Mayr's Database of Reactivity Parameters

MacMillan-iminium ion (1st generation)

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Name MacMillan-iminium ion (1st generation)
Molecule class Electrophiles » C-Electrophiles » Carbocations » N-substituted carbocations (iminium ions)
SMILES O=C([C@@H]/1CC2=CC=CC=C2)N(C)C(C)(C)[N+]1=C\C=C\C3=CC=CC=C3
Molecular formula C22H25N2O+
Quality ***

E Param.: -7.37

Comment The previously published tentative E = -7.20 has been revised in this work on the basis of additional kinetic experiments.
Solvent MeCN
Reference Angew. Chem. Int. Ed. 2011, 50, 9953-9956