Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
10% ethanol/90% MeCN (v/v)
C2H6O *
 EtOH-MeCN mix

N  Param.: 5.19

sN Param.: 0.96		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
91% methanol/9% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.45

sN Param.: 0.87		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% methanol/20% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.20

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% methanol/33% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 7.01

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
50% methanol/50% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.67

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
33% methanol/67% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.38

sN Param.: 0.92		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
20% methanol/80% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 6.04

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
10% methanol/90% MeCN (v/v)
CH4O *
 MeOH-MeCN mix

N  Param.: 5.55

sN Param.: 0.97		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
1,1-diethoxyethene
C6H12O2 *
 dichloromethane

N  Param.: 9.81

sN Param.: 0.81		 *** Eur. J. Org. Chem. 2004, , 2791-2796
10.1002/ejoc.200400134
1-butoxy-1-(trimethylsiloxy)ethene
C9H20O2Si *
 dichloromethane

N  Param.: 10.21

sN Param.: 0.82		 **** Eur. J. Org. Chem. 2004, , 2791-2796
10.1002/ejoc.200400134