Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Allyl-B

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Allyl Element Compounds
Found 5 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
dichloromethaneN  Parameter: -0.64
sN Parameter: 1.10
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 9.49
sN Parameter: 0.82
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 8.71
sN Parameter: 0.80
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 11.20
sN Parameter: 0.64
*J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

potassium allyltrifluoroborate (in MeCN)
MeCNN  Parameter: 5.29
sN Parameter: 0.87
**J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240