Mayr's Database of Reactivity Parameters

MacMillan-iminium ion (1st generation)

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations » N-substituted carbocations (iminium ions)

Information panel

Name MacMillan-iminium ion (1st generation)
Structure
image of molecule
Molecule class Electrophiles » C-Electrophiles » Carbocations » N-substituted carbocations (iminium ions)
SMILES O=C([C@@H]/1CC2=CC=CC=C2)N(C)C(C)(C)[N+]1=C\C=C\C3=CC=CC=C3
Molecular formula C22H25N2O+
Quality ***
Parameters

E Param.: -7.37
Comment The previously published tentative E = -7.20 has been revised in this work on the basis of additional kinetic experiments.
Solvent MeCN
Reference Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683