameter: -2.86 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,3-oxazolidin-2-one anion (in DMSO) | DMSO | N Parameter: 22.40 sN Parameter: 0.59 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
1,4-cyclohexadiene | dichloromethane | N Parameter: 0.09 sN Parameter: 0.98 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
1,4-cyclohexadiene (in MeCN) | MeCN | N Parameter: 0.35 sN Parameter: 0.98 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,4-dihydronaphthalene | dichloromethane | N Parameter: -0.07 sN Parameter: 1.03 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
1,4-dihydronaphthalene (in MeCN) | MeCN | N Parameter: -2.50 sN Parameter: 1.00 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2) | dichloromethane | N Parameter: 1.88 sN Parameter: 0.96 | J. Am. Chem. Soc. 2014, 136, 13863-13873 DOI: 10.1021/ja507598y | |
1,4-pentadiene | dichloromethane | N Parameter: -2.99 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
1,6-bis(trimethylsilyl)hexane | dichloromethane | N Parameter: -4.70 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1,6-dimethyl-2-methylene-1,2-dihydropyridine (in DMSO) | DMSO | N Parameter: 20.76 sN Parameter: 0.60 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1-((4-chlorobenzylidene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO) | DMSO | N Parameter: 29.02 sN Parameter: 0.49 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO) | DMSO | N Parameter: 26.95 sN Parameter: 0.52 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
1-(1-cyclohexenyl)-4-methylpiperazine | dichloromethane | N Parameter: 12.51 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(2-methyl-4,5-dihydro-1H-imidazol-1-yl)ethanone (in CH2Cl2) | dichloromethane | N Parameter: 10.03 sN Parameter: 0.75 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
1-(3-chloropyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 17.98 sN Parameter: 0.63 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
1-(4-(dimethylamino)pyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 21.61 sN Parameter: 0.58 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
1-(4-(tert-butyl)phenyl)-2-methylene-4,6-diphenyl-1,2-dihydropyridine (in DMSO) | DMSO | N Parameter: 19.36 sN Parameter: 0.68 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1-(benzylideneamino)-2-ethoxy-2-oxoethan-1-ide (in DMSO) | DMSO | N Parameter: 29.10 sN Parameter: 0.50 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
1-(ethoxycarbonyl)-2-oxocyclododecan-1-ide (in DMSO) | DMSO | N Parameter: 20.60 sN Parameter: 0.63 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-(ethoxycarbonyl)-2-oxocycloheptan-1-ide | DMSO | N Parameter: 19.53 sN Parameter: 0.83 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-(ethoxycarbonyl)-2-oxocyclohexan-1-ide (in DMSO) | DMSO | N Parameter: 18.32 sN Parameter: 0.84 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-(ethoxycarbonyl)-2-oxocyclooctan-1-ide (in DMSO) | DMSO | N Parameter: 20.02 sN Parameter: 0.76 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-(ethoxycarbonyl)-2-oxocyclopentan-1-ide (in DMSO) | DMSO | N Parameter: 18.63 sN Parameter: 0.82 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-(isoquinolin-2-ium-2-yl)-2-oxo-2-phenylethan-1-ide (in DMSO) | DMSO | N Parameter: 20.08 sN Parameter: 0.57 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
1-(N-morpholino)cyclohexene | dichloromethane | N Parameter: 11.40 sN Parameter: 0.83 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-(N-morpholino)cyclopentene | dichloromethane | N Parameter: 13.41 sN Parameter: 0.82 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(N-piperidino)cyclohexene | dichloromethane | N Parameter: 13.36 sN Parameter: 0.81 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-(N-piperidino)cyclohexene (in MeCN) | MeCN | N Parameter: 14.02 sN Parameter: 0.76 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
1-(N-piperidino)cyclopentene | dichloromethane | N Parameter: 15.06 sN Parameter: 0.82 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(N-pyrrolidino)cyclohexene | dichloromethane | N Parameter: 14.91 sN Parameter: 0.86 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(N-pyrrolidino)cyclohexene (in MeCN) | MeCN | N Parameter: 16.42 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2010, 49, 9526-9529 DOI: 10.1002/anie.201004344 | |
1-(N-pyrrolidino)cyclopentene | dichloromethane | N Parameter: 15.91 sN Parameter: 0.86 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(p-tolyl)-1-(trimethylsilyl)ethene | dichloromethane | N Parameter: -0.65 sN Parameter: 1.59 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
1-(perfluorophenyl)-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 1.47 sN Parameter: 0.89 | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w | |
1-(phenylethynyl)pyrrolidin-2-one | dichloromethane | N Parameter: 3.12 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2014, 53, 4968-4971 DOI: 10.1002/anie.201402055 | |
1-(phenylmethylamino)cyclohexene | dichloromethane | N Parameter: 10.73 sN Parameter: 0.81 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(phenylmethylamino)cyclopentene | dichloromethane | N Parameter: 12.90 sN Parameter: 0.79 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-(trimethylsiloxy)-3,4-dihydronaphthalene (in MeCN) | MeCN | N Parameter: 5.06 sN Parameter: 0.91 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
1-(trimethylsiloxy)buta-1,3-diene | dichloromethane | N Parameter: 4.60 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1-(trimethylsiloxy)cycloheptene | dichloromethane | N Parameter: 6.62 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1-(trimethylsiloxy)cyclohexene | dichloromethane | N Parameter: 5.21 sN Parameter: 1.00 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-(trimethylsiloxy)cyclooctene | dichloromethane | N Parameter: 6.77 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
1-(trimethylsiloxy)cyclopentene | dichloromethane | N Parameter: 6.57 sN Parameter: 0.93 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-(trimethylsiloxy)cyclopentene (in MeCN) | MeCN | N Parameter: 6.43 sN Parameter: 0.89 | Chem. Asian J. 2012, 7, 1401-1407 DOI: 10.1002/asia.201101046 | |
1-(trimethylsilyl)-imidazole (in MeCN) | MeCN | N Parameter: 11.43 sN Parameter: 0.79 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-(triphenylsiloxy)cyclopentene | dichloromethane | N Parameter: 5.76 sN Parameter: 1.02 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
1-(tris(pentafluorophenyl)siloxy)-cyclopentene | dichloromethane | N Parameter: 1.38 sN Parameter: 0.93 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
1-(tris(trimethylsilyl)siloxy)cyclohexene | dichloromethane | N Parameter: 5.07 sN Parameter: 0.91 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
1-aminopropan-2-ol (in DMSO) | DMSO | N Parameter: 15.47 sN Parameter: 0.65 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
1-benzyl-2-phenyl-4,5-dihydro-1H-imidazole (in CH2Cl2) | dichloromethane | N Parameter: 13.11 sN Parameter: 0.83 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
1-butoxy-1-(t-butyl-dimethylsiloxy)ethene | dichloromethane | N Parameter: 10.32 sN Parameter: 0.79 | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 | |
1-butoxy-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 10.21 sN Parameter: 0.82 | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 | |
1-ethinylcyclohexenyl-Co2(CO)6 | dichloromethane | N Parameter: -0.44 sN Parameter: 1.06 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-ethoxy-2-methyl-1,3-dioxobutan-2-ide (in DMSO) | DMSO | N Parameter: 19.58 sN Parameter: 0.73 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
1-ethoxy-3-(4-nitrophenyl)-1,3-dioxopropan-2-ide (in DMSO) | DMSO | N Parameter: 16.26 sN Parameter: 0.83 | J. Am. Chem. Soc. 2018, 140, 11474-11486 DOI: 10.1021/jacs.8b07147 | |
1-hexene | dichloromethane | N Parameter: -2.77 sN Parameter: 1.41 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
1-mesityl-3-methyl-5-methylene-2,4,6-triphenyl-2,5-dihydropyridin-1-ium-2-ide (in THF) | THF | N Parameter: 26.16 sN Parameter: 0.52 | Angew. Chem. Int. Ed. 2024, , e202318283 DOI: 10.1002/anie.202318283 | |
1-methoxy-2-methyl-1-(trimethylsiloxy)propene | dichloromethane | N Parameter: 9.00 sN Parameter: 0.98 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-methoxy-2-methyl-1-(trimethylsiloxy)propene (in MeCN) | MeCN | N Parameter: 9.11 sN Parameter: 0.88 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
1-methyl uracil anion (in DMSO) | DMSO | N Parameter: 16.36 sN Parameter: 0.69 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
1-methyl uracil anion (in water) | water | N Parameter: 8.54 sN Parameter: 0.77 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine (MeTBD) | dichloromethane | N Parameter: 14.43 sN Parameter: 0.81 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
1-methyl-2-methylene-3-phenyl-1,2-dihydropyridine (in DMSO) | DMSO | N Parameter: 19.41 sN Parameter: 0.61 | Eur. J. Org. Chem. 2024, 27, e202400373 DOI: 10.1002/ejoc.202400373 | |
1-methyl-2-phenylpyrrolidine (in CH2Cl2) | dichloromethane | N Parameter: 16.80 sN Parameter: 0.49 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
1-methyl-2-phenylpyrrolidine (in MeCN) | MeCN | N Parameter: 15.70 sN Parameter: 0.54 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
1-methyl-4-(N-morpholino)tetrahydropyridine | dichloromethane | N Parameter: 12.03 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
1-methyl-4-vinyl-benzene | dichloromethane | N Parameter: 1.70 sN Parameter: 1.06 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-methyl-benzimidazole (in MeCN) | MeCN | N Parameter: 10.37 sN Parameter: 0.82 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-methyl-benzotriazole (in MeCN) | MeCN | N Parameter: 7.77 sN Parameter: 0.76 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-methyl-imidazole (in MeCN) | MeCN | N Parameter: 11.90 sN Parameter: 0.73 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-methyl-imidazole (in water) | water | N Parameter: 9.91 sN Parameter: 0.55 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-methylcyclohexene | dichloromethane | N Parameter: 0.08 sN Parameter: 1.15 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-methylcyclopentene | dichloromethane | N Parameter: 1.18 sN Parameter: 1.17 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
1-methylsiletane | dichloromethane | N Parameter: 2.30 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1-methylsilolane | dichloromethane | N Parameter: 2.20 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1-phenoxy-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 8.23 sN Parameter: 0.81 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-phenyl-1-(trimethylsiloxy)ethene | dichloromethane | N Parameter: 6.22 sN Parameter: 0.96 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
1-phenyl-imidazole (in MeCN) | MeCN | N Parameter: 11.31 sN Parameter: 0.67 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
1-phenyl-N-(phenylmethyl)methanimine (in CH2Cl2) | dichloromethane | N Parameter: 7.90 sN Parameter: 0.76 | Z. Naturforsch. B 2013, 68b, 693-699 DOI: 10.5560/ZNB.2013-3085 | |
1-pyrrolidino-3,4-dihydronaphthalene (in MeCN) | MeCN | N Parameter: 14.09 sN Parameter: 0.66 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
10% ethanol/90% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 5.19 sN Parameter: 0.96 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10% methanol/90% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 5.55 sN Parameter: 0.97 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10% water/90% acetone (v/v) | water-acetone mix | N Parameter: 5.70 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 DOI: 10.1002/anie.200353468 | |
10% water/90% HFIP (w/w) | water-HFIP mix | N Parameter: 0.96 sN Parameter: 0.93 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
10% water/90% MeCN (v/v) | water-MeCN mix | N Parameter: 4.56 sN Parameter: 0.94 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10% water/90%EtOH (v/v) | water-EtOH mix | N Parameter: 7.03 sN Parameter: 0.86 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10% water/90%TFE (v/v) | water-TFE mix | N Parameter: 2.93 sN Parameter: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
10-methyl-9,10-dihydroacridine | dichloromethane | N Parameter: 5.54 sN Parameter: 0.90 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
10-methyl-9,10-dihydroacridine (in MeCN) | MeCN | N Parameter: 4.00 sN Parameter: 0.70 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
1H-indole-5-carboxylic acid | MeCN | N Parameter: 3.97 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
2% water/98% HFIP (w/w) | water-HFIP mix | N Parameter: -1.62 sN Parameter: 1.10 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
2,2,2-trifluoroethanolate (in water) | water | N Parameter: 12.66 sN Parameter: 0.59 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
2,2,2-trifluoroethylamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 10.20 sN Parameter: 0.92 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
2,2,2-trifluoroethylamine (in DMSO) | DMSO | N Parameter: 12.15 sN Parameter: 0.65 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
2,2,2-trifluoroethylamine (in MeCN) | MeCN | N Parameter: 10.13 sN Parameter: 0.75 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
2,2-dimethyl-5-(4-nitrobenzyl)-4,6-dioxo-1,3-dioxan-5-ide (in DMSO) | DMSO | N Parameter: 12.02 sN Parameter: 1.17 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
2,2-dimethylpyrrolidine | MeCN | N Parameter: 13.96 sN Parameter: 0.76 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
2,3,3-trimethyl-but-1-ene | dichloromethane | N Parameter: 0.06 sN Parameter: 1.07 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine | dichloromethane | N Parameter: 16.16 sN Parameter: 0.75 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
2,3,4,6,7,8-hexahydropyrimido[2,1-b][1,3]thiazine | dichloromethane | N Parameter: 14.10 sN Parameter: 0.82 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
2,3,5,6-tetrahydro-1H-imidazo[1,2-a]imidazole (TBO) | dichloromethane | N Parameter: 14.44 sN Parameter: 0.79 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
2,3,5,6-tetrahydroimidazo[2,1-b]thiazole | dichloromethane | N Parameter: 12.98 sN Parameter: 0.81 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
2,3-dihydrobenzo[d]imidazo[2,1-b]thiazole | dichloromethane | N Parameter: 13.42 sN Parameter: 0.73 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
2,3-dihydrofuran | dichloromethane | N Parameter: 4.37 sN Parameter: 0.90 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
2,3-dimethyl-but-1-ene | dichloromethane | N Parameter: 0.65 sN Parameter: 1.00 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2,3-dimethyl-buta-1,3-diene | dichloromethane | N Parameter: 1.17 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2,4,4-trimethyl-pent-1-ene | dichloromethane | N Parameter: 0.79 sN Parameter: 1.07 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2,4,5-trimethyl-1,3-dioxolane (anti) | dichloromethane | N Parameter: -3.00 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2,4,5-trimethyl-1,3-dioxolane (syn) | dichloromethane | N Parameter: -2.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2,4,6-trimethylpyridine (in CH2Cl2) | dichloromethane | N Parameter: 9.34 sN Parameter: 0.71 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2,4,6-trimethylpyridine (in MeCN) | MeCN | N Parameter: 9.39 sN Parameter: 0.60 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2,4,6-trimethylstyrene | dichloromethane | N Parameter: 0.68 sN Parameter: 1.09 | Macromolecules 2005, 38, 33-40 DOI: 10.1021/ma048389o | |
2,4-dimethyl-imidazole (in MeCN) | MeCN | N Parameter: 11.51 sN Parameter: 0.84 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
2,4-dimethyl-imidazole anion (in DMSO) | DMSO | N Parameter: 20.69 sN Parameter: 0.60 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
2,4-dimethyl-penta-1,4-diene | dichloromethane | N Parameter: 0.54 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2,4-dimethylpyrrole | MeCN | N Parameter: 10.67 sN Parameter: 0.91 | Eur. J. Org. Chem. 2008, , 2369-2374 DOI: 10.1002/ejoc.200800092 | |
2,5-dimethyl-benzimidazole (in DMSO) | DMSO | N Parameter: 10.21 sN Parameter: 0.85 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
2,5-dimethyl-hexa-1,5-diene | dichloromethane | N Parameter: 1.14 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2,5-dimethylindole | MeCN | N Parameter: 7.22 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
2,5-dimethylpyrrole | MeCN | N Parameter: 8.01 sN Parameter: 0.96 | Eur. J. Org. Chem. 2008, , 2369-2374 DOI: 10.1002/ejoc.200800092 | |
2,6-dimethyl-hepta-1,6-diene | dichloromethane | N Parameter: 1.69 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2,6-dimethylphenyl isocyanide | dichloromethane | N Parameter: 4.59 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2007, 46, 3563-3566 DOI: 10.1002/anie.200605205 | |
2,6-dimethylpyridine (in CH2Cl2) | dichloromethane | N Parameter: 9.87 sN Parameter: 0.68 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2,6-dimethylpyridine (in MeCN) | MeCN | N Parameter: 9.11 sN Parameter: 0.69 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2,7-dimethylocta-1,7-diene | dichloromethane | N Parameter: 1.58 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-((2,2,5,5-tetramethyl-1-(prop-1-en-1-yl)-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in MeCN) | MeCN | N Parameter: 9.25 sN Parameter: 0.84 | Chem. Commun. 2023, 59, 8091-8084 DOI: 10.1039/d3cc01912h | |
2-((2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in CH2Cl2) | dichloromethane | N Parameter: 7.06 sN Parameter: 1.11 | Chem. Commun. 2023, 59, 8091-8084 DOI: 10.1039/d3cc01912h | |
2-((2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in MeCN) | MeCN | N Parameter: 7.74 sN Parameter: 0.87 | Chem. Commun. 2023, 59, 8091-8084 DOI: 10.1039/d3cc01912h | |
2-(3-chlorophenyl)-1,3-dimethyl-benzimidazoline (in MeCN) | MeCN | N Parameter: 9.38 sN Parameter: 0.71 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-(3-Cl-C6H4)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 27.57 sN Parameter: 0.53 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-(4-(trifluoromethyl)phenyl)-1,3-dimethyl-benzimidazoline (in MeCN) | MeCN | N Parameter: 8.74 sN Parameter: 0.71 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-(4-Br-C6H4)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 27.62 sN Parameter: 0.53 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-(4-CN-C6H4)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 23.64 sN Parameter: 0.65 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-(4-nitrophenyl)-1,3-dimethyl-benzimidazoline (in MeCN) | MeCN | N Parameter: 8.36 sN Parameter: 0.71 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-(4-NO2-C6H4)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 20.00 sN Parameter: 0.71 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-(benzylideneamino)-1-ethoxy-1-oxopropan-2-ide (in DMSO) | DMSO | N Parameter: 30.82 sN Parameter: 0.41 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
2-(bis(tert-butyldimethylsiloxy)amino)propene | dichloromethane | N Parameter: 4.23 sN Parameter: 0.93 | J. Org. Chem. 2001, 66, 3196-3200 DOI: 10.1021/jo0015927 | |
2-(bis(trimethylsiloxy)amino)propene | dichloromethane | N Parameter: 4.76 sN Parameter: 0.86 | J. Org. Chem. 2001, 66, 3196-3200 DOI: 10.1021/jo0015927 | |
2-(diethylamino)-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 27.45 sN Parameter: 0.38 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
2-(naphthylmethyl)quinuclidine (in MeCN) | MeCN | N Parameter: 15.66 sN Parameter: 0.62 | J. Org. Chem. 2009, 74, 7157-7164 DOI: 10.1021/jo901670w | |
2-(p-anisyl)-1,3-dimethyl-benzimidazoline | MeCN | N Parameter: 10.01 sN Parameter: 0.72 | Chem. Asian J. 2009, 4, 1824-1829 DOI: 10.1002/asia.200900322 | |
2-(p-tolyl)-1,3-dimethyl-benzimidazoline | MeCN | N Parameter: 10.14 sN Parameter: 0.70 | Chem. Asian J. 2009, 4, 1824-1829 DOI: 10.1002/asia.200900322 | |
2-(pentamethyldisilyl)propene | dichloromethane | N Parameter: -0.26 sN Parameter: 0.95 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
2-(pyrid-4-yl)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 23.27 sN Parameter: 0.70 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO) | DMSO | N Parameter: 27.77 sN Parameter: 0.47 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
2-(tert.butyldimethylsiloxy)propene | dichloromethane | N Parameter: 5.58 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(tributylsilyl)furan | dichloromethane | N Parameter: 2.37 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(tributylstannyl)furan | dichloromethane | N Parameter: 3.63 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(tributylstannyl)thiophene | dichloromethane | N Parameter: 1.53 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(triethylsilyl)furan | dichloromethane | N Parameter: 2.20 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(trifluoromethyl)pyrrolidine | MeCN | N Parameter: 11.34 sN Parameter: 0.73 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
2-(triisopropylsiloxy)propene | dichloromethane | N Parameter: 5.38 sN Parameter: 0.85 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran | dichloromethane | N Parameter: 10.61 sN Parameter: 0.86 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran (in MeCN) | MeCN | N Parameter: 10.52 sN Parameter: 0.78 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
2-(trimethylsiloxy)buta-1,3-diene | dichloromethane | N Parameter: 4.83 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(trimethylsiloxy)furan | dichloromethane | N Parameter: 7.22 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(trimethylsiloxy)propene | dichloromethane | N Parameter: 5.41 sN Parameter: 0.91 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-(trimethylsilyl)furan | dichloromethane | N Parameter: 2.16 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(trimethylsilyl)propene | dichloromethane | N Parameter: -1.46 sN Parameter: 1.05 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
2-(trimethylsilyl)thiophene | dichloromethane | N Parameter: -0.80 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(triphenylsiloxy)propene | dichloromethane | N Parameter: 4.46 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-(triphenylsilyl)pyrrolidine | MeCN | N Parameter: 14.00 sN Parameter: 0.84 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
2-(tris(pentafluorophenyl)siloxy)-propene | dichloromethane | N Parameter: 0.58 sN Parameter: 0.91 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
2-(tris(trimethylsilyl)siloxy)propene | dichloromethane | N Parameter: 6.04 sN Parameter: 0.82 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
2-(tris(trimethylsilyl)silyl)propene | dichloromethane | N Parameter: -0.31 sN Parameter: 0.99 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
2-Ac super-dmap (in MeCN) | MeCN | N Parameter: 15.39 sN Parameter: 0.60 | Org. Lett. 2011, 13, 530-533 DOI: 10.1021/ol1029589 | |
2-aminobutan-1-ol (in DMSO) | DMSO | N Parameter: 14.39 sN Parameter: 0.67 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
2-benzyl-1,1,3,3-tetramethylguanidine | dichloromethane | N Parameter: 14.36 sN Parameter: 0.79 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
2-benzylpyrrolidine | MeCN | N Parameter: 17.43 sN Parameter: 0.66 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
2-Bn super-dmap (in MeCN) | MeCN | N Parameter: 17.69 sN Parameter: 0.57 | Org. Lett. 2011, 13, 530-533 DOI: 10.1021/ol1029589 | |
2-Bz super-dmap (in MeCN) | MeCN | N Parameter: 14.19 sN Parameter: 0.67 | Org. Lett. 2011, 13, 530-533 DOI: 10.1021/ol1029589 | |
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO) | DMSO | N Parameter: 18.19 sN Parameter: 0.74 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-chloropropene | dichloromethane | N Parameter: -3.65 sN Parameter: 1.97 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2-cyclopropylpropene | dichloromethane | N Parameter: 2.60 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-diazo-1-benzosuberone | dichloromethane | N Parameter: 2.72 sN Parameter: 0.96 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-diazo-1-tetralone | dichloromethane | N Parameter: 3.51 sN Parameter: 0.86 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-diazobenzothiophen-3(2H)-one | dichloromethane | N Parameter: 0.40 sN Parameter: 0.93 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-diazocyclohexanone | dichloromethane | N Parameter: 3.44 sN Parameter: 0.83 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-diazoindan-1-one | dichloromethane | N Parameter: 5.61 sN Parameter: 0.65 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-diazoindandione | dichloromethane | N Parameter: 0.16 sN Parameter: 0.86 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
2-Et super-dmap (in MeCN) | MeCN | N Parameter: 16.81 sN Parameter: 0.60 | Org. Lett. 2011, 13, 530-533 DOI: 10.1021/ol1029589 | |
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 20.51 sN Parameter: 0.64 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 19.15 sN Parameter: 0.59 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 18.81 sN Parameter: 0.59 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-ethoxy-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 26.71 sN Parameter: 0.37 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
2-ethyl-4,5-dimethyl-1,3-dioxolane (anti) | dichloromethane | N Parameter: -2.90 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn) | dichloromethane | N Parameter: -2.40 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO) | DMSO | N Parameter: 19.03 sN Parameter: 0.58 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-formyl-imidazole anion (in DMSO) | DMSO | N Parameter: 16.06 sN Parameter: 0.68 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
2-formyl-imidazole anion (in water) | water | N Parameter: 11.07 sN Parameter: 0.50 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
2-isopropyl-4,5-dimethyl-1,3-dioxolane (ani) | dichloromethane | N Parameter: -4.10 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-isopropyl-4,5-dimethyl-1,3-dioxolane (syn) | dichloromethane | N Parameter: -3.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-Me super-dmap (in MeCN) | MeCN | N Parameter: 16.65 sN Parameter: 0.58 | Org. Lett. 2011, 13, 530-533 DOI: 10.1021/ol1029589 | |
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO) | DMSO | N Parameter: 17.36 sN Parameter: 0.71 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
2-methyl-1,3-dioxolane | dichloromethane | N Parameter: -3.30 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-methyl-1,4,5,6-tetrahydropyrimidine (in CH2Cl2) | dichloromethane | N Parameter: 15.21 sN Parameter: 0.69 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-1,4,5,6-tetrahydropyrimidine (in DMSO) | DMSO | N Parameter: 14.58 sN Parameter: 0.79 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-1,4,5,6-tetrahydropyrimidine (in MeCN) | MeCN | N Parameter: 14.43 sN Parameter: 0.79 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-1-(trimethylsiloxy)propen | dichloromethane | N Parameter: 3.94 sN Parameter: 1.00 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-methyl-4,5-dihydro-1,3-oxazole (in CH2Cl2) | dichloromethane | N Parameter: 9.81 sN Parameter: 0.77 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-4,5-dihydro-1H-imidazole (in CH2Cl2) | dichloromethane | N Parameter: 12.92 sN Parameter: 0.77 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-4,5-dihydro-3H-pyrrole (in CH2Cl2) | dichloromethane | N Parameter: 13.12 sN Parameter: 0.69 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-4,5-dihydrothiazole (in CH2Cl2) | dichloromethane | N Parameter: 10.20 sN Parameter: 0.71 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-methyl-benzimidazole (in DMSO) | DMSO | N Parameter: 10.02 sN Parameter: 0.85 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
2-methyl-but-1-ene | dichloromethane | N Parameter: 1.00 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-methyl-but-2-ene | dichloromethane | N Parameter: 0.65 sN Parameter: 1.17 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-methyl-buta-1,3-diene (isoprene) | dichloromethane | N Parameter: 1.10 sN Parameter: 0.98 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-methyl-imidazole (in MeCN) | MeCN | N Parameter: 11.74 sN Parameter: 0.76 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
2-methyl-imidazole (in water) | water | N Parameter: 9.45 sN Parameter: 0.54 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
2-methyl-imidazole anion (in DMSO) | DMSO | N Parameter: 21.03 sN Parameter: 0.50 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
2-methyl-pent-1-ene | dichloromethane | N Parameter: 0.84 sN Parameter: 1.06 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2-methylfuran | dichloromethane | N Parameter: 3.61 sN Parameter: 1.11 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-methylindole | MeCN | N Parameter: 6.91 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
2-methylpropene (isobutylene) | dichloromethane | N Parameter: 1.11 sN Parameter: 0.98 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
2-methylpyridine (in CH2Cl2) | dichloromethane | N Parameter: 10.52 sN Parameter: 0.78 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2-methylpyridine (in MeCN) | MeCN | N Parameter: 10.98 sN Parameter: 0.66 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
2-methylpyrrolidine (in MeCN) | MeCN | N Parameter: 16.78 sN Parameter: 0.71 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
2-methylthiophene | dichloromethane | N Parameter: 1.35 sN Parameter: 0.99 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
2-oxo-1-(pyridin-1-ium-1-yl)propan-1-ide (in DMSO) | DMSO | N Parameter: 20.24 sN Parameter: 0.60 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
2-oxo-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 19.46 sN Parameter: 0.58 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
2-oxo-2-phenyl-1-(quinolin-1-ium-1-yl)ethan-1-ide (in DMSO) | DMSO | N Parameter: 19.38 sN Parameter: 0.50 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
2-PhCH(-)CO2Et (in DMSO) | DMSO | N Parameter: 27.54 sN Parameter: 0.57 | Eur. J. Org. Chem. 2013, , 4255-4261 DOI: 10.1002/ejoc.201300265 | |
2-phenyl-1,3-dimethyl-benzimidazoline | MeCN | N Parameter: 9.72 sN Parameter: 0.72 | Chem. Asian J. 2009, 4, 1824-1829 DOI: 10.1002/asia.200900322 | |
2-phenyl-1,4,5,6-tetrahydropyrimidine (in CH2Cl2) | dichloromethane | N Parameter: 14.62 sN Parameter: 0.72 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-phenyl-4,5-dihydro-1H-imidazole (in CH2Cl2) | dichloromethane | N Parameter: 12.31 sN Parameter: 0.77 | Eur. J. Org. Chem. 2013, , 3369-3377 DOI: 10.1002/ejoc.201300213 | |
2-phenyl-4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6 | dichloromethane | N Parameter: 1.33 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
2-phenyl-allyltrimethylsilane | dichloromethane | N Parameter: 5.38 sN Parameter: 0.89 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
2-phenyldioxolane | dichloromethane | N Parameter: -0.90 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-phenylethylamine (in water) | water | N Parameter: 13.40 sN Parameter: 0.57 | ChemPlusChem 2015, 80, 1673-1679 DOI: 10.1002/cplu.201500246 | |
2-phenylperoxyacetate (in H2O) | water | N Parameter: 15.63 sN Parameter: 0.56 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
2-propyl-1,3-dioxolane | dichloromethane | N Parameter: -1.06 sN Parameter: 0.81 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
2-pyridone anion (in DMSO) | DMSO | N Parameter: 19.91 sN Parameter: 0.60 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
2-pyridone anion (in MeCN) | MeCN | N Parameter: 20.11 sN Parameter: 0.57 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
2-pyridone anion (in water) | water | N Parameter: 12.47 sN Parameter: 0.52 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
2-sulfidoacetate (in water) | water | N Parameter: 22.62 sN Parameter: 0.43 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
2-thiobarbiturate anion (in DMSO) | DMSO | N Parameter: 14.24 sN Parameter: 0.82 | J. Org. Chem. 2017, 82, 8476-8488 DOI: 10.1021/acs.joc.7b01223 | |
2-tritylpyrrolidine | MeCN | N Parameter: 9.16 sN Parameter: 1.39 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
20% ethanol/80% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 5.77 sN Parameter: 0.92 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
20% methanol/80% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 6.04 sN Parameter: 0.94 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
20% water/80% acetone (v/v) | water-acetone mix | N Parameter: 5.77 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 DOI: 10.1002/anie.200353468 | |
20% water/80% MeCN (v/v) | water-MeCN mix | N Parameter: 5.02 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
20% water/80%EtOH (v/v) | water-EtOH mix | N Parameter: 6.68 sN Parameter: 0.85 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
20% water/80%TFE (v/v) | water-TFE mix | N Parameter: 3.20 sN Parameter: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO) | DMSO | N Parameter: 16.06 sN Parameter: 0.69 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
3% water/97% HFIP (w/w) | water-HFIP mix | N Parameter: -1.19 sN Parameter: 1.08 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
3,3,3-trifluoro-2-(trimethylsiloxy)propene | dichloromethane | N Parameter: -2.94 sN Parameter: 1.11 | Org. Lett. 2012, 14, 3990-3993 DOI: 10.1021/ol301766w | |
3,3-dimethyl-2-(trimethylsiloxy)buten | dichloromethane | N Parameter: 3.78 sN Parameter: 0.79 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
3,5,6,7-tetrahydro-2H-imidazo[2,1-b][1,3]thiazine | dichloromethane | N Parameter: 13.00 sN Parameter: 0.83 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
3,5-bis(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 19.71 sN Parameter: 0.86 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
3,5-dichloroperoxybenzoate (in H2O) | water | N Parameter: 17.93 sN Parameter: 0.50 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
3,5-dinitrobenzoate (in acetone) | acetone | N Parameter: 18.80 sN Parameter: 0.62 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
3,5-dinitrobenzoate (in MeCN) | MeCN | N Parameter: 14.90 sN Parameter: 0.71 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
3-(2,6-dimethoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 23.00 sN Parameter: 0.46 | Org. Lett. 2016, 18, 3566-3569 DOI: 10.1021/acs.orglett.6b01525 | |
3-(4-methoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 20.41 sN Parameter: 0.46 | Org. Lett. 2016, 18, 3566-3569 DOI: 10.1021/acs.orglett.6b01525 | |
3-(tert-butyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 16.54 sN Parameter: 0.47 | Org. Lett. 2016, 18, 3566-3569 DOI: 10.1021/acs.orglett.6b01525 | |
3-(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 21.75 sN Parameter: 0.86 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
3-(trihexylsilyl)cyclopentene | dichloromethane | N Parameter: 1.98 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
3-(trimethylsiloxy)-1H-indene (in MeCN) | MeCN | N Parameter: 7.32 sN Parameter: 0.82 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
3-(trimethylsilyl)cyclopentene | dichloromethane | N Parameter: 1.77 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO) | DMSO | N Parameter: 17.00 sN Parameter: 0.74 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
3-bromo-4-(dimethylamino)pyridine (in MeCN) | MeCN | N Parameter: 12.96 sN Parameter: 0.67 | J. Phys. Chem. A 2012, 116, 8494-8499 DOI: 10.1021/jp3049247 | |
3-chloro-4-methoxyperoxybenzoate (in H2O) | water | N Parameter: 18.56 sN Parameter: 0.48 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
3-chloroperoxybenzoate (in H2O) | water | N Parameter: 18.19 sN Parameter: 0.47 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
3-chlorothiophenolate (in DMSO) | DMSO | N Parameter: 22.50 sN Parameter: 0.78 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
3-diazoindolin-2-one | dichloromethane | N Parameter: 3.16 sN Parameter: 1.03 | Eur. J. Org. Chem. 2023, 26, e202300005 DOI: 10.1002/ejoc.202300005 | |
3-ethyl-2,4-dimethylpyrrole | MeCN | N Parameter: 11.63 sN Parameter: 0.95 | Eur. J. Org. Chem. 2008, , 2369-2374 DOI: 10.1002/ejoc.200800092 | |
3-mesityl-1-methyl-1H-imidazol-3-ium-2-ide (in THF) | THF | N Parameter: 21.50 sN Parameter: 0.45 | Org. Lett. 2016, 18, 3566-3569 DOI: 10.1021/acs.orglett.6b01525 | |
3-methoxythiophene | MeCN | N Parameter: 3.06 sN Parameter: 1.19 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
3-methyl-1,4-pentadiene | dichloromethane | N Parameter: -3.08 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
3-methyl-2,4-dioxotetrahydro-2H-pyran-3-ide (in DMSO) | DMSO | N Parameter: 14.46 sN Parameter: 0.91 | Eur. J. Org. Chem. 2015, , 7594-7601 DOI: 10.1002/ejoc.201501107 | |
3-methyl-2-(trimethylsiloxy)but-1-ene | dichloromethane | N Parameter: 5.41 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
3-methylanisole | dichloromethane | N Parameter: 0.13 sN Parameter: 1.27 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
3-methylpyridine (in CH2Cl2) | dichloromethane | N Parameter: 10.90 sN Parameter: 0.93 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
3-methylpyridine (in MeCN) | MeCN | N Parameter: 11.50 sN Parameter: 0.80 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
3-propylcyclopentene | dichloromethane | N Parameter: -0.88 sN Parameter: 0.94 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
3-pyrrolidino-1H-indene (in MeCN) | MeCN | N Parameter: 15.27 sN Parameter: 0.93 | Synthesis 2019, 51, 1157-1170 DOI: 10.1055/s-0037-1611634 | |
30% water/70% HFIP (w/w) | water-HFIP mix | N Parameter: 1.65 sN Parameter: 0.96 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
33% ethanol/67% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 6.06 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
33% methanol/67% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 6.38 sN Parameter: 0.92 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
33% water/67% MeCN (v/v) | water-MeCN mix | N Parameter: 5.02 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2) | dichloromethane | N Parameter: -0.64 sN Parameter: 1.10 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
4,4-dimethyl-glutarimide anion (in DMSO) | DMSO | N Parameter: 17.52 sN Parameter: 0.63 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
4,5-dimethyl-1,3-dioxolane (anti) | dichloromethane | N Parameter: -2.40 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
4,5-dimethyl-2-vinyl-1,3-dioxolane | dichloromethane | N Parameter: -2.60 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
4-(2-(fluorodiphenylmethyl)pyrrolidin-1-yl)pyridine | dichloromethane | N Parameter: 14.57 sN Parameter: 0.75 | Eur. J. Org. Chem. 2014, , 1202-1211 DOI: 10.1002/ejoc.201301730 | |
4-(bis(trimethylsiloxy)amino)pent-4-enoic acid methyl ester | dichloromethane | N Parameter: 3.84 sN Parameter: 0.87 | J. Org. Chem. 2001, 66, 3196-3200 DOI: 10.1021/jo0015927 | |
4-(dimethylamino)pyridine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.20 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-(dimethylamino)pyridine (in CH2Cl2) | dichloromethane | N Parameter: 15.80 sN Parameter: 0.66 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-(dimethylamino)pyridine (in DMF) | DMF | N Parameter: 14.90 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-(dimethylamino)pyridine (in DMSO) | DMSO | N Parameter: 14.80 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-(dimethylamino)pyridine (in H2O) | water | N Parameter: 13.19 sN Parameter: 0.56 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-(dimethylamino)pyridine (in MeCN) | MeCN | N Parameter: 15.51 sN Parameter: 0.62 | J. Phys. Chem. A 2012, 116, 8494-8499 DOI: 10.1021/jp3049247 | |
4-(dimethylamino)pyridine (in THF) | THF | N Parameter: 15.90 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
4-(morpholino)pyridine (in CH2Cl2) | dichloromethane | N Parameter: 14.59 sN Parameter: 0.69 | Eur. J. Org. Chem. 2016, , 4050-4058 DOI: 10.1002/ejoc.201600572 | |
4-(morpholino)pyridine (in MeCN) | MeCN | N Parameter: 14.80 sN Parameter: 0.63 | J. Phys. Chem. A 2012, 116, 8494-8499 DOI: 10.1021/jp3049247 | |
4-(trifluoromethyl)thiophenolate (in DMSO) | DMSO | N Parameter: 21.30 sN Parameter: 0.86 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)5(PPh3) | dichloromethane | N Parameter: -0.76 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6 | dichloromethane | N Parameter: -1.11 sN Parameter: 0.92 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
4-acetamido-pyridine (in MeCN) | MeCN | N Parameter: 13.24 sN Parameter: 0.67 | J. Phys. Chem. A 2012, 116, 8494-8499 DOI: 10.1021/jp3049247 | |
4-amino-3,5-dibromo-pyridine (in MeCN) | MeCN | N Parameter: 11.11 sN Parameter: 0.75 | J. Phys. Chem. A 2012, 116, 8494-8499 DOI: 10.1021/jp3049247 | |
4-aminopyridine (in CH2Cl2) | dichloromethane | N Parameter: 15.20 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-aminopyridine (in H2O) | water | N Parameter: 12.19 sN Parameter: 0.66 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-bromothiophenolate (in DMSO) | DMSO | N Parameter: 22.80 sN Parameter: 0.78 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
4-chloroaniline (in MeCN) | MeCN | N Parameter: 12.92 sN Parameter: 0.60 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
4-chloropyridine (in CH2Cl2) | dichloromethane | N Parameter: 11.70 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-chloropyridine (in H2O) | water | N Parameter: 10.50 sN Parameter: 0.73 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-cyanophenyl isocyanide | dichloromethane | N Parameter: 3.57 sN Parameter: 0.72 | Angew. Chem. Int. Ed. 2007, 46, 3563-3566 DOI: 10.1002/anie.200605205 | |
4-fluoroperoxybenzoate (in H2O) | water | N Parameter: 17.99 sN Parameter: 0.47 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
4-formyl-imidazole anion (in DMSO) | DMSO | N Parameter: 16.40 sN Parameter: 0.67 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
4-methoxy-indole | MeCN | N Parameter: 5.41 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
4-methoxyaniline (in MeCN) | MeCN | N Parameter: 13.42 sN Parameter: 0.73 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
4-methoxyaniline (in water) | water | N Parameter: 14.28 sN Parameter: 0.68 | ChemPlusChem 2015, 80, 1673-1679 DOI: 10.1002/cplu.201500246 | |
4-methoxyperoxybenzoate (in H2O) | water | N Parameter: 17.84 sN Parameter: 0.46 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
4-methoxypyridine (in CH2Cl2) | dichloromethane | N Parameter: 13.70 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-methoxypyridine (in H2O) | water | N Parameter: 11.44 sN Parameter: 0.68 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-methoxythiophenolate (in DMSO) | DMSO | N Parameter: 24.97 sN Parameter: 0.68 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
4-methyl-2,5-heptadiene | dichloromethane | N Parameter: -0.73 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
4-methyl-5-(trimethylsiloxy)-2,3-dihydrofuran | dichloromethane | N Parameter: 11.50 sN Parameter: 0.91 | Eur. J. Org. Chem. 2004, , 2791-2796 DOI: 10.1002/ejoc.200400134 | |
4-methyl-imidazole (in MeCN) | MeCN | N Parameter: 11.79 sN Parameter: 0.77 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
4-methyl-imidazole anion (in DMSO) | DMSO | N Parameter: 21.29 sN Parameter: 0.51 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
4-methyl-N-(2-phenylethynyl)-N-(phenylmethyl)benzenesulfonamide | dichloromethane | N Parameter: 3.85 sN Parameter: 0.84 | Angew. Chem. Int. Ed. 2014, 53, 4968-4971 DOI: 10.1002/anie.201402055 | |
4-methyl-penta-1,3-diene | dichloromethane | N Parameter: 2.60 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
4-methyl-quinoline alias lepidine (in MeCN) | MeCN | N Parameter: 11.60 sN Parameter: 0.62 | J. Org. Chem. 2009, 74, 7157-7164 DOI: 10.1021/jo901670w | |
4-methylpiperazin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 23.61 sN Parameter: 0.57 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
4-methylpyridine (in CH2Cl2) | dichloromethane | N Parameter: 13.70 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-methylpyridine (in H2O) | water | N Parameter: 11.10 sN Parameter: 0.75 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-methylthiophenolate (in DMSO) | DMSO | N Parameter: 24.35 sN Parameter: 0.69 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
4-nitro-imidazole anion (in DMSO) | DMSO | N Parameter: 14.81 sN Parameter: 0.71 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
4-nitro-imidazole anion (in water) | water | N Parameter: 11.37 sN Parameter: 0.53 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
4-nitroperoxybenzoate (in H2O) | water | N Parameter: 17.43 sN Parameter: 0.50 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
4-nitrothiophenolate (in DMSO) | DMSO | N Parameter: 18.92 sN Parameter: 0.87 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
4-pyridone anion (in DMSO) | DMSO | N Parameter: 18.97 sN Parameter: 0.62 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
4-pyridone anion (in MeCN) | MeCN | N Parameter: 20.22 sN Parameter: 0.49 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
4-pyridone anion (in water) | water | N Parameter: 14.76 sN Parameter: 0.48 | J. Am. Chem. Soc. 2010, 132, 15380-15389 DOI: 10.1021/ja106962u | |
4-pyrrolidinopyridine (in CH2Cl2) | dichloromethane | N Parameter: 15.90 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-pyrrolidinopyridine (in H2O) | water | N Parameter: 12.39 sN Parameter: 0.66 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
4-pyrrolidinopyridine (in MeCN) | MeCN | N Parameter: 14.99 sN Parameter: 0.69 | Chem. Eur. J. 2013, 19, 6435-6442 DOI: 10.1002/chem.201204452 | |
40% water/60%EtOH (v/v) | water-EtOH mix | N Parameter: 6.28 sN Parameter: 0.87 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
40% water/60%TFE (v/v) | water-TFE mix | N Parameter: 3.42 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
5% water/95% HFIP (w/w) | water-HFIP mix | N Parameter: -0.10 sN Parameter: 0.97 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
5,6-dimethyl-benzimidazole (in DMSO) | DMSO | N Parameter: 11.08 sN Parameter: 0.71 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
5-(4-(dimethylamino)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide | MeCN | N Parameter: 7.15 sN Parameter: 0.81 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-(4-(dimethylamino)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO) | DMSO | N Parameter: 14.48 sN Parameter: 0.86 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-(4-(methoxy)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide | MeCN | N Parameter: 6.21 sN Parameter: 0.68 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-(4-(methoxy)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO) | DMSO | N Parameter: 15.13 sN Parameter: 0.75 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-(4-cyanobenzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO) | DMSO | N Parameter: 13.79 sN Parameter: 0.86 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-(tert-Butyl)-1,3-diisopropyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF) | THF | N Parameter: 31.92 sN Parameter: 0.52 | Angew. Chem. Int. Ed. 2023, 62, e202309790 DOI: 10.1002/anie.202309790 | |
5-(trimethylsiloxy)-2,3-dihydrofuran | dichloromethane | N Parameter: 12.56 sN Parameter: 0.70 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
5-(trimethylsiloxy)-2,3-dihydrofuran (in MeCN) | MeCN | N Parameter: 12.34 sN Parameter: 0.72 | J. Am. Chem. Soc. 2013, 135, 6579-6587 DOI: 10.1021/ja401106x | |
5-(triphenylsiloxy)-2,3-dihydrofuran | dichloromethane | N Parameter: 11.28 sN Parameter: 0.91 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
5-(tris(pentafluorophenyl)siloxy)-2,3-dihydrofuran | dichloromethane | N Parameter: 8.16 sN Parameter: 0.67 | Eur. J. Org. Chem. 2005, , 1760-1764 DOI: 10.1002/ejoc.200400706 | |
5-amino-indole | MeCN | N Parameter: 7.22 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-benzyl-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide | MeCN | N Parameter: 5.51 sN Parameter: 0.70 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-benzyl-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO) | DMSO | N Parameter: 15.02 sN Parameter: 0.75 | Chem. Eur. J. 2014, 20, 11069-11077 DOI: 10.1002/chem.201403161 | |
5-bromo-indole | MeCN | N Parameter: 4.38 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-chloro-2-methylindole | MeCN | N Parameter: 6.08 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-chloro-indole | MeCN | N Parameter: 4.42 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-cyano-indole | MeCN | N Parameter: 2.83 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-hydroxy-indole | MeCN | N Parameter: 6.44 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-methoxy-2-methylindole | MeCN | N Parameter: 7.26 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-methoxy-benzimidazole (in DMSO) | DMSO | N Parameter: 11.00 sN Parameter: 0.71 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
5-methoxy-indole | dichloromethane | N Parameter: 6.22 sN Parameter: 1.12 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
5-methyl-benzimidazole (in DMSO) | DMSO | N Parameter: 10.69 sN Parameter: 0.79 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
5-methyl-indole | MeCN | N Parameter: 6.00 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
50% ethanol/50% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 6.37 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
50% methanol/50% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 6.67 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
50% water/50% HFIP (w/w) | water-HFIP mix | N Parameter: 1.50 sN Parameter: 1.03 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
50% water/50% MeCN (v/v) | water-MeCN mix | N Parameter: 5.05 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
50% water/50%EtOH (v/v) | water-EtOH mix | N Parameter: 5.96 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
50% water/50%TFE (v/v) | water-TFE mix | N Parameter: 3.57 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
6,6-dimethylfulvene | MeCN | N Parameter: 3.93 sN Parameter: 0.88 | Eur. J. Org. Chem. 2009, , 1202-1206 DOI: 10.1002/ejoc.200801099 | |
6-(4-dimethylamino-phenyl)fulvene | MeCN | N Parameter: 6.72 sN Parameter: 0.87 | Eur. J. Org. Chem. 2009, , 1202-1206 DOI: 10.1002/ejoc.200801099 | |
6-(julolidin-9-yl)fulvene | MeCN | N Parameter: 7.79 sN Parameter: 1.06 | Eur. J. Org. Chem. 2009, , 1202-1206 DOI: 10.1002/ejoc.200801099 | |
6-methoxy-quinoline (in MeCN) | MeCN | N Parameter: 10.86 sN Parameter: 0.66 | J. Org. Chem. 2009, 74, 7157-7164 DOI: 10.1021/jo901670w | |
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2) | dichloromethane | N Parameter: 4.67 sN Parameter: 0.92 | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 | |
60% water/40%EtOH (v/v) | water-EtOH mix | N Parameter: 5.81 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
60% water/40%TFE (v/v) | water-TFE mix | N Parameter: 3.77 sN Parameter: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
67% ethanol/33% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 6.74 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
67% methanol/33% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 7.01 sN Parameter: 0.91 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
67% water/33% MeCN (v/v) | water-MeCN mix | N Parameter: 5.05 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
7% water/93% HFIP (w/w) | water-HFIP mix | N Parameter: 0.34 sN Parameter: 0.96 | J. Phys. Org. Chem. 2013, 26, 59-63 DOI: 10.1002/poc.3064 | |
7-azaindole | MeCN | N Parameter: 3.87 sN Parameter: 1.10 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
80% ethanol/20% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 6.94 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
80% methanol/20% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 7.20 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
80% water/20% MeCN (v/v) | water-MeCN mix | N Parameter: 5.04 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
80% water/20%EtOH (v/v) | water-EtOH mix | N Parameter: 5.54 sN Parameter: 0.94 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
80% water/20%TFE (v/v) | water-TFE mix | N Parameter: 4.78 sN Parameter: 0.83 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
9,10-dihydroanthracene | dichloromethane | N Parameter: -0.86 sN Parameter: 0.92 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
9-methyl guanine anion (in water) | water | N Parameter: 10.77 sN Parameter: 0.65 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
90% water/10%EtOH (v/v) | water-EtOH mix | N Parameter: 5.38 sN Parameter: 0.91 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
90% water/10%TFE (v/v) | water-TFE mix | N Parameter: 5.04 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
91% ethanol/9% MeCN (v/v) | EtOH-MeCN mix | N Parameter: 7.10 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
91% methanol/9% MeCN (v/v) | MeOH-MeCN mix | N Parameter: 7.45 sN Parameter: 0.87 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
91% n-propanol/9% MeCN (v/v) | nPrOH-MeCN mix | N Parameter: 7.05 sN Parameter: 0.80 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
91% propan-2-ol/9% MeCN (v/v) | iPrOH-MeCN mix | N Parameter: 6.49 sN Parameter: 0.96 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
91% water/9% MeCN (v/v) | water-MeCN mix | N Parameter: 5.16 sN Parameter: 0.91 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
acetate (in 80A20W) | aq acetone | N Parameter: 12.50 sN Parameter: 0.60 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
acetate (in 90A10W) | aq acetone | N Parameter: 12.71 sN Parameter: 0.68 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
acetate (in MeCN) | MeCN | N Parameter: 16.90 sN Parameter: 0.75 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
acetonitrile (in MeCN) | MeCN | N Parameter: 2.23 sN Parameter: 0.84 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
adenine anion (in DMSO) | DMSO | N Parameter: 18.00 sN Parameter: 0.55 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
adenine anion (in water) | water | N Parameter: 10.93 sN Parameter: 0.62 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
alanine (anionic, in water) | water | N Parameter: 13.01 sN Parameter: 0.58 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
allyl-tert.butyl-dimethylsilane | dichloromethane | N Parameter: 1.80 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allylamine (in MeCN) | MeCN | N Parameter: 14.37 sN Parameter: 0.66 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
allylamine (in water) | water | N Parameter: 13.21 sN Parameter: 0.54 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
allylbenzene | dichloromethane | N Parameter: -4.12 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
allylchlorodimethylsilane | dichloromethane | N Parameter: -0.57 sN Parameter: 1.06 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
allyltri-n-butylsilane | dichloromethane | N Parameter: 2.09 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltributylstannane | dichloromethane | N Parameter: 5.46 sN Parameter: 0.89 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyltriethylsilane | dichloromethane | N Parameter: 1.93 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltrihexylsilane | dichloromethane | N Parameter: 2.11 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltriisopropylsilane | dichloromethane | N Parameter: 2.04 sN Parameter: 0.95 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltrimethylsilane | dichloromethane | N Parameter: 1.68 sN Parameter: 1.00 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
allyltriphenylgermane | dichloromethane | N Parameter: 1.20 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
allyltriphenylsilane | dichloromethane | N Parameter: -0.13 sN Parameter: 1.21 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyltriphenylstannane | dichloromethane | N Parameter: 3.09 sN Parameter: 0.90 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
allyltris(trimethylsilyl)silane | dichloromethane | N Parameter: 1.95 sN Parameter: 0.98 | Org. Lett. 2010, 12, 5206-5209 DOI: 10.1021/ol102220e | |
alpha-(N-morpholino)styrene | dichloromethane | N Parameter: 9.96 sN Parameter: 0.79 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
alpha-(N-morpholino)styrene (in MeCN) | MeCN | N Parameter: 10.30 sN Parameter: 0.80 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
alpha-(N-piperidino)styrene (in MeCN) | MeCN | N Parameter: 11.60 sN Parameter: 0.80 | Chem. Eur. J. 2018, 24, 5901-5910 DOI: 10.1002/chem.201705962 | |
alpha-(pentamethyldisilyl)styrene | dichloromethane | N Parameter: 0.61 sN Parameter: 1.01 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
alpha-(trimethylsilyl)styrene | dichloromethane | N Parameter: -1.13 sN Parameter: 1.46 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
alpha-methylstyrene | dichloromethane | N Parameter: 2.35 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
ammonia (in MeCN) | MeCN | N Parameter: 11.39 sN Parameter: 0.69 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
ammonia (in water) | water | N Parameter: 9.48 sN Parameter: 0.59 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
aniline (in MeCN) | MeCN | N Parameter: 12.64 sN Parameter: 0.68 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
aniline (in water) | water | N Parameter: 12.99 sN Parameter: 0.73 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
anion of (3-nitrophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.75 sN Parameter: 0.71 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of (3-nitrophenyl)nitromethane (in DMSO) | DMSO | N Parameter: 18.06 sN Parameter: 0.71 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (3-nitrophenyl)nitromethane (in water) | water | N Parameter: 14.25 sN Parameter: 0.46 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (4-CF3-C6H4)CH2SO2Ph (in DMSO) | DMSO | N Parameter: 24.30 sN Parameter: 0.51 | Org. Biomol. Chem. 2008, 6, 3052-3058 DOI: 10.1039/b805604h | |
anion of (4-CN-C6H4)CH2SO2Ph (in DMSO) | DMSO | N Parameter: 22.60 sN Parameter: 0.57 | Org. Biomol. Chem. 2008, 6, 3052-3058 DOI: 10.1039/b805604h | |
anion of (4-cyanophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.92 sN Parameter: 0.74 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of (4-cyanophenyl)nitromethane (in DMSO) | DMSO | N Parameter: 16.96 sN Parameter: 0.73 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (4-cyanophenyl)nitromethane (in water) | water | N Parameter: 13.23 sN Parameter: 0.52 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (4-nitrophenyl)nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.05 sN Parameter: 0.72 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of (4-nitrophenyl)nitromethane (in DMSO) | DMSO | N Parameter: 16.29 sN Parameter: 0.75 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (4-nitrophenyl)nitromethane (in water) | water | N Parameter: 13.58 sN Parameter: 0.52 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of (4-NO2-C6H4)CH2SO2Ph (in DMSO) | DMSO | N Parameter: 18.50 sN Parameter: 0.75 | Org. Biomol. Chem. 2008, 6, 3052-3058 DOI: 10.1039/b805604h | |
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN) | MeCN | N Parameter: 19.90 sN Parameter: 0.66 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
anion of (benzylsulfonyl)benzene (in DMSO) | DMSO | N Parameter: 25.77 sN Parameter: 0.56 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO) | DMSO | N Parameter: 15.07 sN Parameter: 0.79 | Eur. J. Org. Chem. 2017, , 1196-1202 DOI: 10.1002/ejoc.201601513 | |
anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO) | DMSO | N Parameter: 14.99 sN Parameter: 0.83 | Eur. J. Org. Chem. 2017, , 1196-1202 DOI: 10.1002/ejoc.201601513 | |
anion of 1,2-diphenylethanone (in DMSO) | DMSO | N Parameter: 23.15 sN Parameter: 0.60 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 1,3-diphenylpropane-1,3-dione (in DMSO) | DMSO | N Parameter: 17.46 sN Parameter: 0.65 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 1-phenyl-2-(phenylsulfonyl)ethanone (in DMSO) | DMSO | N Parameter: 17.19 sN Parameter: 0.56 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 1-phenylbutane-1,3-dione (in DMSO) | DMSO | N Parameter: 16.03 sN Parameter: 0.86 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 1-phenylpropan-2-one (in DMSO) | DMSO | N Parameter: 24.99 sN Parameter: 0.60 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 2-(4-CN-C6H4)propionitrile (in DMSO) | DMSO | N Parameter: 25.35 sN Parameter: 0.56 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 2-(4-NO2-C6H4)propionitrile (in DMSO) | DMSO | N Parameter: 19.61 sN Parameter: 0.60 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 2-nitro-1-phenylethan-1-one (in DMSO) | DMSO | N Parameter: 13.91 sN Parameter: 0.76 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 2-nitropropane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 12.20 sN Parameter: 0.71 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of 2-nitropropane (in DMSO) | DMSO | N Parameter: 20.61 sN Parameter: 0.69 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of 2-nitropropane (in water) | water | N Parameter: 10.69 sN Parameter: 0.56 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO) | DMSO | N Parameter: 15.97 sN Parameter: 0.72 | Eur. J. Org. Chem. 2017, , 1196-1202 DOI: 10.1002/ejoc.201601513 | |
anion of 2-phenyl-propionitrile (in DMSO) | DMSO | N Parameter: 28.95 sN Parameter: 0.58 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 2-phenylmalononitrile (in DMSO) | DMSO | N Parameter: 15.58 sN Parameter: 1.00 | Eur. J. Org. Chem. 2017, , 1196-1202 DOI: 10.1002/ejoc.201601513 | |
anion of 3-methyl acetylacetone (in DMSO) | DMSO | N Parameter: 18.38 sN Parameter: 0.72 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of 3-methyl acetylacetone (in water) | water | N Parameter: 14.33 sN Parameter: 0.69 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of 3-oxo-3-phenylpropanenitrile (in DMSO) | DMSO | N Parameter: 16.55 sN Parameter: 0.78 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 20.72 sN Parameter: 0.58 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO) | DMSO | N Parameter: 17.33 sN Parameter: 0.74 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN) | MeCN | N Parameter: 16.15 sN Parameter: 0.99 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
anion of 4-(trifluoromethyl)benzyl-CN (in DMSO) | DMSO | N Parameter: 27.28 sN Parameter: 0.50 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 19.49 sN Parameter: 0.63 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO) | DMSO | N Parameter: 16.28 sN Parameter: 0.75 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN) | MeCN | N Parameter: 15.62 sN Parameter: 0.99 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
anion of 4-cyanobenzyl-CN (in DMSO) | DMSO | N Parameter: 25.11 sN Parameter: 0.54 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO) | DMSO | N Parameter: 19.35 sN Parameter: 0.67 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.24 sN Parameter: 0.66 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO) | DMSO | N Parameter: 14.49 sN Parameter: 0.86 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of 4-nitrobenzyl-CN (in DMSO) | DMSO | N Parameter: 19.67 sN Parameter: 0.68 | J. Org. Chem. 2009, 74, 75-81 DOI: 10.1021/jo802241x | |
anion of 4-nitrobenzyl-CN (in MeCN) | MeCN | N Parameter: 20.10 sN Parameter: 0.71 | J. Am. Chem. Soc. 2020, 142, 8383-8402 DOI: 10.1021/jacs.0c01960 | |
anion of 5-(p-anisyl) Meldrum's acid (in DMSO) | DMSO | N Parameter: 12.35 sN Parameter: 0.90 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of 5-phenyl Meldrum's acid (in DMSO) | DMSO | N Parameter: 11.54 sN Parameter: 0.95 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of acetylacetone (in DMSO) | DMSO | N Parameter: 17.64 sN Parameter: 0.73 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of acetylacetone (in water) | water | N Parameter: 13.73 sN Parameter: 0.64 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of benzyl trifluoromethyl sulfone (in DMSO) | DMSO | N Parameter: 18.67 sN Parameter: 0.68 | J. Am. Chem. Soc. 2007, 129, 9753-9761 DOI: 10.1021/ja072135b | |
anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO) | DMSO | N Parameter: 14.94 sN Parameter: 0.96 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-(acetyl)malonate (in DMSO) | DMSO | N Parameter: 13.83 sN Parameter: 0.84 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-(benzoyl)malonate (in DMSO) | DMSO | N Parameter: 13.63 sN Parameter: 0.80 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-(isopropyl)malonate (in DMSO) | DMSO | N Parameter: 18.74 sN Parameter: 0.71 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-(p-anisyl)malonate (in DMSO) | DMSO | N Parameter: 16.73 sN Parameter: 0.91 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-butylmalonate (in DMSO) | DMSO | N Parameter: 23.00 sN Parameter: 0.55 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-cyclohexylmalonate (in DMSO) | DMSO | N Parameter: 19.23 sN Parameter: 0.67 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl 2-phenylmalonate (in DMSO) | DMSO | N Parameter: 15.93 sN Parameter: 0.99 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anion of diethyl malonate (in DMSO) | DMSO | N Parameter: 20.22 sN Parameter: 0.65 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of diethyl malonate (in water) | water | N Parameter: 16.15 sN Parameter: 0.66 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of diethyl methylmalonate (in DMSO) | DMSO | N Parameter: 21.13 sN Parameter: 0.68 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of diethyl methylmalonate (in water) | water | N Parameter: 17.68 sN Parameter: 0.50 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of dimedone (in DMSO) | DMSO | N Parameter: 16.27 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of dimedone (in water) | water | N Parameter: 11.77 sN Parameter: 0.63 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of dimethyl malonate (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.24 sN Parameter: 0.64 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of ethyl 2-cyano-2-phenylacetate (in DMSO) | DMSO | N Parameter: 15.85 sN Parameter: 1.04 | Eur. J. Org. Chem. 2017, , 1196-1202 DOI: 10.1002/ejoc.201601513 | |
anion of ethyl 2-nitroacetate (in DMSO) | DMSO | N Parameter: 15.24 sN Parameter: 0.74 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of ethyl 3-oxo-3-phenylpropanoate (in DMSO) | DMSO | N Parameter: 17.52 sN Parameter: 0.74 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of ethyl acetylacetate (in DMSO) | DMSO | N Parameter: 18.82 sN Parameter: 0.69 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of ethyl acetylacetate (in water) | water | N Parameter: 15.99 sN Parameter: 0.62 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of ethyl cyanoacetate (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.59 sN Parameter: 0.65 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of ethyl cyanoacetate (in DMSO) | DMSO | N Parameter: 19.62 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of ethyl cyanoacetate (in water) | water | N Parameter: 15.57 sN Parameter: 0.58 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of malononitrile (in 91M9AN) | MeOH-MeCN mix | N Parameter: 18.21 sN Parameter: 0.69 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of malononitrile (in DMSO) | DMSO | N Parameter: 19.36 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of malononitrile (in water) | water | N Parameter: 19.50 sN Parameter: 0.55 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of Meldrum's acid (in water) | water | N Parameter: 12.06 sN Parameter: 0.66 | J. Am. Chem. Soc. 2003, 125, 12980-12986 DOI: 10.1021/ja036838e | |
anion of Meldrums acid (in DMSO) | DMSO | N Parameter: 13.91 sN Parameter: 0.86 | Angew. Chem. Int. Ed. 2002, 41, 91-95 DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P | |
anion of N,N-diethyl-3-oxo-3-phenylpropanoate (in DMSO) | DMSO | N Parameter: 19.28 sN Parameter: 0.65 | Chem. Eur. J. 2015, 21, 875-884 DOI: 10.1002/chem.201404500 | |
anion of nitroethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.41 sN Parameter: 0.67 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of nitroethane (in DMF) | DMF | N Parameter: 22.21 sN Parameter: 0.48 | Chem. Eur. J. 2008, 14, 6108-6118 DOI: 10.1002/chem.200800329 | |
anion of nitroethane (in DMSO) | DMSO | N Parameter: 21.54 sN Parameter: 0.62 | J. Org. Chem. 2003, 68, 6880-6886 DOI: 10.1021/jo0344182 | |
anion of nitroethane (in water) | water | N Parameter: 11.25 sN Parameter: 0.52 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of nitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.02 sN Parameter: 0.61 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of nitromethane (in DMSO) | DMSO | N Parameter: 20.71 sN Parameter: 0.60 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of nitromethane (in water) | water | N Parameter: 12.06 sN Parameter: 0.53 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of p-tolylnitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.58 sN Parameter: 0.64 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of p-tolylnitromethane (in DMSO) | DMSO | N Parameter: 18.31 sN Parameter: 0.76 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of p-tolylnitromethane (in water) | water | N Parameter: 13.09 sN Parameter: 0.50 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of phenylnitromethane (in 91M9AN) | MeOH-MeCN mix | N Parameter: 12.51 sN Parameter: 0.67 | Eur. J. Org. Chem. 2006, , 2530-2537 DOI: 10.1002/ejoc.200500769 | |
anion of phenylnitromethane (in DMSO) | DMSO | N Parameter: 18.29 sN Parameter: 0.71 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of phenylnitromethane (in H2O) | water | N Parameter: 12.05 sN Parameter: 0.53 | J. Org. Chem. 2004, 69, 7565-7576 DOI: 10.1021/jo048773j | |
anion of triethyl methanetricarboxylate (in DMSO) | DMSO | N Parameter: 15.33 sN Parameter: 0.72 | Eur. J. Org. Chem. 2016, , 1841-1848 DOI: 10.1002/ejoc.201600107 | |
anisole | dichloromethane | N Parameter: -1.18 sN Parameter: 1.20 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
arginine (betaine, in water) | water | N Parameter: 12.96 sN Parameter: 0.57 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
asparagine (anionic, in water) | water | N Parameter: 13.03 sN Parameter: 0.53 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
aspartate (dianionic, in water) | water | N Parameter: 13.81 sN Parameter: 0.53 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
azide ion (in 45M55AN) | MeOH-MeCN mix | N Parameter: 15.01 sN Parameter: 0.80 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azide ion (in 91E9AN) | EtOH-MeCN mix | N Parameter: 16.30 sN Parameter: 0.73 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azide ion (in 91iPr9AN) | iPrOH-MeCN mix | N Parameter: 17.07 sN Parameter: 0.71 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azide ion (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.54 sN Parameter: 0.82 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azide ion (in 91nPr9AN) | nPrOH-MeCN mix | N Parameter: 16.70 sN Parameter: 0.73 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azide ion (in DMSO) | DMSO | N Parameter: 20.50 sN Parameter: 0.59 | J. Phys. Org. Chem. 2006, 19, 706-713 DOI: 10.1002/poc.1063 | |
azulene | MeCN | N Parameter: 6.66 sN Parameter: 1.02 | Eur. J. Org. Chem. 2009, , 1202-1206 DOI: 10.1002/ejoc.200801099 | |
barbiturate anion (in DMSO) | DMSO | N Parameter: 15.59 sN Parameter: 0.80 | J. Org. Chem. 2017, 82, 8476-8488 DOI: 10.1021/acs.joc.7b01223 | |
benzimidazole (in DMSO) | DMSO | N Parameter: 10.50 sN Parameter: 0.79 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
benzimidazole anion (in DMSO) | DMSO | N Parameter: 19.13 sN Parameter: 0.55 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
benzoate (in 90AN10W) | aq MeCN | N Parameter: 11.30 sN Parameter: 0.72 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
benzoate (in MeCN) | MeCN | N Parameter: 16.82 sN Parameter: 0.70 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
benzoate (inMeCN) | MeCN | N Parameter: 16.45 sN Parameter: 0.72 | J. Am. Chem. Soc. 2020, 142, 5221-5233 DOI: 10.1021/jacs.9b12998 | |
benzohydrazide (in MeCN) | MeCN | N Parameter: 12.49 sN Parameter: 0.66 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
benzotriazole (in MeCN) | MeCN | N Parameter: 7.69 sN Parameter: 0.76 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
benzotriazole anion (in DMSO) | DMSO | N Parameter: 16.29 sN Parameter: 0.65 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
benzotriazole anion (in water) | water | N Parameter: 11.52 sN Parameter: 0.67 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
benzyl (1-phenylvinyl)carbamate | MeCN | N Parameter: 6.21 sN Parameter: 0.87 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
benzyl isocyanide | dichloromethane | N Parameter: 4.90 sN Parameter: 0.74 | Angew. Chem. Int. Ed. 2007, 46, 3563-3566 DOI: 10.1002/anie.200605205 | |
benzylamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.46 sN Parameter: 0.62 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
benzylamine (in DMSO) | DMSO | N Parameter: 15.28 sN Parameter: 0.65 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
benzylamine (in MeCN) | MeCN | N Parameter: 14.29 sN Parameter: 0.67 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
benzylamine (in water) | water | N Parameter: 13.44 sN Parameter: 0.55 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
benzyldimethylsilane | dichloromethane | N Parameter: 2.78 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
beta-(trimethylsilyl)styrene | dichloromethane | N Parameter: -0.43 sN Parameter: 1.06 | Chem. Eur. J. 2014, 20, 1103-1110 DOI: 10.1002/chem.201303215 | |
beta-alanine (anionic, in water) | water | N Parameter: 13.26 sN Parameter: 0.58 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
beta-piperidinium-peroxypropionate | water | N Parameter: 13.94 sN Parameter: 0.62 | Eur. J. Org. Chem. 2018, , 6010-6017 DOI: 10.1002/ejoc.201801158 | |
bis(4-(dimethylamino)phenyl)phenylmethane (in MeCN) | MeCN | N Parameter: -4.20 sN Parameter: 0.82 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
bis(4-methoxyphenyl)methane (in CH2Cl2) | dichloromethane | N Parameter: -2.11 sN Parameter: 0.98 | J. Am. Chem. Soc. 2014, 136, 13863-13873 DOI: 10.1021/ja507598y | |
bis(4-methoxyphenyl)phenylmethane (in MeCN) | MeCN | N Parameter: -7.00 sN Parameter: 0.82 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
bis(4-nitrophenyl)methanide (in DMSO) | DMSO | N Parameter: 19.92 sN Parameter: 0.67 | ARKIVOC 2008, (x), 37-53 DOI: 10.3998/ark.5550190.0009.a05 | |
bis(phenylsulfonyl)methanide (in DMSO) | DMSO | N Parameter: 15.68 sN Parameter: 0.74 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
borane-2,6-lutidine-complex | dichloromethane | N Parameter: 10.33 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-4-methoxypyridine-complex | dichloromethane | N Parameter: 11.01 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-4-tBu-pyridine-complex | dichloromethane | N Parameter: 10.46 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-DMAP-complex | dichloromethane | N Parameter: 12.44 sN Parameter: 0.76 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N,N-diethylaniline-complex | dichloromethane | N Parameter: 8.53 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N,N-diisopropylaniline-complex | dichloromethane | N Parameter: 8.84 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-N-ethyl-N-isopropylaniline-complex | dichloromethane | N Parameter: 9.12 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-pyridine-complex | dichloromethane | N Parameter: 10.01 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
borane-triethylamine-complex | dichloromethane | N Parameter: 8.90 sN Parameter: 0.75 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
borane-trimethylamine-complex | dichloromethane | N Parameter: 7.97 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
bromide (in 20% aq MeCN) | water-MeCN mix | N Parameter: 12.20 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in 40% aq MeCN) | water-MeCN mix | N Parameter: 12.80 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in 50% aq EtOH) | water-EtOH mix | N Parameter: 13.60 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in 50% aq MeCN) | water-MeCN mix | N Parameter: 13.80 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in 80% aq EtOH) | water-EtOH mix | N Parameter: 14.50 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in CF3CH2OH) | TFE | N Parameter: 11.70 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromide (in H2O) | water | N Parameter: 11.70 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
bromite (in water) | water | N Parameter: 12.75 sN Parameter: 0.59 | Org. Lett. 2018, 20, 2816-2820 DOI: 10.1021/acs.orglett.8b00645 | |
bromo(phenylsulfonyl)methanide (in DMSO) | DMSO | N Parameter: 23.90 sN Parameter: 0.62 | J. Org. Chem. 2017, 82, 2011-2017 DOI: 10.1021/acs.joc.6b02844 | |
bromoborane-triethylamine-complex | dichloromethane | N Parameter: 7.49 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
Bu4NBH4 (in DMSO) | DMSO | N Parameter: 14.94 sN Parameter: 0.79 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
buta-1,3-diene | dichloromethane | N Parameter: -0.87 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
butyltrimethylsilane | dichloromethane | N Parameter: -5.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
chloride (in 20% aq MeCN) | water-MeCN mix | N Parameter: 11.31 sN Parameter: 0.58 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 40% aq MeCN) | water-MeCN mix | N Parameter: 11.30 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 50% aq EtOH) | water-EtOH mix | N Parameter: 11.80 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 50% aq MeCN) | water-MeCN mix | N Parameter: 12.00 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 50/50 MeOH/MeCN) | MeOH-MeCN mix | N Parameter: 14.10 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 60% aq MeCN) | water-MeCN mix | N Parameter: 12.00 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 80% aq EtOH) | water-EtOH mix | N Parameter: 13.00 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in 80% aq MeCN) | water-MeCN mix | N Parameter: 13.30 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in CF3CH2OH) | TFE | N Parameter: 10.30 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in EtOH) | EtOH | N Parameter: 14.70 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in H2O) | water | N Parameter: 10.10 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in hexafluoroisopropanol) | HFIP | N Parameter: 8.00 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in MeCN) | MeCN | N Parameter: 17.20 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloride (in MeOH) | MeOH | N Parameter: 12.90 sN Parameter: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 DOI: 10.1021/ja045562n | |
chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO) | DMSO | N Parameter: 26.90 sN Parameter: 0.45 | J. Org. Chem. 2017, 82, 2011-2017 DOI: 10.1021/acs.joc.6b02844 | |
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO) | DMSO | N Parameter: 25.59 sN Parameter: 0.51 | J. Org. Chem. 2017, 82, 2011-2017 DOI: 10.1021/acs.joc.6b02844 | |
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO) | DMSO | N Parameter: 24.88 sN Parameter: 0.49 | J. Org. Chem. 2017, 82, 2011-2017 DOI: 10.1021/acs.joc.6b02844 | |
chloro(phenylsulfonyl)methanide (in DMF) | DMF | N Parameter: 26.64 sN Parameter: 0.64 | Chem. Eur. J. 2008, 14, 6108-6118 DOI: 10.1002/chem.200800329 | |
chloro(phenylsulfonyl)methanide (in DMSO) | DMSO | N Parameter: 28.27 sN Parameter: 0.42 | J. Org. Chem. 2017, 82, 2011-2017 DOI: 10.1021/acs.joc.6b02844 | |
chlorodimethylsilane | dichloromethane | N Parameter: 0.79 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
cis-HMn(PCy3)(CO)4 | dichloromethane | N Parameter: 2.20 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
cis-HMn(PPh3)(CO)4 | dichloromethane | N Parameter: 2.30 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
cis-HRe(PPh3)(CO)4 | dichloromethane | N Parameter: 4.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
Cp2Ti(CH2Ph)2 - Dibenzyltitanocene | dichloromethane | N Parameter: 4.38 sN Parameter: 1.00 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene | dichloromethane | N Parameter: 5.10 sN Parameter: 1.03 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
Cp2Zr(Me)2 - Dimethylzirconocene | dichloromethane | N Parameter: 4.35 sN Parameter: 1.09 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
cumene peroxy anion (in H2O) | water | N Parameter: 13.92 sN Parameter: 0.61 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
cyanamide anion (in DMSO) | DMSO | N Parameter: 20.33 sN Parameter: 0.64 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
cyanate (in MeCN) | MeCN | N Parameter: 13.60 sN Parameter: 0.84 | Chem. Eur. J. 2008, 14, 3866-3868 DOI: 10.1002/chem.200800314 | |
cyanide (in MeCN) | MeCN | N Parameter: 16.27 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2005, 44, 142-145 DOI: 10.1002/anie.200461640 | |
cyano((diphenylmethylene)amino)methanide | DMSO | N Parameter: 29.50 sN Parameter: 0.50 | Tetrahedron 2019, 75, 459-463 DOI: 10.1016/j.tet.2018.11.075 | |
cyano(pyridin-1-ium-1-yl)methanide (in DMSO) | DMSO | N Parameter: 25.94 sN Parameter: 0.42 | J. Am. Chem. Soc. 2013, 135, 15216-15224 DOI: 10.1021/ja407885h | |
cyanoborate ion (in water) | water | N Parameter: 9.99 sN Parameter: 0.54 | Org. Biomol. Chem. 2023, 21, 85-88 DOI: 10.1039/D2OB02041F | |
cyclohepta-1,3,5-trienyl-Fe(CO)3 | dichloromethane | N Parameter: 3.42 sN Parameter: 0.94 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
cyclohepta-1,3-diene | dichloromethane | N Parameter: 0.06 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
cycloheptatriene | dichloromethane | N Parameter: 0.52 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
cycloheptatriene (in MeCN) | MeCN | N Parameter: 0.55 sN Parameter: 0.97 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
cyclohexa-1,3-diene | dichloromethane | N Parameter: 0.67 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
cycloocta-1,3-diene | dichloromethane | N Parameter: -0.50 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
cyclopentadiene | dichloromethane | N Parameter: 2.30 sN Parameter: 1.06 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
cyclopentene | dichloromethane | N Parameter: -1.55 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
cysteine (dianionic, in water, S-nucleophile!) | water | N Parameter: 23.43 sN Parameter: 0.42 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
DABCO (in MeCN) | MeCN | N Parameter: 18.80 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2007, 46, 6176-6179 DOI: 10.1002/anie.200701489 | |
Danishefskys diene | dichloromethane | N Parameter: 8.57 sN Parameter: 0.84 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
DBN (in CH2Cl2) | dichloromethane | N Parameter: 15.50 sN Parameter: 0.76 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
DBN (in MeCN) | MeCN | N Parameter: 16.28 sN Parameter: 0.67 | Chem. Commun. 2008, , 1792-1794 DOI: 10.1039/b801811a | |
DBU (in MeCN) | MeCN | N Parameter: 15.29 sN Parameter: 0.70 | Chem. Commun. 2008, , 1792-1794 DOI: 10.1039/b801811a | |
DBU (in THF) | THF | N Parameter: 16.12 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
Desoxy Breslow intermediate 2a | THF | N Parameter: 17.12 sN Parameter: 0.80 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Desoxy Breslow intermediate 2a | DMSO | N Parameter: 17.41 sN Parameter: 0.74 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Desoxy Breslow intermediate 2a' | THF | N Parameter: 14.45 sN Parameter: 0.71 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Desoxy Breslow intermediate 2b | THF | N Parameter: 13.91 sN Parameter: 0.64 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Desoxy Breslow intermediate 2b' | THF | N Parameter: 11.42 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Desoxy Breslow intermediate 2c' | THF | N Parameter: 12.75 sN Parameter: 0.71 | Angew. Chem. Int. Ed. 2012, 51, 6231-6235 DOI: 10.1002/anie.201202327 | |
Dexoxy Breslow intermediate 6 | THF | N Parameter: 15.58 sN Parameter: 0.57 | Angew. Chem. Int. Ed. 2012, 51, 10408-10412 DOI: 10.1002/anie.201204524 | |
DHPB (3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine) | dichloromethane | N Parameter: 13.86 sN Parameter: 0.78 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
di(methoxyethyl)amine (in MeCN) | MeCN | N Parameter: 13.24 sN Parameter: 0.93 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
diacetamide anion (in DMSO) | DMSO | N Parameter: 16.05 sN Parameter: 0.70 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
diazoacetone | dichloromethane | N Parameter: 3.96 sN Parameter: 0.91 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
diazocyclopentadiene (in CH2Cl2) | dichloromethane | N Parameter: 4.84 sN Parameter: 1.06 | Synthesis 2023, 55, 354-358 DOI: 10.1055/s-0041-1737327 | |
diazomethane | dichloromethane | N Parameter: 10.48 sN Parameter: 0.78 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
dibutylsulfide (in CH2Cl2) | dichloromethane | N Parameter: 11.86 sN Parameter: 0.74 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
dichloro(methyl)silane | dichloromethane | N Parameter: -3.20 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
diethanolamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.71 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
diethanolamine (in DMSO) | DMSO | N Parameter: 15.51 sN Parameter: 0.70 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
diethanolamine (in water) | water | N Parameter: 13.00 sN Parameter: 0.61 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
diethyl diazomalonate | dichloromethane | N Parameter: -0.35 sN Parameter: 0.93 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
diethyl(methyl)silane | dichloromethane | N Parameter: 3.40 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
diethylamine (in MeCN) | MeCN | N Parameter: 15.10 sN Parameter: 0.73 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
diethylamine (in water) | water | N Parameter: 14.68 sN Parameter: 0.53 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
diethylether (in dichloromethane) | dichloromethane | N Parameter: -5.10 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
diethylmercury (in MeCN) | MeCN | N Parameter: -0.70 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dihexylsilane | dichloromethane | N Parameter: 2.27 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
Dimedone iodonium ylide (in CH2Cl2) | dichloromethane | N Parameter: 6.18 sN Parameter: 0.81 | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 | |
dimethoxymethane | dichloromethane | N Parameter: -4.90 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
Dimethyl 1,1'-isopropylidenezirconocene | dichloromethane | N Parameter: 5.20 sN Parameter: 1.00 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
Dimethyl bis(indenyl)zirconium(IV) | dichloromethane | N Parameter: 6.89 sN Parameter: 1.00 | Chem. Eur. J. 2016, 22, 11196-11200 DOI: 10.1002/chem.201602452 | |
dimethyl diazomalonate | dichloromethane | N Parameter: -1.24 sN Parameter: 0.81 | Angew. Chem. Int. Ed. Engl. 1994, 33, 938-957 DOI: 10.1002/anie.199409381 | |
dimethyl((trimethylgermyl)methyl)silane | dichloromethane | N Parameter: 5.36 sN Parameter: 0.62 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethyl((trimethylstannyl)methyl)silane | dichloromethane | N Parameter: 6.53 sN Parameter: 0.58 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethyl(neopentyl)silane | dichloromethane | N Parameter: 3.55 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethyl(p-tolyl)silane | dichloromethane | N Parameter: 3.83 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethyl(phenyl)silane | dichloromethane | N Parameter: 3.55 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethyl(propoxy)silane | dichloromethane | N Parameter: 2.40 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dimethylamine (in MeCN) | MeCN | N Parameter: 17.96 sN Parameter: 0.63 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
dimethylamine (in water) | water | N Parameter: 17.12 sN Parameter: 0.50 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
dimethylselenide (in CH2Cl2) | dichloromethane | N Parameter: 12.60 sN Parameter: 0.72 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
dimethylsulfide (in CH2Cl2) | dichloromethane | N Parameter: 12.32 sN Parameter: 0.72 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
dimethylsulfide (in MeCN) | MeCN | N Parameter: 12.70 sN Parameter: 0.72 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
diphenyldiazomethane | dichloromethane | N Parameter: 5.29 sN Parameter: 0.92 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
diphenylsilane | dichloromethane | N Parameter: 1.52 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
dipp Imd boronate | dichloromethane | N Parameter: 9.55 sN Parameter: 0.81 | Org. Lett. 2012, 14, 82-85 DOI: 10.1021/ol202836p | |
dipropylamine (in MeCN) | MeCN | N Parameter: 14.51 sN Parameter: 0.80 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
ditert-butyl-phenylphosphane | dichloromethane | N Parameter: 12.40 sN Parameter: 0.55 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
DMSO (O attack) | DMSO | N Parameter: 11.30 sN Parameter: 0.74 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
enolate of 2-coumaranone (in DMSO) | DMSO | N Parameter: 19.60 sN Parameter: 0.75 | J. Org. Chem. 2024, 89, 6915-6928 DOI: 10.1021/acs.joc.4c00277 | |
enolate of 3-isochromanone (in DMSO) | DMSO | N Parameter: 25.39 sN Parameter: 0.54 | J. Org. Chem. 2024, 89, 6915-6928 DOI: 10.1021/acs.joc.4c00277 | |
ethanol | EtOH | N Parameter: 7.44 sN Parameter: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
ethanol (in MeCN) | MeCN | N Parameter: 7.13 sN Parameter: 0.71 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
ethanolamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.23 sN Parameter: 0.65 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
ethanolamine (in DMSO) | DMSO | N Parameter: 16.07 sN Parameter: 0.61 | J. Am. Chem. Soc. 2009, 131, 11392-11401 DOI: 10.1021/ja903207b | |
ethanolamine (in MeCN) | MeCN | N Parameter: 14.11 sN Parameter: 0.71 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
ethanolamine (in water) | water | N Parameter: 12.61 sN Parameter: 0.58 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
ethanolate (in 91E9AN) | EtOH-MeCN mix | N Parameter: 16.08 sN Parameter: 0.62 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
ethanolate (in ethanol) | EtOH | N Parameter: 15.78 sN Parameter: 0.65 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
ethyl (E)-3-(dimethylamino)acrylate | dichloromethane | N Parameter: 9.43 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
ethyl (E)-3-(N-morpholino)acrylate | dichloromethane | N Parameter: 8.52 sN Parameter: 0.80 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
ethyl diazoacetate | dichloromethane | N Parameter: 4.91 sN Parameter: 0.95 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
ethyl glycinate (in DMSO) | DMSO | N Parameter: 14.30 sN Parameter: 0.67 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
ethyl N-acetylcarbamate anion (in DMSO) | DMSO | N Parameter: 15.99 sN Parameter: 0.70 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
ethyl-vinylether | dichloromethane | N Parameter: 3.92 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
ethylamine (in water) | water | N Parameter: 12.87 sN Parameter: 0.58 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
ethyldimethylsilane | dichloromethane | N Parameter: 3.30 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
ethylenediamine (in water) | water | N Parameter: 13.28 sN Parameter: 0.58 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
fluoride (in 10 % aq MeCN) | water-MeCN mix | N Parameter: 8.05 sN Parameter: 0.64 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in 60% aq MeCN) | water-MeCN mix | N Parameter: 9.75 sN Parameter: 0.63 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in 80% aq EtOH) | water-EtOH mix | N Parameter: 13.20 sN Parameter: 0.53 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in 80% aq MeCN) | water-MeCN mix | N Parameter: 11.40 sN Parameter: 0.59 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in 90% aq MeCN) | water-MeCN mix | N Parameter: 12.27 sN Parameter: 0.59 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in 98% aq MeCN) | water-MeCN mix | N Parameter: 10.88 sN Parameter: 0.83 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in MeOH) | MeOH | N Parameter: 11.31 sN Parameter: 0.63 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluoride (in water) | water | N Parameter: 7.70 sN Parameter: 0.66 | J. Org. Chem. 2012, 77, 3325-3335 DOI: 10.1021/jo300141z | |
fluorobis(phenylsulfonyl)methanide (in DMSO) | DMSO | N Parameter: 17.46 sN Parameter: 0.73 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
formohydrazide (in MeCN) | MeCN | N Parameter: 10.35 sN Parameter: 0.76 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
furan | dichloromethane | N Parameter: 1.33 sN Parameter: 1.29 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
gamma-aminobutyric acid (anionic, in water) | water | N Parameter: 13.55 sN Parameter: 0.56 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
glutamate (dianionic, in water) | water | N Parameter: 13.96 sN Parameter: 0.54 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
glutamine (anionic, in water) | water | N Parameter: 13.45 sN Parameter: 0.54 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
glutathione GSH(NH3+/S-) | water | N Parameter: 20.97 sN Parameter: 0.56 | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 DOI: 10.1002/anie.201909803 | |
glycine (anionic, in water) | water | N Parameter: 13.51 sN Parameter: 0.58 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
glycineamide (in water) | water | N Parameter: 12.29 sN Parameter: 0.58 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
glycinenitrile (in water) | water | N Parameter: 10.80 sN Parameter: 0.61 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
glycylglycine (anionic, in water) | water | N Parameter: 12.91 sN Parameter: 0.59 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
glycylglycylglycine (anionic, in water) | water | N Parameter: 12.26 sN Parameter: 0.63 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
guanine anion (in water) | water | N Parameter: 11.63 sN Parameter: 0.59 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
guanosine anion (in water) | water | N Parameter: 12.09 sN Parameter: 0.52 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
H2O (in water) | water | N Parameter: 5.20 sN Parameter: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
Hantzsch ester | dichloromethane | N Parameter: 9.00 sN Parameter: 0.90 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
HCr(CO)3Cp* | dichloromethane | N Parameter: 1.60 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
hexylsilane | dichloromethane | N Parameter: 0.19 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HFe(CO)2Cp* | dichloromethane | N Parameter: 8.20 sN Parameter: 0.69 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
histidine (anionic, in water) | water | N Parameter: 13.83 sN Parameter: 0.54 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
HMn(CO)5 | dichloromethane | N Parameter: 1.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HMo(CO)3Cp* | dichloromethane | N Parameter: 4.30 sN Parameter: 0.77 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HMo(Cp)(CO)3 | dichloromethane | N Parameter: 4.88 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HOO- (in water) | water | N Parameter: 15.40 sN Parameter: 0.55 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
HOs(CO)2Cp* | dichloromethane | N Parameter: 5.20 sN Parameter: 0.95 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HRe(CO)5 | dichloromethane | N Parameter: 3.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HRu(CO)2Cp* | dichloromethane | N Parameter: 8.00 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(CO)3(C5H4CO2Me) | dichloromethane | N Parameter: -0.90 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(CO)3(C5H4Me) | dichloromethane | N Parameter: 2.40 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(CO)3(indenyl) | dichloromethane | N Parameter: 3.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(CO)3Cp | dichloromethane | N Parameter: 1.70 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(CO)3Cp* | dichloromethane | N Parameter: 3.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
HW(NO)2Cp | dichloromethane | N Parameter: 4.70 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
hydantoin anion (in DMSO) | DMSO | N Parameter: 17.52 sN Parameter: 0.55 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
hydrazine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.47 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
hydrazine (in MeCN) | MeCN | N Parameter: 16.45 sN Parameter: 0.56 | Angew. Chem. Int. Ed. 2012, 51, 1353-1356 DOI: 10.1002/anie.201107315 | |
hydrazine (in water) | water | N Parameter: 13.46 sN Parameter: 0.57 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
hydroxylamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 12.23 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
hydroxylamine (in MeCN) | MeCN | N Parameter: 12.80 sN Parameter: 0.63 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
hydroxylamine (in water) | water | N Parameter: 11.41 sN Parameter: 0.55 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
hypobromite (in water) | water | N Parameter: 16.69 sN Parameter: 0.46 | Org. Lett. 2018, 20, 2816-2820 DOI: 10.1021/acs.orglett.8b00645 | |
hypochlorite (in water) | water | N Parameter: 14.50 sN Parameter: 0.58 | Org. Lett. 2018, 20, 2816-2820 DOI: 10.1021/acs.orglett.8b00645 | |
imidazole (in 91M9AN) | MeOH-MeCN mix | N Parameter: 10.41 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
imidazole (in DMSO) | DMSO | N Parameter: 11.58 sN Parameter: 0.79 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
imidazole (in MeCN) | MeCN | N Parameter: 11.47 sN Parameter: 0.79 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
imidazole (in water) | water | N Parameter: 9.63 sN Parameter: 0.57 | Org. Biomol. Chem. 2010, 8, 1929-1935 DOI: 10.1039/c000965b | |
imidazole anion (in DMSO) | DMSO | N Parameter: 21.09 sN Parameter: 0.51 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
Indole | dichloromethane | N Parameter: 5.55 sN Parameter: 1.09 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
isobutylenyl-ethylether | dichloromethane | N Parameter: 4.23 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
isopropanol (in aq. sulfuric acid) | water | N Parameter: -2.60 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
isopropanol (in MeCN) | MeCN | N Parameter: 6.82 sN Parameter: 0.70 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
isopropanolate (in 91iPr9AN) | iPrOH-MeCN mix | N Parameter: 17.71 sN Parameter: 0.58 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
isopropanolate (in propan-2-ol) | iPrOH | N Parameter: 17.03 sN Parameter: 0.63 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
isopropylamine (in MeCN) | MeCN | N Parameter: 13.77 sN Parameter: 0.70 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
isopropylamine (in water) | water | N Parameter: 12.00 sN Parameter: 0.56 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
KBH4 (in DMSO) | DMSO | N Parameter: 15.14 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
leucine (anionic, in water) | water | N Parameter: 14.01 sN Parameter: 0.52 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
lithium (5-methylfuran-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate | MeCN | N Parameter: 8.13 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)glycolborate | MeCN | N Parameter: 11.23 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)neopentylglycolborate | MeCN | N Parameter: 10.13 sN Parameter: 0.91 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)pinacolborate | MeCN | N Parameter: 5.53 sN Parameter: 1.00 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-(dimethylamino)phenyl)pinacolborate | MeCN | N Parameter: 8.02 sN Parameter: 0.89 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)catecholglycolborate | MeCN | N Parameter: 6.50 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)neopentylglycolborate | MeCN | N Parameter: 11.85 sN Parameter: 0.72 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-chlorophenyl)pinacolborate | MeCN | N Parameter: 6.77 sN Parameter: 0.88 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-methoxyphenyl)pinacolborate | MeCN | N Parameter: 7.51 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(4-methylphenyl)pinacolborate | MeCN | N Parameter: 6.98 sN Parameter: 0.93 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (5-methylthiophen-2-yl)(phenyl)pinacolborate | MeCN | N Parameter: 7.24 sN Parameter: 0.83 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 9.49 sN Parameter: 0.82 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium 2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 7.46 sN Parameter: 0.76 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 8.71 sN Parameter: 0.80 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 11.20 sN Parameter: 0.64 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
lithium 2-benzyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 6.30 sN Parameter: 0.78 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-benzyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 7.15 sN Parameter: 0.77 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-benzyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 8.92 sN Parameter: 0.70 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-cyclopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 7.72 sN Parameter: 0.75 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-ethyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 7.68 sN Parameter: 0.78 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 2-isopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 6.63 sN Parameter: 0.75 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 4,4,5,5-tetramethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 8.56 sN Parameter: 0.76 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 10.97 sN Parameter: 0.63 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN) | MeCN | N Parameter: 11.00 sN Parameter: 0.57 | J. Am. Chem. Soc. 2022, 144, 16118-16130 DOI: 10.1021/jacs.2c06493 | |
lithium 5,5-dimethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborinan-2-uide (in MeCN) | MeCN | N Parameter: 11.29 sN Parameter: 0.76 | Org. Lett. 2015, 17, 2614-2617 DOI: 10.1021/acs.orglett.5b00918 | |
lithium bis(5-methylthiophen-2-yl)pinacolborate | MeCN | N Parameter: 7.67 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2015, 54, 2780-2783 DOI: 10.1002/anie.201410562 | |
lithium indenide (in DMSO) | DMSO | N Parameter: 23.66 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
m-(trifluoromethyl)phenolate (in DMF) | DMF | N Parameter: 23.40 sN Parameter: 0.51 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-(trifluoromethyl)phenolate (in DMSO) | DMSO | N Parameter: 22.62 sN Parameter: 0.51 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-(trifluoromethyl)phenolate (in MeCN) | MeCN | N Parameter: 23.20 sN Parameter: 0.51 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-methoxyphenolate (in MeCN) | MeCN | N Parameter: 18.81 sN Parameter: 0.80 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-nitrophenolate (in DMF) | DMF | N Parameter: 22.41 sN Parameter: 0.54 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-nitrophenolate (in DMSO) | DMSO | N Parameter: 21.29 sN Parameter: 0.54 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-nitrophenolate (in MeCN) | MeCN | N Parameter: 25.51 sN Parameter: 0.43 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
m-xylene | dichloromethane | N Parameter: -3.57 sN Parameter: 2.08 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
magnesium 2-carboperoxybenzoate (in H2O) | water | N Parameter: 18.43 sN Parameter: 0.46 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
maleimide anion (in DMSO) | DMSO | N Parameter: 14.87 sN Parameter: 0.76 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
Me2 Imd boronate | dichloromethane | N Parameter: 11.88 sN Parameter: 0.71 | Org. Lett. 2012, 14, 82-85 DOI: 10.1021/ol202836p | |
Me2S(O)=CH2 (in DMSO) | DMSO | N Parameter: 21.29 sN Parameter: 0.47 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
Me2S=CH(4-CN-C6H4) (in DMSO) | DMSO | N Parameter: 21.07 sN Parameter: 0.68 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
Me2S=CH(p-NO2-C6H4) (in DMSO) | DMSO | N Parameter: 18.42 sN Parameter: 0.65 | J. Am. Chem. Soc. 2010, 132, 17894-17900 DOI: 10.1021/ja1084749 | |
Me2S=CH-CN (in DMSO) | DMSO | N Parameter: 16.23 sN Parameter: 0.60 | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 | |
Me2S=CH-CO2Et (in DMSO) | DMSO | N Parameter: 15.85 sN Parameter: 0.61 | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 | |
Meldrum's acid iodonium ylide (in CH2Cl2) | dichloromethane | N Parameter: 4.36 sN Parameter: 1.06 | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 | |
MeO-Breslow 1a | THF | N Parameter: 14.77 sN Parameter: 0.80 | Angew. Chem. Int. Ed. 2012, 51, 10408-10412 DOI: 10.1002/anie.201204524 | |
MeO-Breslow 1b | THF | N Parameter: 10.45 sN Parameter: 0.81 | Angew. Chem. Int. Ed. 2012, 51, 10408-10412 DOI: 10.1002/anie.201204524 | |
MeO-Breslow 1c | THF | N Parameter: 16.61 sN Parameter: 0.68 | Angew. Chem. Int. Ed. 2012, 51, 10408-10412 DOI: 10.1002/anie.201204524 | |
MeO-Breslow 1e | THF | N Parameter: 15.65 sN Parameter: 0.52 | Angew. Chem. Int. Ed. 2012, 51, 10408-10412 DOI: 10.1002/anie.201204524 | |
MeSO-CH-CO2Et (in DMSO) | DMSO | N Parameter: 20.61 sN Parameter: 0.64 | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 | |
MeSO2-CH-CO2Et (in DMSO) | DMSO | N Parameter: 18.00 sN Parameter: 0.66 | Chem. Eur. J. 2010, 16, 8610-8614 DOI: 10.1002/chem.201001455 | |
methanesulfonamide anion (in DMSO) | DMSO | N Parameter: 18.61 sN Parameter: 0.53 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
methanol | MeOH | N Parameter: 7.54 sN Parameter: 0.92 | J. Am. Chem. Soc. 2004, 126, 5174-5181 DOI: 10.1021/ja031828z | |
methanol (in MeCN) | MeCN | N Parameter: 6.86 sN Parameter: 0.73 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
methanolate (in 91M9AN) | MeOH-MeCN mix | N Parameter: 14.51 sN Parameter: 0.68 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
methanolate (in methanol) | MeOH | N Parameter: 15.78 sN Parameter: 0.56 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
methionine (anionic, in water) | water | N Parameter: 13.16 sN Parameter: 0.58 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
methoxybis(phenylsulfonyl)methanide (in DMSO) | DMSO | N Parameter: 17.29 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2016, 55, 12845-12848 DOI: 10.1002/anie.201605616 | |
methyl (cyclohexen-1-yl)prolinate (in MeCN) | MeCN | N Parameter: 14.96 sN Parameter: 0.68 | Angew. Chem. Int. Ed. 2010, 49, 9526-9529 DOI: 10.1002/anie.201004344 | |
methyl carbonate (in MeCN) | MeCN | N Parameter: 16.03 sN Parameter: 0.64 | Eur. J. Org. Chem. 2010, , 4205-4210 DOI: 10.1002/ejoc.201000414 | |
methyl diazoacetate | dichloromethane | N Parameter: 4.68 sN Parameter: 0.94 | J. Am. Chem. Soc. 2023, 145, 7416-7434 DOI: 10.1021/jacs.2c13872 | |
methyl glycinate (in water) | water | N Parameter: 12.08 sN Parameter: 0.60 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
methyl L-prolinate | MeCN | N Parameter: 14.75 sN Parameter: 0.82 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
methyl(neopentyl)(phenyl)silane | dichloromethane | N Parameter: 0.87 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
methyl(phenyl)silane | dichloromethane | N Parameter: 2.13 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
methylamine (in MeCN) | MeCN | N Parameter: 15.19 sN Parameter: 0.68 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
methylamine (in water) | water | N Parameter: 13.85 sN Parameter: 0.53 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
methyldiphenylsilane | dichloromethane | N Parameter: 2.72 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
methylenecyclobutane | dichloromethane | N Parameter: 1.65 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclodecane | dichloromethane | N Parameter: 2.82 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclododecane | dichloromethane | N Parameter: 1.52 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecycloheptane | dichloromethane | N Parameter: 2.24 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclohexane | dichloromethane | N Parameter: 1.16 sN Parameter: 1.04 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
methylenecyclononane | dichloromethane | N Parameter: 2.57 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclooctane | dichloromethane | N Parameter: 3.16 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclopentadecane | dichloromethane | N Parameter: 1.69 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecyclopentane | dichloromethane | N Parameter: 2.82 sN Parameter: 0.90 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
methylenecyclopropane | dichloromethane | N Parameter: -0.47 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylenecycloundecane | dichloromethane | N Parameter: 2.33 sN Parameter: 0.90 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
methylhydrazine (in MeCN) | MeCN | N Parameter: 17.73 sN Parameter: 0.58 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
methylhydrazine (in water) | water | N Parameter: 17.23 sN Parameter: 0.45 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
morpholin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 21.72 sN Parameter: 0.64 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
morpholine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 15.40 sN Parameter: 0.64 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
morpholine (in DMSO) | DMSO | N Parameter: 16.96 sN Parameter: 0.67 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
morpholine (in MeCN) | MeCN | N Parameter: 15.65 sN Parameter: 0.74 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
morpholine (in water) | water | N Parameter: 15.62 sN Parameter: 0.54 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
morpholinoisobutylene | dichloromethane | N Parameter: 10.04 sN Parameter: 0.82 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
N',N'-dimethylformohydrazide (in MeCN) | MeCN | N Parameter: 15.69 sN Parameter: 0.51 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
N,N-dimethyl dithiocarbamate (in MeCN) | MeCN | N Parameter: 20.93 sN Parameter: 0.69 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2) | dichloromethane | N Parameter: 7.98 sN Parameter: 0.71 | J. Am. Chem. Soc. 2016, 138, 10304-10313 DOI: 10.1021/jacs.6b05768 | |
N-(1,3-dimethylimidazolidin-2-ylidene)-1-phenylmethanamine | dichloromethane | N Parameter: 14.00 sN Parameter: 0.70 | ChemCatChem 2012, 4, 993-999 DOI: 10.1002/cctc.201200143 | |
N-(1-(4-chlorophenyl)vinyl)acetamide | MeCN | N Parameter: 5.60 sN Parameter: 1.00 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(1-(4-methoxyphenyl)vinyl)acetamide | MeCN | N Parameter: 7.06 sN Parameter: 0.85 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(1-(naphthalen-2-yl)vinyl)acetamide | MeCN | N Parameter: 6.28 sN Parameter: 0.95 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(1-(p-tolyl)vinyl)acetamide | MeCN | N Parameter: 6.57 sN Parameter: 0.91 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(1-phenylvinyl)acetamide | MeCN | N Parameter: 5.73 sN Parameter: 0.97 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(1-phenylvinyl)benzamide | MeCN | N Parameter: 5.44 sN Parameter: 1.00 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(3,3-dimethylbut-1-en-2-yl)acetamide | MeCN | N Parameter: 4.61 sN Parameter: 0.98 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(3,4-dihydronaphthalen-1-yl)acetamide | MeCN | N Parameter: 4.91 sN Parameter: 0.87 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(cyclohex-1-en-1-yl)acetamide | MeCN | N Parameter: 5.64 sN Parameter: 0.79 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(cyclopent-1-en-1-yl)acetamide | MeCN | N Parameter: 7.06 sN Parameter: 0.87 | Chem. Eur. J. 2012, 18, 5732-5740 DOI: 10.1002/chem.201103519 | |
N-(p-anisyl)-1,4-dihydronicotineamide | dichloromethane | N Parameter: 8.11 sN Parameter: 0.92 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
N-(p-tolyl)-1,4-dihydronicotineamide | dichloromethane | N Parameter: 7.68 sN Parameter: 0.95 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
N-(phenylmethyl)propan-2-imine (in CH2Cl2) | dichloromethane | N Parameter: 11.13 sN Parameter: 0.73 | Z. Naturforsch. B 2013, 68b, 693-699 DOI: 10.5560/ZNB.2013-3085 | |
N-(triisopropylsilyl)pyrrole | dichloromethane | N Parameter: 3.12 sN Parameter: 0.93 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
N-benzyl-1,4-dihydronicotineamide | dichloromethane | N Parameter: 8.67 sN Parameter: 0.82 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
N-benzyl-1,4-dihydronicotineamide (in 50W50AN) | water-MeCN mix | N Parameter: 9.79 sN Parameter: 0.70 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
N-benzyl-1,4-dihydronicotineamide (in 67W33AN) | water-MeCN mix | N Parameter: 10.19 sN Parameter: 0.70 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
N-benzyl-1,4-dihydronicotineamide (in 80W20AN) | water-MeCN mix | N Parameter: 10.67 sN Parameter: 0.70 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
N-benzyl-1,4-dihydronicotineamide (in 90W10AN) | water-MeCN mix | N Parameter: 11.35 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
N-benzyl-1,4-dihydronicotineamide (in MeCN) | MeCN | N Parameter: 9.80 sN Parameter: 0.70 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
N-benzyl-N-((2-methoxyphenyl)ethynyl)-4-methylbenzenesulfonamide | dichloromethane | N Parameter: 4.40 sN Parameter: 0.86 | Angew. Chem. Int. Ed. 2014, 53, 4968-4971 DOI: 10.1002/anie.201402055 | |
N-benzyl-N-(but-1-yn-1-yl)-4-methylbenzenesulfonamide | dichloromethane | N Parameter: 5.16 sN Parameter: 0.85 | Angew. Chem. Int. Ed. 2014, 53, 4968-4971 DOI: 10.1002/anie.201402055 | |
n-butyl vinyl ether | dichloromethane | N Parameter: 3.76 sN Parameter: 0.91 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
n-butylamine (in MeCN) | MeCN | N Parameter: 15.27 sN Parameter: 0.63 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
N-methyl-1-phenylmethanimine (in CH2Cl2) | dichloromethane | N Parameter: 8.60 sN Parameter: 0.77 | Z. Naturforsch. B 2013, 68b, 693-699 DOI: 10.5560/ZNB.2013-3085 | |
N-methyl-glycinenitrile (in water) | water | N Parameter: 13.50 sN Parameter: 0.59 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
N-methyl-morpholine (in CH2Cl2) | dichloromethane | N Parameter: 16.50 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-morpholine (in MeCN) | MeCN | N Parameter: 16.80 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-piperidine (in CH2Cl2) | dichloromethane | N Parameter: 18.90 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-piperidine (in MeCN) | MeCN | N Parameter: 18.72 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-pyrrolidine (in CH2Cl2) | dichloromethane | N Parameter: 20.60 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-pyrrolidine (in MeCN) | MeCN | N Parameter: 20.59 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
N-methyl-trifluoroacetamide anion (in DMSO) | DMSO | N Parameter: 15.70 sN Parameter: 0.71 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
N-methylenepyrrolidin-1-amine (in CH2Cl2) | dichloromethane | N Parameter: 7.84 sN Parameter: 0.89 | Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092 | |
N-methylenepyrrolidin-1-amine (in CH2Cl2) | dichloromethane | N Parameter: 17.90 sN Parameter: 0.48 | Angew. Chem. Int. Ed. 2013, 52, 11900-11904 DOI: 10.1002/anie.201305092 | |
N-methylhydroxylamine (in MeCN) | MeCN | N Parameter: 14.10 sN Parameter: 0.76 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
N-methylindole | dichloromethane | N Parameter: 5.75 sN Parameter: 1.23 | J. Org. Chem. 2006, 71, 9088-9095 DOI: 10.1021/jo0614339 | |
N-methylpyrrole | dichloromethane | N Parameter: 5.85 sN Parameter: 1.03 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
N-phenyl-1,4-dihydronicotineamide | dichloromethane | N Parameter: 7.53 sN Parameter: 0.87 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
N-phenylcyclohexanimine (in CH2Cl2) | dichloromethane | N Parameter: 8.80 sN Parameter: 1.00 | Z. Naturforsch. B 2013, 68b, 693-699 DOI: 10.5560/ZNB.2013-3085 | |
N-phenylpropan-2-imine (in CH2Cl2) | dichloromethane | N Parameter: 9.53 sN Parameter: 0.85 | Z. Naturforsch. B 2013, 68b, 693-699 DOI: 10.5560/ZNB.2013-3085 | |
n-propanolate (in 91nPr9AN) | nPrOH-MeCN mix | N Parameter: 16.73 sN Parameter: 0.63 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
n-propanolate (in propan-1-ol) | nPrOH | N Parameter: 16.03 sN Parameter: 0.70 | Can. J. Chem. 2005, 83, 1554-1560 DOI: 10.1139%2Fv05-170 | |
n-propylamine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 13.41 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
n-propylamine (in DMSO) | DMSO | N Parameter: 15.70 sN Parameter: 0.64 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
n-propylamine (in MeCN) | MeCN | N Parameter: 15.11 sN Parameter: 0.63 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
n-propylamine (in water) | water | N Parameter: 13.33 sN Parameter: 0.56 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
N-vinylcarbazole | dichloromethane | N Parameter: 5.02 sN Parameter: 0.94 | Macromolecules 2002, 35, 5454-5458 DOI: 10.1021/ma020306l | |
NaB(OAc)3H (in DMSO) | DMSO | N Parameter: 14.45 sN Parameter: 0.76 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
NaBH3(CN) (in DMSO) | DMSO | N Parameter: 11.52 sN Parameter: 0.67 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
NaBH4 (in DMSO) | DMSO | N Parameter: 14.74 sN Parameter: 0.81 | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 DOI: 10.1002/anie.200804263 | |
NADH (in water) | water | N Parameter: 10.37 sN Parameter: 0.54 | Org. Biomol. Chem. 2023, 21, 85-88 DOI: 10.1039/D2OB02041F | |
NADPH (in water) | water | N Parameter: 10.68 sN Parameter: 0.54 | Org. Biomol. Chem. 2023, 21, 85-88 DOI: 10.1039/D2OB02041F | |
naphthalene-2-thiolate (in DMSO) | DMSO | N Parameter: 22.55 sN Parameter: 0.83 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
nicotine (in CH2Cl2) | dichloromethane | N Parameter: 10.40 sN Parameter: 1.04 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
nicotine (in MeCN) | MeCN | N Parameter: 11.60 sN Parameter: 0.81 | J. Phys. Org. Chem. 2016, 29, 759-767 DOI: 10.1002/poc.3580 | |
nitrite ion (in MeCN) | MeCN | N Parameter: 17.20 sN Parameter: 0.72 | Angew. Chem. Int. Ed. 2005, 44, 4623-4626 DOI: 10.1002/anie.200501274 | |
norbornene | dichloromethane | N Parameter: -0.25 sN Parameter: 1.09 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
o,o'-di-tert-butylphenolate (in DMSO) | DMSO | N Parameter: 21.02 sN Parameter: 0.59 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
o-(trifluoromethyl)phenolate (in DMF) | DMF | N Parameter: 20.37 sN Parameter: 0.58 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
o-(trifluoromethyl)phenolate (in DMSO) | DMSO | N Parameter: 18.47 sN Parameter: 0.61 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
o-(trifluoromethyl)phenolate (in MeCN) | MeCN | N Parameter: 18.39 sN Parameter: 0.69 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
O-ethyl dithiocarbonate (in MeCN) | MeCN | N Parameter: 19.30 sN Parameter: 0.69 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
O-isopropyl dithiocarbonate (in MeCN) | MeCN | N Parameter: 18.27 sN Parameter: 0.78 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
OH- (in 50/50 water/MeCN) | water-MeCN mix | N Parameter: 10.19 sN Parameter: 0.62 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
OH- (in water) | water | N Parameter: 10.47 sN Parameter: 0.61 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
p-(tert-butyl)phenolate (in DMF) | DMF | N Parameter: 19.90 sN Parameter: 0.80 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-(tert-butyl)phenolate (in DMSO) | DMSO | N Parameter: 19.67 sN Parameter: 0.79 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-(tert-butyl)phenolate (in MeCN) | MeCN | N Parameter: 21.70 sN Parameter: 0.58 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-(trifluoromethyl)phenolate (in DMF) | DMF | N Parameter: 22.05 sN Parameter: 0.53 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-(trifluoromethyl)phenolate (in DMSO) | DMSO | N Parameter: 18.98 sN Parameter: 0.63 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-(trifluoromethyl)phenolate (in MeCN) | MeCN | N Parameter: 21.69 sN Parameter: 0.53 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-chlorophenolate (in DMF) | DMF | N Parameter: 19.67 sN Parameter: 0.72 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-chlorophenolate (in DMSO) | DMSO | N Parameter: 20.34 sN Parameter: 0.64 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-chlorophenolate (in MeCN) | MeCN | N Parameter: 18.32 sN Parameter: 0.82 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-cyanophenolate (in DMF) | DMF | N Parameter: 17.85 sN Parameter: 0.71 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-cyanophenolate (in DMSO) | DMSO | N Parameter: 18.78 sN Parameter: 0.57 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-cyanophenolate (in MeCN) | MeCN | N Parameter: 19.58 sN Parameter: 0.59 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-cymene | dichloromethane | N Parameter: -2.80 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
p-methoxyphenolate (in DMF) | DMF | N Parameter: 19.90 sN Parameter: 0.82 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-methoxyphenolate (in DMSO) | DMSO | N Parameter: 20.09 sN Parameter: 0.80 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-methoxyphenolate (in MeCN) | MeCN | N Parameter: 20.62 sN Parameter: 0.69 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-methylphenolate (in DMF) | DMF | N Parameter: 19.65 sN Parameter: 0.85 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-methylphenolate (in DMSO) | DMSO | N Parameter: 19.08 sN Parameter: 0.87 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-methylphenolate (in H2O) | water | N Parameter: 14.30 sN Parameter: 0.55 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-nitrobenzoate (in acetone) | acetone | N Parameter: 18.74 sN Parameter: 0.68 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
p-nitrobenzoate (in MeCN) | MeCN | N Parameter: 15.30 sN Parameter: 0.76 | J. Am. Chem. Soc. 2008, 130, 3012-3022 DOI: 10.1021/ja0765464 | |
p-nitrophenolate (in DMSO) | DMSO | N Parameter: 14.32 sN Parameter: 0.77 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
p-toluenesulfonamide anion (in DMSO) | DMSO | N Parameter: 17.14 sN Parameter: 0.60 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
p-toluidine (in MeCN) | MeCN | N Parameter: 13.19 sN Parameter: 0.69 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
p-toluidine (in water) | water | N Parameter: 13.00 sN Parameter: 0.79 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
p-tosylmethyl isocyanide (TosMIC) | dichloromethane | N Parameter: 3.50 sN Parameter: 0.76 | Angew. Chem. Int. Ed. 2007, 46, 3563-3566 DOI: 10.1002/anie.200605205 | |
perhydroazepine (in water) | water | N Parameter: 18.29 sN Parameter: 0.46 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
peroxomonosulfate (in water) | water | N Parameter: 14.41 sN Parameter: 0.60 | Org. Lett. 2018, 20, 2816-2820 DOI: 10.1021/acs.orglett.8b00645 | |
peroxy-beta-alanate | water | N Parameter: 14.07 sN Parameter: 0.56 | Eur. J. Org. Chem. 2018, , 6010-6017 DOI: 10.1002/ejoc.201801158 | |
peroxy-GABA | water | N Parameter: 14.33 sN Parameter: 0.57 | Eur. J. Org. Chem. 2018, , 6010-6017 DOI: 10.1002/ejoc.201801158 | |
peroxybenzoate (in H2O) | water | N Parameter: 18.57 sN Parameter: 0.43 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
Ph2P(O)CH(-)CN (in DMSO) | DMSO | N Parameter: 18.69 sN Parameter: 0.72 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph2P(O)CH(-)CO2Et (in DMSO) | DMSO | N Parameter: 19.20 sN Parameter: 0.69 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph3P=C(CH3)-CO2Et | dichloromethane | N Parameter: 13.09 sN Parameter: 0.73 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph3P=CH-C(O)Me (in MeCN) | MeCN | N Parameter: 10.27 sN Parameter: 0.83 | J. Am. Chem. Soc. 2016, 138, 11272-11281 DOI: 10.1021/jacs.6b06264 | |
Ph3P=CH-CHO (in MeCN) | MeCN | N Parameter: 9.09 sN Parameter: 0.74 | J. Am. Chem. Soc. 2016, 138, 11272-11281 DOI: 10.1021/jacs.6b06264 | |
Ph3P=CH-CN | dichloromethane | N Parameter: 12.29 sN Parameter: 0.75 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph3P=CH-CO2Et | dichloromethane | N Parameter: 12.79 sN Parameter: 0.77 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph3P=CH-CO2Et (in DMSO) | DMSO | N Parameter: 12.21 sN Parameter: 0.62 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
Ph3P=CH-COPh | dichloromethane | N Parameter: 9.54 sN Parameter: 0.97 | J. Am. Chem. Soc. 2009, 131, 704-714 DOI: 10.1021/ja8056216 | |
phenolate (in DMF) | DMF | N Parameter: 18.86 sN Parameter: 0.89 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
phenolate (in DMSO) | DMSO | N Parameter: 19.86 sN Parameter: 0.71 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
phenolate (in MeCN) | MeCN | N Parameter: 18.53 sN Parameter: 0.85 | J. Org. Chem. 2019, 84, 8837-8858 DOI: 10.1021/acs.joc.9b01485 | |
phenylacetylene | dichloromethane | N Parameter: -0.04 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2014, 53, 4968-4971 DOI: 10.1002/anie.201402055 | |
phenylalanine (anionic, in water) | water | N Parameter: 14.12 sN Parameter: 0.53 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
phenyldiazomethane | dichloromethane | N Parameter: 9.35 sN Parameter: 0.83 | Chem. Eur. J. 2003, 9, 4068-4076 DOI: 10.1002/chem.200304913 | |
phenylsilane | dichloromethane | N Parameter: 0.06 sN Parameter: 0.71 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
phenylsulfinate (in 50W50AN) | water-MeCN mix | N Parameter: 13.75 sN Parameter: 0.68 | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 | |
phenylsulfinate (in DMSO) | DMSO | N Parameter: 19.60 sN Parameter: 0.60 | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 | |
phenylsulfinate (in MeCN) | MeCN | N Parameter: 20.11 sN Parameter: 0.59 | J. Am. Chem. Soc. 2010, 132, 4796-4805 DOI: 10.1021/ja9102056 | |
phthalimide anion (in DMSO) | DMSO | N Parameter: 15.52 sN Parameter: 0.67 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
phthalimidoperoxyhexanoate (in H2O) | water | N Parameter: 16.02 sN Parameter: 0.54 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
piperazine (in water) | water | N Parameter: 17.22 sN Parameter: 0.50 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
piperidin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 23.84 sN Parameter: 0.57 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
piperidine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 15.63 sN Parameter: 0.64 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
piperidine (in DMSO) | DMSO | N Parameter: 17.19 sN Parameter: 0.71 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
piperidine (in MeCN) | MeCN | N Parameter: 17.35 sN Parameter: 0.68 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
piperidine (in water) | water | N Parameter: 18.13 sN Parameter: 0.44 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
potassium (1-(tert-butoxycarbonyl)-1H-indol-2-yl)trifluoroborate | MeCN | N Parameter: 6.46 sN Parameter: 0.96 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium (1-(tert-butoxycarbonyl)-1H-indol-3-yl)trifluoroborate | MeCN | N Parameter: 4.06 sN Parameter: 0.79 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium (1-(tert-butoxycarbonyl)-5-methoxy-1H-indol-2-yl)trifluoroborate | MeCN | N Parameter: 7.10 sN Parameter: 1.18 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium allyltrifluoroborate (in MeCN) | MeCN | N Parameter: 5.29 sN Parameter: 0.87 | J. Am. Chem. Soc. 2017, 139, 15324-15327 DOI: 10.1021/jacs.7b10240 | |
potassium indenide (in DMSO) | DMSO | N Parameter: 24.16 sN Parameter: 0.68 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
potassium trifluoro(1-methyl-1H-indol-2-yl)borate | MeCN | N Parameter: 9.55 sN Parameter: 1.16 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium trifluoro(1-methyl-1H-indol-5-yl)borate | MeCN | N Parameter: 8.77 sN Parameter: 1.09 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium trifluoro(3-methoxy-thiophen-2-yl)borate | MeCN | N Parameter: 7.32 sN Parameter: 0.90 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
potassium trifluoro(furan-3-yl)borate | MeCN | N Parameter: 6.83 sN Parameter: 0.93 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
prenyl-tributylstannane | dichloromethane | N Parameter: 4.74 sN Parameter: 1.15 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
prolinate (in MeCN) | MeCN | N Parameter: 19.95 sN Parameter: 0.68 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
proline (anionic, in water) | water | N Parameter: 18.08 sN Parameter: 0.50 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
propargylamine (in water) | water | N Parameter: 12.29 sN Parameter: 0.59 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
propene | dichloromethane | N Parameter: -2.41 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
purine anion (in DMSO) | DMSO | N Parameter: 15.03 sN Parameter: 0.77 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
purine anion (in water) | water | N Parameter: 11.00 sN Parameter: 0.54 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
pyridine (in CH2Cl2) | dichloromethane | N Parameter: 12.90 sN Parameter: 0.67 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
pyridine (in H2O) | water | N Parameter: 11.05 sN Parameter: 0.73 | Chem. Eur. J. 2007, 13, 336-345 DOI: 10.1002/chem.200600941 | |
pyridine (in MeCN) | MeCN | N Parameter: 13.60 sN Parameter: 0.60 | Synthesis 2017, 49, 3495-3504 DOI: 10.1055/s-0036-1590504 | |
pyrrole | dichloromethane | N Parameter: 4.63 sN Parameter: 1.00 | Chem. Eur. J. 2003, 9, 2209-2218 DOI: 10.1002/chem.200204666 | |
pyrrolidin-1-yl dithiocarbamate (in MeCN) | MeCN | N Parameter: 22.40 sN Parameter: 0.63 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
pyrrolidine (in 91M9AN) | MeOH-MeCN mix | N Parameter: 15.97 sN Parameter: 0.63 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
pyrrolidine (in water) | water | N Parameter: 17.21 sN Parameter: 0.49 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
pyrrolidine (inMeCN) | MeCN | N Parameter: 18.58 sN Parameter: 0.61 | J. Am. Chem. Soc. 2020, 142, 1526-1547 DOI: 10.1021/jacs.9b11877 | |
quinidine | dichloromethane | N Parameter: 10.54 sN Parameter: 0.74 | J. Org. Chem. 2009, 74, 7157-7164 DOI: 10.1021/jo901670w | |
quinine | dichloromethane | N Parameter: 10.46 sN Parameter: 0.75 | J. Org. Chem. 2009, 74, 7157-7164 DOI: 10.1021/jo901670w | |
quinuclidine (in MeCN) | MeCN | N Parameter: 20.54 sN Parameter: 0.60 | Angew. Chem. Int. Ed. 2007, 46, 6176-6179 DOI: 10.1002/anie.200701489 | |
saccharin anion (in MeCN) | MeCN | N Parameter: 10.78 sN Parameter: 0.89 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
semicarbazide (in water) | water | N Parameter: 11.05 sN Parameter: 0.52 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
serine (anionic, in water) | water | N Parameter: 13.16 sN Parameter: 0.55 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
SO3(2-) (in water) | water | N Parameter: 16.83 sN Parameter: 0.56 | J. Am. Chem. Soc. 2003, 125, 286-295 DOI: 10.1021/ja021010y | |
sodium indenide (in DMSO) | DMSO | N Parameter: 23.74 sN Parameter: 0.71 | Angew. Chem. Int. Ed. 2015, 54, 12497-12500 DOI: 10.1002/anie.201501385 | |
styrene | dichloromethane | N Parameter: 0.78 sN Parameter: 0.95 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
succinimide anion (in DMSO) | DMSO | N Parameter: 16.03 sN Parameter: 0.66 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
t-butylperoxy anion (in H2O) | water | N Parameter: 14.29 sN Parameter: 0.51 | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 DOI: 10.1002/anie.201707086 | |
TCAP (in MeCN) | MeCN | N Parameter: 15.60 sN Parameter: 0.68 | Chem. Eur. J. 2013, 19, 6435-6442 DOI: 10.1002/chem.201204452 | |
tert-butanol (in MeCN) | MeCN | N Parameter: 5.35 sN Parameter: 0.72 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
tert-butyl hydrazinecarboxylate (in MeCN) | MeCN | N Parameter: 11.40 sN Parameter: 0.70 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
tert-butyl indole-1-carboxylate | MeCN | N Parameter: 1.68 sN Parameter: 1.26 | J. Am. Chem. Soc. 2013, 135, 6317-6324 DOI: 10.1021/ja4017655 | |
tert-butyl isocyanide | dichloromethane | N Parameter: 5.47 sN Parameter: 0.77 | Angew. Chem. Int. Ed. 2007, 46, 3563-3566 DOI: 10.1002/anie.200605205 | |
tert-butylamine (in MeCN) | MeCN | N Parameter: 12.35 sN Parameter: 0.72 | Eur. J. Org. Chem. 2009, , 6379-6385 DOI: 10.1002/ejoc.200900925 | |
tert-butylamine (in water) | water | N Parameter: 10.48 sN Parameter: 0.65 | J. Org. Chem. 2007, 72, 3679-3688 DOI: 10.1021/jo062586z | |
tetra-sec.butylstannane (in 1,2-DCE) | 1,2-dichloroethane | N Parameter: -1.10 sN Parameter: 1.15 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetrabutylstannane | dichloromethane | N Parameter: -0.30 sN Parameter: 1.07 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetraethylgermane (in MeCN) | MeCN | N Parameter: -4.70 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetraethylplumbane (in MeCN) | MeCN | N Parameter: 0.10 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetraethylsilane | MeCN | N Parameter: -6.50 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetraethylstannane (in 1,2-DCE) | 1,2-dichloroethane | N Parameter: -1.90 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetraethylstannane (in MeCN) | MeCN | N Parameter: -2.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetrahydroborate ion (in water) | water | N Parameter: 12.10 sN Parameter: 0.79 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetrahydrofuran (in dichloromethane) | dichloromethane | N Parameter: -3.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetrahydrothiophene (in CH2Cl2) | dichloromethane | N Parameter: 13.10 sN Parameter: 0.72 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
tetrahydrothiophene (in MeCN) | MeCN | N Parameter: 13.30 sN Parameter: 0.72 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
tetrahydrothiopyran (in CH2Cl2) | dichloromethane | N Parameter: 11.94 sN Parameter: 0.75 | Chem. Eur. J. 2021, 21, 11367-11376 DOI: 10.1002/chem.202100977 | |
tetraisobutylstannane | dichloromethane | N Parameter: 1.35 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tetrakis(5-methyl-furan-2-yl)borate | MeCN | N Parameter: 9.09 sN Parameter: 1.12 | Chem. Sci. 2012, 3, 878-882 DOI: 10.1039/c2sc00883a | |
tetramethylethylene | dichloromethane | N Parameter: -1.00 sN Parameter: 1.40 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
tetrapropylstannane (in 1,2-DCE) | 1,2-dichloroethane | N Parameter: -0.50 sN Parameter: 1.13 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
theophylline anion (in DMSO) | DMSO | N Parameter: 14.78 sN Parameter: 0.71 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
theophylline anion (in water) | water | N Parameter: 10.06 sN Parameter: 0.71 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
thioacetate (in MeCN) | MeCN | N Parameter: 21.20 sN Parameter: 0.63 | Org. Biomol. Chem. 2011, 9, 8046-8050 DOI: 10.1039/c1ob06245j | |
thiocyanate (in MeCN) | MeCN | N Parameter: 17.94 sN Parameter: 0.60 | J. Am. Chem. Soc. 2003, 125, 14126-14132 DOI: 10.1021/ja037317u | |
thiocyanate (in MeCN) | MeCN | N Parameter: 12.13 sN Parameter: 0.60 | J. Am. Chem. Soc. 2003, 125, 14126-14132 DOI: 10.1021/ja037317u | |
thiophene | dichloromethane | N Parameter: -1.01 sN Parameter: 1.10 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
thiophenolate (in DMSO) | DMSO | N Parameter: 23.36 sN Parameter: 0.74 | J. Org. Chem. 2021, 86, 5965-5972 DOI: 10.1021/acs.joc.1c00025 | |
threonine (anionic, in water) | water | N Parameter: 12.69 sN Parameter: 0.60 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
THTP (3,5,6,7-tetrahydro-2H-thiazolo[3,2-a]pyrimidine) | dichloromethane | N Parameter: 14.45 sN Parameter: 0.78 | J. Org. Chem. 2011, 76, 5104-5112 DOI: 10.1021/jo200803x | |
thymine anion (in DMSO) | DMSO | N Parameter: 17.63 sN Parameter: 0.62 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
thymine anion (in water) | water | N Parameter: 11.17 sN Parameter: 0.51 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
toluene | dichloromethane | N Parameter: -4.36 sN Parameter: 1.77 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
trans-HMo(CO)2(PCy3)Cp | dichloromethane | N Parameter: 6.50 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trans-HMo(CO)2(PMe3)Cp | dichloromethane | N Parameter: 7.80 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trans-HMo(CO)2(PPh3)Cp | dichloromethane | N Parameter: 6.60 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tri-n-butylphosphane | dichloromethane | N Parameter: 15.49 sN Parameter: 0.69 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
tri-p-tolylmethane | dichloromethane | N Parameter: -3.62 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tri-p-tolylmethane (in MeCN) | MeCN | N Parameter: -8.80 sN Parameter: 0.82 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tributyl phosphite | dichloromethane | N Parameter: 10.36 sN Parameter: 0.70 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
tributylgermane | dichloromethane | N Parameter: 5.92 sN Parameter: 0.73 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
tributylsilane | dichloromethane | N Parameter: 3.99 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tributylstannane | dichloromethane | N Parameter: 9.96 sN Parameter: 0.55 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
tricyclohexylphosphane | dichloromethane | N Parameter: 14.64 sN Parameter: 0.68 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
triethoxysilane | dichloromethane | N Parameter: -1.80 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triethylamine (in CH2Cl2) | dichloromethane | N Parameter: 17.30 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
triethylamine (in MeCN) | MeCN | N Parameter: 17.10 sN Parameter: 0.52 | J. Phys. Org. Chem. 2010, 23, 1029-1035 DOI: 10.1002/poc.1707 | |
triethylgermane | dichloromethane | N Parameter: 4.00 sN Parameter: 0.75 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triethylsilane | dichloromethane | N Parameter: 3.58 sN Parameter: 0.70 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
trifluoroacetamide anion (in DMSO) | DMSO | N Parameter: 15.81 sN Parameter: 0.64 | J. Org. Chem. 2010, 75, 5250-5258 DOI: 10.1021/jo1009883 | |
trifluoroethanol | TFE | N Parameter: 1.11 sN Parameter: 0.96 | J. Am. Chem. Soc. 2012, 134, 13902-13911 DOI: 10.1021/ja306522b | |
trihexylsilane | dichloromethane | N Parameter: 3.89 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triisopropylphosphane | dichloromethane | N Parameter: 13.37 sN Parameter: 0.70 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
triisopropylsilane | dichloromethane | N Parameter: 2.93 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl phosphite (in 91M9AN) | MeOH-MeCN mix | N Parameter: 9.04 sN Parameter: 0.70 | Angew. Chem. Int. Ed. 2006, 45, 3869-3874 DOI: 10.1002/anie.200600542 | |
trimethyl(3-(trimethylgermyl)propyl)silane (in MeCN) | MeCN | N Parameter: -4.80 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(3-(trimethylplumbyl)propyl)germane (in MeCN) | MeCN | N Parameter: -1.00 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(3-(trimethylplumbyl)propyl)silane (in MeCN) | MeCN | N Parameter: -1.20 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(3-(trimethylstannyl)propyl)germane (in MeCN) | MeCN | N Parameter: -2.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(3-(trimethylstannyl)propyl)silane (in MeCN) | MeCN | N Parameter: -3.40 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(4-methylphenethyl)stannane | 1,2-dichloroethane | N Parameter: -0.50 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(phenethyl)silane | dichloromethane | N Parameter: -3.50 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(phenethyl)stannane | 1,2-dichloroethane | N Parameter: -1.10 sN Parameter: 1.10 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
trimethyl(prenyl)silane | dichloromethane | N Parameter: 0.90 sN Parameter: 1.17 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
trimethylamine (in MeCN) | MeCN | N Parameter: 23.05 sN Parameter: 0.45 | J. Org. Chem. 2012, 77, 8142-8155 DOI: 10.1021/jo301497g | |
trimethylhydrazine (in MeCN) | MeCN | N Parameter: 12.43 sN Parameter: 0.75 | Angew. Chem. Int. Ed. 2012, 51, 1353-1356 DOI: 10.1002/anie.201107315 | |
trimethylhydrazine (in MeCN) | MeCN | N Parameter: 17.75 sN Parameter: 0.53 | Angew. Chem. Int. Ed. 2012, 51, 1353-1356 DOI: 10.1002/anie.201107315 | |
trimethylsilane | dichloromethane | N Parameter: 3.15 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triphenyl phosphite | dichloromethane | N Parameter: 5.51 sN Parameter: 0.76 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
triphenylgermane | dichloromethane | N Parameter: 3.99 sN Parameter: 0.62 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
triphenylmethane | dichloromethane | N Parameter: -4.27 sN Parameter: 0.80 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triphenylphosphane | dichloromethane | N Parameter: 14.33 sN Parameter: 0.65 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
triphenylphosphine (in THF) | THF | N Parameter: 13.59 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2011, 50, 6915-6919 DOI: 10.1002/anie.201102435 | |
triphenylsilane | dichloromethane | N Parameter: 2.65 sN Parameter: 0.72 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
triphenylstannane | dichloromethane | N Parameter: 5.64 sN Parameter: 0.59 | J. Am. Chem. Soc. 2001, 123, 9500-9512 DOI: 10.1021/ja010890y | |
tripropylsilane | dichloromethane | N Parameter: 3.67 sN Parameter: 0.73 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris((butyldimethylsilyl)methyl)silane | dichloromethane | N Parameter: 3.73 sN Parameter: 0.68 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris((dimethyl(phenyl)silyl)methyl)silane | dichloromethane | N Parameter: 3.40 sN Parameter: 0.66 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris((trimethylsilyl)methyl)silane | dichloromethane | N Parameter: 3.59 sN Parameter: 0.67 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris(2,4-dimethylphenyl)phosphane | dichloromethane | N Parameter: 14.88 sN Parameter: 0.41 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
tris(2,6-dimethoxyphenyl)phosphane | dichloromethane | N Parameter: 15.19 sN Parameter: 0.88 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
tris(2,6-dimethoxyphenyl)phosphane (in MeCN) | MeCN | N Parameter: 18.11 sN Parameter: 0.62 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
tris(2-methoxyphenyl)phosphane | dichloromethane | N Parameter: 14.26 sN Parameter: 0.73 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
tris(2-methylphenyl)phosphane | dichloromethane | N Parameter: 8.56 sN Parameter: 0.70 | Chem. Eur. J. 2017, 23, 7422-7427 DOI: 10.1002/chem.201701080 | |
tris(4-(dimethylamino)phenyl)methane (in MeCN) | MeCN | N Parameter: -3.30 sN Parameter: 0.82 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris(4-chlorophenyl)phosphane | dichloromethane | N Parameter: 12.58 sN Parameter: 0.65 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
tris(4-dimethylaminophenyl)phosphane | dichloromethane | N Parameter: 18.39 sN Parameter: 0.64 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
tris(4-methoxyphenyl)methane (in MeCN) | MeCN | N Parameter: -5.18 sN Parameter: 0.82 | Chem. Eur. J. 2013, 19, 249-263 DOI: 10.1002/chem.201202839 | |
tris(4-methoxyphenyl)phosphane | dichloromethane | N Parameter: 16.17 sN Parameter: 0.62 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
tris(4-methylphenyl)phosphane | dichloromethane | N Parameter: 15.44 sN Parameter: 0.64 | Chem. Eur. J. 2005, 11, 917-927 DOI: 10.1002/chem.200400696 | |
uracil anion (in DMSO) | DMSO | N Parameter: 17.04 sN Parameter: 0.63 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
uracil anion (in water) | water | N Parameter: 10.75 sN Parameter: 0.53 | Chem. Eur. J. 2012, 18, 127-137 DOI: 10.1002/chem.201102411 | |
valine (anionic, in water) | water | N Parameter: 13.65 sN Parameter: 0.57 | Org. Biomol. Chem. 2007, 5, 3814-3820 DOI: 10.1039/b713778h | |
water (in MeCN) | MeCN | N Parameter: 5.79 sN Parameter: 0.72 | Bull. Chem. Soc. Jpn. 2018, 91, 523-530 DOI: 10.1246/bcsj.20170360 | |
xanthene | dichloromethane | N Parameter: 0.64 sN Parameter: 0.97 | J. Am. Chem. Soc. 2002, 124, 4076-4083 DOI: 10.1021/ja0121538 | |
Z-3-(trimethylsiloxy)pent-2-ene | dichloromethane | N Parameter: 5.58 sN Parameter: 1.00 | Acc. Chem. Res. 2003, 36, 66-77 DOI: 10.1021/ar020094c | |
[H-B(2,4,6-F3C6H2)3]- [NEt4]+ | MeCN | N Parameter: 14.13 sN Parameter: 0.61 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 | |
[H-B(2,6-F2C6H3)3]- [NEt4]+ | MeCN | N Parameter: 13.97 sN Parameter: 0.66 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 | |
[H-B(C6F5)3]- [NEt4]+ | MeCN | N Parameter: 10.04 sN Parameter: 0.73 | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 DOI: 10.1002/anie.201507298 |