Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of dimedone (in DMSO)
C8H11O2 *
 DMSO

N  Param.: 16.27

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
anion of acetylacetone (in DMSO)
C5H7O2 *
 DMSO

N  Param.: 17.64

sN Param.: 0.73		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
anion of ethyl acetylacetate (in DMSO)
C6H9O3 *
 DMSO

N  Param.: 18.82

sN Param.: 0.69		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
anion of malononitrile (in DMSO)
C3HN2 *
 DMSO

N  Param.: 19.36

sN Param.: 0.67		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
anion of ethyl cyanoacetate (in DMSO)
C5H6NO2 *
 DMSO

N  Param.: 19.62

sN Param.: 0.67		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
triphenylphosphane
C18H15P *
 dichloromethane

N  Param.: 14.33

sN Param.: 0.65		 *** Chem. Eur. J. 2005, 11, 917-927
10.1002/chem.200400696
anion of diethyl malonate (in DMSO)
C7H11O4 *
 DMSO

N  Param.: 20.22

sN Param.: 0.65		 *** Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
methylenecyclopropane
C4H6 *
 dichloromethane

N  Param.: -0.47

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclobutane
C5H8 *
 dichloromethane

N  Param.: 1.65

sN Param.: 0.90		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclohexane
C7H12 *
 dichloromethane

N  Param.: 1.16

sN Param.: 1.04		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b