MacMillan-iminium ion (1st generation)
Information panel
Name | MacMillan-iminium ion (1st generation) |
Structure | |
Molecule class | Electrophiles » C-Electrophiles » Carbocations » N-substituted carbocations (iminium ions) |
SMILES | O=C([C@@H]/1CC2=CC=CC=C2)N(C)C(C)(C)[N+]1=C\C=C\C3=CC=CC=C3 |
Molecular formula | C22H25N2O+ |
Quality | |
Parameters |
E Param.: -7.37 |
Comment | The previously published tentative E = -7.20 has been revised in this work on the basis of additional kinetic experiments. |
Solvent | MeCN |
Reference |
Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 |