Mayr's Database of Reactivity Parameters

S-Ylides

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Ylides
« Back Forward » Found 10 molecules, displaying page 1 of 1 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(4-Br-C6H4)-(CO)-CH=SMe2
*
 dichloromethane

N  Param.: 11.95

sN Param.: 0.76		***Angew. Chem. Int. Ed. 2009, 48, 5034-5037
10.1002/anie.200900933
Me2S=CH-CO2Et (in DMSO)
*
 DMSO

N  Param.: 15.85

sN Param.: 0.61		***Chem. Eur. J. 2010, 16, 8610-8614
10.1002/chem.201001455
Me2S=CH-CN (in DMSO)
*
 DMSO

N  Param.: 16.23

sN Param.: 0.60		***Chem. Eur. J. 2010, 16, 8610-8614
10.1002/chem.201001455
(4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 13.78

sN Param.: 0.72		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(C6H5)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 13.95

sN Param.: 0.69		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 14.48

sN Param.: 0.71		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 15.68

sN Param.: 0.65		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
Me2S=CH(p-NO2-C6H4) (in DMSO)
*
 DMSO

N  Param.: 18.42

sN Param.: 0.65		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
Me2S=CH(4-CN-C6H4) (in DMSO)
*
 DMSO

N  Param.: 21.07

sN Param.: 0.68		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
Me2S(O)=CH2 (in DMSO)
*
 DMSO

N  Param.: 21.29

sN Param.: 0.47		***J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749