Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Allyl Element Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 38 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
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(1H-inden-1-yl)trimethylsilane (in CH2Cl2)
dichloromethaneN  Parameter: -0.10
sN Parameter: 1.05
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
image of molecule

(1H-inden-1-yl)trimethylstannane (in CH2Cl2)
dichloromethaneN  Parameter: 6.68
sN Parameter: 0.81
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
image of molecule

(1H-inden-1-yl)zinc(II) bromide*LiBr (in DMSO)
DMSON  Parameter: 15.60
sN Parameter: 0.51
**Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
image of molecule

(1H-inden-1-yl)zinc(II) chloride*LiCl (in DMSO)
DMSON  Parameter: 18.10
sN Parameter: 0.46
**Angew. Chem. Int. Ed. 2015, 54, 12497-12500
DOI: 10.1002/anie.201501385
image of molecule

(2,3-dimethylbut-2-enyl)triethylsilane
dichloromethaneN  Parameter: 3.15
sN Parameter: 1.15
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II)
dichloromethaneN  Parameter: 8.45
sN Parameter: 0.83
***Helv. Chim. Acta 2005, 88, 1754-1768
DOI: 10.1002/hlca.200590137
image of molecule

(2-methylallyl)tributylstannane
dichloromethaneN  Parameter: 7.48
sN Parameter: 0.89
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(2-methylallyl)trichlorosilane
dichloromethaneN  Parameter: -0.57
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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(2-methylallyl)trimethylsilane
dichloromethaneN  Parameter: 4.41
sN Parameter: 0.96
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(2-methylallyl)triphenylgermane
dichloromethaneN  Parameter: 4.67
sN Parameter: 0.81
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(2-methylallyl)triphenylsilane
dichloromethaneN  Parameter: 4.17
sN Parameter: 0.79
**J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(2-methylallyl)triphenylstannane
dichloromethaneN  Parameter: 5.13
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

(2-methylallyl)tris(trimethylsilyl)silane
dichloromethaneN  Parameter: 4.63
sN Parameter: 0.87
***Org. Lett. 2010, 12, 5206-5209
DOI: 10.1021/ol102220e
image of molecule

(allyl)dicarbonyl(cyclopentadienyl)iron(II)
dichloromethaneN  Parameter: 6.78
sN Parameter: 0.95
***Helv. Chim. Acta 2005, 88, 1754-1768
DOI: 10.1002/hlca.200590137
image of molecule

(E)-but-2-enyltrimethylsilane
dichloromethaneN  Parameter: 1.94
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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(Z)-but-2-enyltrimethylsilane
dichloromethaneN  Parameter: 1.69
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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2-phenyl-allyltrimethylsilane
dichloromethaneN  Parameter: 5.38
sN Parameter: 0.89
***Chem. Eur. J. 2014, 20, 1103-1110
DOI: 10.1002/chem.201303215
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3-(trihexylsilyl)cyclopentene
dichloromethaneN  Parameter: 1.98
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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3-(trimethylsilyl)cyclopentene
dichloromethaneN  Parameter: 1.77
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
dichloromethaneN  Parameter: -0.64
sN Parameter: 1.10
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

allyl-tert.butyl-dimethylsilane
dichloromethaneN  Parameter: 1.80
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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allylchlorodimethylsilane
dichloromethaneN  Parameter: -0.57
sN Parameter: 1.06
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

allyltri-n-butylsilane
dichloromethaneN  Parameter: 2.09
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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allyltributylstannane
dichloromethaneN  Parameter: 5.46
sN Parameter: 0.89
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

allyltriethylsilane
dichloromethaneN  Parameter: 1.93
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

allyltrihexylsilane
dichloromethaneN  Parameter: 2.11
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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allyltriisopropylsilane
dichloromethaneN  Parameter: 2.04
sN Parameter: 0.95
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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allyltrimethylsilane
dichloromethaneN  Parameter: 1.68
sN Parameter: 1.00
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

allyltriphenylgermane
dichloromethaneN  Parameter: 1.20
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

allyltriphenylsilane
dichloromethaneN  Parameter: -0.13
sN Parameter: 1.21
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

allyltriphenylstannane
dichloromethaneN  Parameter: 3.09
sN Parameter: 0.90
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

allyltris(trimethylsilyl)silane
dichloromethaneN  Parameter: 1.95
sN Parameter: 0.98
***Org. Lett. 2010, 12, 5206-5209
DOI: 10.1021/ol102220e
image of molecule

lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 9.49
sN Parameter: 0.82
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 8.71
sN Parameter: 0.80
***J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)
MeCNN  Parameter: 11.20
sN Parameter: 0.64
*J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

potassium allyltrifluoroborate (in MeCN)
MeCNN  Parameter: 5.29
sN Parameter: 0.87
**J. Am. Chem. Soc. 2017, 139, 15324-15327
DOI: 10.1021/jacs.7b10240
image of molecule

prenyl-tributylstannane
dichloromethaneN  Parameter: 4.74
sN Parameter: 1.15
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

trimethyl(prenyl)silane
dichloromethaneN  Parameter: 0.90
sN Parameter: 1.17
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y